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    w

    g

    g

    w

    g

    w

    n

    n

    n/C

    n/C

    v

    v  

    Since frequency f of light does not change, vw = wf and vg = gf we obtain,

    w

    g

    g

    w

    g

    w

    n

    n

    v

    v

     

    8

    9

    3/4

    2/3

    g

    w

     

    8

    1

    8

    89

    g

    gw

     

    8

    1

    g

    .

    Q.5.  Momentum of a photon = h/ 

    momentum of electron = mvso  = h / mv

     =531

    34

    102101.9

    1063.6

     

     = 3.6 nm

    Q.6. 2/12/1 T/t)T(

    0 2

    1

    e

    1

    N

    N

     

    also4

    1

    N

    N

    0

    1   or t1 = 2T1/2 

    &81

    NN

    0

    2   or t2 = 3T1/2 

    t = 10 = t2 – t1 = T1/2 T1/2 = 10 sec.

    Tmean =693.0

    T 2/1  = 14.43 sec.

    Q.7.    = a(z - b)

      )bz(ac

    11

      . . . . (i)

    & )bz(ac 22

      . . . (ii)

    From (i) - (ii),

    21

    11c  = a(z1 - z2 )

      a = 5  107  (Hz)1/2 

    From (i) /(ii),bz

    bz

    2

    1

    1

    2

       b = 1.37

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    Q.8.  Removal of an electron results into He+, and energy required to remove an electron from He+ = z2  

    13.6 eV

    = 4  13.6 = 54.4 eVso total energy required= 54.4 + 24.6

    = 79 eV.

    Q.9.  According to Bohr theory

    22

    21

    2

    n

    1

    n

    1RZ

    Thus2Z

    1  

    More the atomic number, smaller is the wavelength obtained in the transition of electron (for

    identical transition).

    Q.10.  )bZ(Rv    

    or 2)1Z(1

      (If b is small)

     2

    si

    u

    91

    46

     

      

     

     

    u = 0.146 A°

    Q.11.  E2 – E1 = hc

    2 1

    1 1

     

    = 1 21 2

    hc( )

     

    taking approximation that

    if y  2 then

    1/ 21 21 2( )

    2

     

    E2 – E1 = 2  10-3 eV.

    Q.12. 

    1 2 3

    hc hc hc

     

     3 = 1 21 2

    .

    Q.13. dN

    n Ndt

     

    0

    N t

    N 0

    dNdt

    n N

     

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    0n N1 lnn N

    = t

      N = t0

    n nN e

     

    Q.14.  Current is independent of work function of metal. It depends on photon density onlyhence I1= I2 

    Q.15.  Let at time ‘t’ number of radioactive nuclear be N.

    Net rate of formation of nuclear of A isdN

    dt =  – N

    Or,dN

    N = dt

    orN

    N0

    dN

    N  =t

    0dt    this gives N = t0

    1N e

     

    Q.16. 1

    2

    /hc

    /hc

    2

    1

     

     = 1.05 eV

    Q.17.  )bZ(Rv    

    or 2)1Z(1

      (If b is small)

     2

    si

    u

    91

    46

     

      

     

     

    u = 0.146 A°

    Q.18. 1

    2

    /hc

    /hc

    2

    1

     

     = 1.05 eV

    Q.19.  Q = total energy released

    =2

    1mv

    2 +2

    1 myvy

    2  . . . . . (i)

    by conservation of momentum

    mv + myvy  = 0 . . . . . (ii)

    from equation (i) and (ii)

    Q =2

    1 mv

     

      

       

    ym

    m1  

     Q = 5.3410 MeValso Q = (Mx – my  m)  931.5 Mx = 239.048 amu.

    Q.20.  Velocity of neutrons =27

    19

    n 1067.1

    0327.0106.12

    m

    eV2

     

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    = s/m1029.6 6  = 2.5  103 m/s

    Time taken by neutron to cover the distance 10 m

    t = 33

    104105.2

    10  

     seconds

    Now t

    0

    eN

    N    

    where N is number of neutron after t seconds i.e. fraction of neutron decayed after t seconds will be

    1-4109.93104

    0

    eN

    N    

    sec/109.9700

    693.0 4   = 4  10-6 

    Q.21.  According to Moseley’s equation for k radiation ;

      

      

    222

    21

    11)1z(R1  

    5405.1

    7092.0

    )1z(

    )1z(2

    1

    21

     

    z = 29 for cu, hence z1 – 1 = 286578.1

    5405.1 = 27

    or z1 = 4z

      Impurity is molybdenum

    similarly ;5405.1

    65768.1

    )1z(

    )1z(2

    2

    2

    1

    2

     

    or z2 – 1 = 28 276578.1

    5405.1  

    z2 = 28

    It is atomic number of Nickel.

    Hence the other impurity is Nickel.

    Q.22.  Energy of a photon = E =6000

    12400hc

     = 206 eV

    = 2.06  1.6  10-19 J= 3.3  10-19 J

    Photon flux =19103.311400

    EIA

     

    = 4.22  1021 photon/sec.

    Q.23.  Momentum of the photon , p=     E

    c

    133 10 1 6 10

    3 10

    6 19

    8

    . . 

    = 7.0910-22 kgms-1 Using momentum conservation recoil energy of the

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    60 Ni   is E =  

       p

    m

    2  22

      2

    272

    7 09 10

    2 60 167 10

    .

    .= 2.5110-18 J = 1.57 10-5 MeV

    Recoil speed of the nucleus, v =  pm

    m s  

     

    7 09 10

    60 1 67 107 07 10

    22

    27

    3.

    .. /  

    Q.24.  (i) Energy of each photon = E =

    hc = 3.975  10-19 J

    No. of photons falling on surface per second & being absorbed,

    n=eV48.2

    J10 = 2.52  1019 eV

    (ii) The linear momentum of each photon = p =c

    hh  

     

      Total momentum of all photons (falling in one sec.)

    =8

    nh 10J

    c 3 10

     = 3.33  10-8 N-s

    Rate of change of momentum = Force =dt

    dp = 3.33  10-8  N.

    Q.25.  By relation,

    eV =

    hc, where  is work function

    Differentiating w.r.t. , we get

    2

    hc

    d

    dVe  

    or dV = -

    de

    hc2

     

    dv = -)106.1()104000(

    10210310623.619210

    10834

     

    = - 1.56 mV.

    Q.26.  Moseley’s law

       

      

     

    22

    n

    111zR

    1 for K- lines where n =2,3,4,.....................

    For K-absorption edge

    R

    11z

     

    or z =

    74110097.110171.0

    1710

       

     

    The element is Tungsten.

    Q.27.  Current is independent of work function of metal. It depends on photon density only hence

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    2

    1

    I

    I = 1

    Q.28.  Velocity of neutrons = 27

    19

    n 1067.1

    0327.0106.12

    m

    eV2

     

    = s/m1029.6 6  = 2.5  103 m/s

    Time taken by neutron to cover the distance 10 m

    t = 33

    104105.2

    10  

     seconds

    Now t

    0

    eN

    N    

    where N is number of neutron after t seconds i.e. fraction of neutron decayed after t seconds will be

    1-4

    109.93

    104

    0e

    NN

     

     

    sec/109.9700

    693.0 4   = 4  10-6 

    Q.29.  At time t lets say there are N atoms. In time dt, dN1 decays and dN2 produces

    dN2 =1000106.1

    dt1019

    4

      dN1 = N dt.

    Total production in time dt dN =  

      

     

      N

    106.1

    112

    dt

        3600

    0

    N

    011

    dtN1025.6

    dN0  

    - 36001025.6

    N1025.6log

    111

    011

     

    N0 = 1.8  108 . (given)    = 8  10-8 

    t1/2  = 8108

    6931.0

     = 8.66  106 sec.

    = 100.26 days.

    Q.30.  

     

     

     

    2221

    2

    n

    1

    n

    1

    RZ

    1

     

     

      

     

      2227 n

    1

    2

    14109678

    10121

    n2 = 4

    no. of revolution per second =ncecircumfere

    orbitthatinvelocity 

    f = 02

    0

    v n / z

    n2 r 

    z

     = 4.09  1014 Hz.

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    Q.31.  En – E1 =

    hc 

    after putting the values we getn = 4

    possible lines in the resulting emission spectrum = 6.

    Q.32. 

      t

    12

    2t

    12

    1

    0

    3 12 ee1N

    N  1 =

    30

    6931.0  2 =

    45

    6931.0, t = 60 min.

    = [1 + (-3) (2)-4/3 - (-2) (2)-2 ]

    = [1 - 3  (2)-4/3 + 2(2)-2 ]=0.71

    Q.33.  E =

    hC =  + (KE)max 

     3.1 = 2.5 + (KE)max 

      (KE)max = 0.6 ev = 0.6  1.6  10 –19 J = 9.6  10 –20 Jp = mK2  = 2031 106.9101.92    = 4.2  10 –25 kg – m/sec

    Q.34.  (a)2

    2613

    n

    Z.En

     

    Excitation energy = E = E3 - E1 = -13.6  (3)2 

    22 1

    1

    3

    = +13.6 (9) [1 - 1/9] = 13.6  (9) (8/9) = 108.8 eV.

    19834

    106.18.108

    1031063.6

    E Δ

    hc

    Wavelength

      = 114.3 A 

    (b) From the excited state (E3), coming back to ground state, there can be3C2  = 3 possible

    radiations.

    Q.35.  Mass defect

    m = (2  2.0141 – 4.0026) amuor  m = (2  2.0141 – 4.0026)   931 MeVEnergy used in reactor per reaction

    =100

    25 (2  2.0141 – 4.0026)  931 = 5.9584 MeV

    = 9.5334  10-13 Joule.

    Total energy obtained per day

    = (200) MW  24  60  60 sec.

    Mass of deuterium required

    =13

    621

    105334.9

    )60602410200)(106691.0(

    = 120 g.

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    Q.36.  dt

    dNq - N

    q = rate of production of nucleiN = number of nuclei in radionuclide at any instant

     = decay constant = T2ln

     

    T = half life

    dt

    dNq - N = q -

    T

    2lnN 

    T

    2lnNqT

    dt

    dN    

    T

    dt

    2lnNqT

    dN

      . . . (1)

    integrating equation (1)

     

    t

    0

    N

    0

    dt

    T

    1

    2lnNqT

    dN 

    N =  

      

     

      T

    2lnt

    e12ln

    qT =

     

      

     

      1620

    2ln3240

    e12ln

    16201000 = 1.753  106 

    Hence, rate of decay A = N = q  

      

     

      T

    2lnt

    e1  

    Hence rate of release of energy at this time,

    = AE0 = qE0 (1 - etln2/T) = 1000  200 (1 – e(3240  ln2/1620))

    = 150  103 MeV/sec.Total number of nuclei decayed upto this time = q  t – Nhence total energy released upto this time

    = (qt – N) E0 = 297.43  106 MeV.

    Q.37.  Let at time ‘t’ number of radioactive nuclear be N.

    Net rate of formation of nuclear of A isdt

    dN =  – N

    Or,N

    dN

     = dt

    or   N

    0N N

    dN =

    t

    0dt    this gives N = t0 eN

    1  

     

    Q.38.  (a) E =

    hC

     =  + (KE)max 

    400

    1242 =  + (KE)max 

    3.1 = 2.5 + (KE)max (KE)max = 0.6 ev = 0.6  1.6  10

     –19 J = 9.6  –20 J

    p = mK2  = 2031 106.9101.92    = 4.2  10 –25 kg – m/sec

    (b) Stopping potential

    e

    KE max  = 0.6 volt

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    Q.39.  Let  be decay constant

    Ndt

    dN  = Rate of formation of nuclei

    dt

    N

    dN

     

    Integrating both side we get

    ln ( - n

    0)N   = - t

    i.e. ln tN

     

    (at t = 0, N = 0)

    teN  

     

    i.e. N =

      )e1( t 

    so as t  , e-t

       0so after very long time

    N = ttancons

     

    or N =693.0

    T 2/1  

    Q.40. The maximum energy of photon during de-excitation will be if transition takes place between (2n)states to ground state.

    hence, 204 = 13.6  

      

     

    2n4

    1

    1

    1z2  … (i)

    also 40.8 = 13.6 222

    zn41

    n1

      

         … (ii)

    dividing (i) by (ii) we get

    5 =3

    1n4 2     n = 2

    substituting n = 2 in equation (i)

    15 =16

    15z2 

      z2 = 16 or z = 4The minimum energy during de-excitation will be if transition takes place between two outer mostadjacent orbit. i.e. n = 4 to 3.

    Emin = 13.6 222 44

    1

    3

    1

      

        

    = 10.57 eV

    Q.41. Mass defect m = 2mD – mT – mP = 2  2.01458 – 3.01605 – 1.00728= 0.00583 amu.

    hence E = 0.00583  930  1.6  10-19  106 = 8.675  10-13 J

    The efficiency of the retardation is 60 %

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    Eavailable = 0.6  8.675  10-13 J

    = 5.205  10-13 JTotal energy required in one hour

    E = 108  3600 = 36  1010 JHence number of deuterium nuclides required

    = EE2 1.38  1024 

    Q.42.  (i) A = 228 + 4 = 232

    & 92 = z + 2   z = 90

    (ii) Bqvr 

    vm 2

        v = 1.59  10

    7 m/s

    From COM, m v = my vy Thus, energy released or the sum of kinetic energies of the products

    =

    2

     

    y

    222

    m

    vmvm  

    = 5.342 MeV= 0.0057 amu.

     Applying COE,

    Mass of 23292 X  = my + m + 0.0057 amu.

    = 232.0387 amu

      Mass defect = 92 (1.008) + 140 (1.009) - 232.0387= 1.9573 amu = 1823 MeV

    Q.43.  Reactant Products

    1023 Ne   22.9945-10me  1123 Na   22.9898-11me 

    10   me    0 .

    Total 22.9945-10me  22.9898-10me 

    mass defect = 22.9945-22.9898=0.0047u

    Since, 1u = 931.4 MeV

      Energy release = (0.0047)(931.4)= 4.4MeV

    The major portions of this energy is shared by  particle and anti-neutrino. Hence the energy rangeof

     - particle varies from 0 to 4.4 Mev.

    Q.44.  h1  = 13.6  (2)2  1.6  10-19 

    22 )1n(

    1

    n

    hf  = 13.6  (2)2  1.6  10-19 

    1

    n

    12

     

    h(f  - 1) = 2

    192

    )1n(

    106.1)2(6.13

        f  - 1 = 3.3  10

    15  (given)

      (n + 1)2  = 4   n = 1

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    1

    hc 13.6  (2)2  1.6  10-19 

    4

    1

    1

    1 .

      1 = 303 A0.

    Q.45.  At time t lets say there are N atoms. In time dt, dN1 decays and dN2 produces

    dN2 =1000106.1

    dt1019

    4

      dN1 = N dt.

    Total production in time dt dN =  

      

     

      N

    106.1

    112

    dt

    0N 3600

    11

    0 0

    dNdt

    6.25 10 N

     

    -11

    0

    11

    6.25 10 N1ln 3600

    6.25 10

       

    N0 = 1.8  108 . (given)

       = 8  10-8 

    t1/2  = 8108

    6931.0

     = 8.66  106 sec.

    = 100.25 days.

    Q.46.  Mass diff. = 2  2.015 – (3.017 + 1.009) = 0.004 amu.  energy released = 0.004  331 MeV = 3.724 MeV

    energy released per deuteron = 724.32

    1 MeV

    No. of deuteron in 1 kg =

    2

    1002.6 26 

      energy released / kg = 1.862  0.301  1026 MeV 9  1013 J.

    Q.47.  (i). Energy of each photon = E =

    hc = 3.975  10-19 J

    No. of photons falling on surface per second & being absorbed,

    n=eV48.2

    J10 = 2.52  1019 eV

    (ii). A = 228 + 4 = 232

    & 92 = z + 2   z = 90

    (1.v) A radioactive nuclide with half life period T is produced at the constant rate of n per second.

    The number of radioactive nuclide at t = 0 is N0 , find

    (i) the number of radioactive present at time t

    (ii) the maximum number of these radioactive nuclei

    (1.v) Nndt

    dN     

    t

    0

    Nt

    0N

    dtNn

    dN   

    t0

    t

    eNnnN  

    Where N is maximum, 0dt

    dN     N =

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    Q.48.  (a)2

    0

    22

    r 4

    Ze

    mv

      . . . (i)

    & mvr =

    2

    nh  . . . (ii)

    From (i) & (ii), r =2

    022

    meZ

    hn

      Here z = 3 & m = 208 me,  r  = 2

    e

    022

    em624

    hn

    ,

    (b)2

    e

    02

    2e

    022

    em

    h

    em624

    hn

        n  25

    (c) En = Total Energy = - 2220

    42

    0

    2

    hn8

    mez

    r 8

    ze

     

    =

    220

    4e

    2 h8

    em

    n

    1872 

    = - 6.13n

    18722

      eV

      E1 = -25.4 keV ; E3 = -2.8 keV & E3 - E1 = 22.6 keV .

      Required wavelength =  =E

    hc

     = 55 pm.

    Q.49.  Mass defect

    m = (2  2.0141 – 4.0026) amuor  m = (2  2.0141 – 4.0026)   931 MeV

    Energy used in reactor per reaction

    =100

    25 (2  2.0141 – 4.0026)  931 = 5.9584 MeV

    = 9.5334  10-13 Joule.

    Total energy obtained per day

    = (200) MW  24  60  60 sec.

    Mass of deuterium required

    =13

    621

    105334.9

    )60602410200)(106691.0(

    = 121 g.

    Q.50.  For photons of 1 = 4000A, energy E1 =4000

    12375eV = 3.094 eV

    and for 2= 6000A, energy E2 =6000

    12375eV = 2.061 eV

    Thus photo-electronic emission is possible with 1 only, which experience Lorenz force and movealong circular path. The ammeter will indicate zero deflection if the photoelectrons just completesemi-circular path before reaching the plate P. Thus separation d = 2r = 10 cm

      r = 5m

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    but, r =qB

    mv    Bmin =

    qr 

    mv 

    Now, eV39.2094.3Whc

    mv2

    1

    1

    2

     

    Substituting the value for v, m, q and r,Bmin = 5.6610

    -5T

    Q.51.  de-Broglie wavelength 1 =p

    h =

    mve2

    Shortest X-ray wavelength 2 =ve

    hc 

     m2

    ve

    c

    1

    mve2c

    ve

    2

    1

     

    Substituting the values, 113

    8

    2

    1 108.12

    1010

    103

    1

     = 0.1

    Q.52.  (a) Using Einstein’s relationEmax = hf - Wo here Emax = hf - Wo = 13.6 eV

    and Emax =

    19883

    o106.11015.12

    1031063.6hcWf 

    6

    5h

     

      

      = 10.2 eV

    From the above two equations,

    6

    hf 3.4 eV

    or f =

    34

    19

    1063.6

    106.14.36

     = 4.92  1015 Hz

    (b) Wo = hf - 13.6 = 6(3.4) - 13.6 = 6.8 eV

    Q.53.  (i) E =   +2

    1m 2maxv  

    = 1.82 + 0.73 = 2.55 eV

    (ii) En = -2n

    6.13eV (for hydrogen atom)

      E1 = -13.6 eV, E2 = - 3.4 eV, E3 = -1.51 eV, E4 = -0.85 eV

    clearly E4 – E2 = -0.85 – (-3.4) = 2.55 eV.Hence quantum levels involved are 4 and 2.

    (iii)  = n    

      

     2

    change in angular momentum = 4 - 2 

    = (4 – 2)

     

      

     

    h

    2

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    (iv) If P = linear momentum, then

    P =c

    E = 1.36  10-27 kg ms-1 

    If v = recoil speed of hydrogen atom of mass M, then from COM,Mv = P

    or v =M

    P  = 0.85 ms-1.

    Q.54.  (a) Number of photoelectrons emitted from plate A upto

    t =10 s 76

    164

    e 1051010

    10)105(n  

     

    (b) Charge on plate B at t = 10 sec

    Qb = 33.7  10-12 – 5  107  1.6  10-19 

    = 25.7  10-12 Calso Qa = 8  10

    -12 C

    )QQ( A2

    1

    22E AB

    00

     A

    0

    B

     

    =124

    12

    1085.8105

    107.17

      = 2000 N/C

     A B

    d =1 cm

    (c) K.E. of most energetic particles

    = (h -) + e(Ed) = 23 Ev

    Q.55.  1102

    m10p

    11

    1500

    11  

      …. (i)

    or E = J10

    P

    11

    1500

    hchc 102

     

     =

     

     

     

     

    219

    10

    p

    11

    106.0(1500

    10hceV

    = 8.28  

      

     

    2p

    11 eV

    (a) wavelength of the most energetic photon is corresponding to p = ,   = 1500  10-10 m = 1500 A0 wavelength of least energetic photon. corresponding to

    p = 2, hence again

     = 1500  10-10  14

    4

     = 2000 A0 

    (b) According to equation

    E = 8.28

    )P1(

    P28.8

    P1P

    2

    22

    2

      

          = eV

    n28.8 2  

    or En  = - 2n

    28.8eV

    for n = 1, E1 = - 8.28 eV n = 3_______ - 0.92 eV

    for n = 2, E2 = - 2.07 eV n = 2_______ -2.07 eV

    for n = 3, E3 = -0.92 eV n = 1_______ -8.28 eV

    (c) Ionization energy = - E1 = 8.28 eV

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    Hence ; ionization potential = 0.28 volt.

    Q.56.  (a)2

    0

    22

    r 4

    Ze

    mv

      . . . (i)

    & mvr =

    2

    nh  . . . (ii)

    From (i) & (ii), r =20

    22

    meZ

    hn

      Here z = 3 & m = 208 me,

     r  = 2e

    022

    em624

    hn

    ,

    (b)2

    e

    02

    2e

    022

    em

    h

    em624

    hn

        n  25

    (c) En = Total Energy = - 2220

    42

    0

    2

    hn8

    mez

    r 8

    ze

     

    =

    220

    4e

    2 h8

    em

    n

    1872 

    = - 6.13n

    18722

      eV

      E1 = -25.4 keV ; E3 = -2.8 keV& E3 - E1 = 22.6 keV .

      Required wavelength =  =E

    hc

     = 55 pm.

    Q.57.    = a(z - b)

      )bz(ac

    11

      . . . . (i)

    & )bz(ac

    22

      . . . . (ii)

    From (i) - (ii),

    21

    11c  = a(z1 - z2 )

      a = 5  107  (Hz)1/2 

    From (i) /(ii),

    bz

    bz

    2

    1

    1

    2

       b = 1.37

    Q.58. Q value of the reaction, Q = (2  4  7.06 – 7  5.6) MeVQ = 17.28 Mev

     Applying C.O.E for collision

    kp  + Q = 2 k  . . . (i)

    ppkm2  = 2 km2 cos 

     kp = 16 k  cos2  

    kp = k  ( cos  = ¼)

    Li p

     

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    Putting in (i) we getkp = Q = 17.28 MeV

    Q.59.  The quantum number of the initial state is given by n, where2

    )1n(n    = 15, i.e. n = 6

    The work function of the photo cathode (B) is given by

    E=199

    834

    106.110830

    1031063.6

    eV

    = 1.5 eV.

    The maximum velocity of the emitted photoelectrons is given by

    v =3

    2

    0

    0

    10

    107.3

    B

    E    = 3.7  105 m/s

    the kinetic energy of the fastest photoelectrons is

    Emax = 19

    25312

    106.1

    )107.3(101.9

    2

    1mv

    2

    1

    eV

    = 0.39 eVThe energy of the emitted photons is

    1.5 eV + 0.39 eV = 1.89 eVIf the atomic number of the atoms is Z, and the quantum number of the final state is m, then

    13.6 Z2  89.16

    1

    m

    122

       

      

       

    Rewriting this equation in the form:

    z =22

    22

    22

    m6

    m6

    7

    1

    6

    1

    m

    1

    6.13/89.1

     

    or, z = )m36(7

    m6

    2  

    We get by substituting possible values of m : 5, 4, 3 …… etc ; for the only possible integral value ofz.The correct values are: n = 6, m = 4 and z = 2.

    Q.60.  (a) Radius of circular path r =qB

    mk2

    qB

    mv  

    k =m2

    )rqB( 2 = 0.86 eV

    (b) E3 – E2 = 13.6 (1/22 – 1/32) = 1.9 eV

     = h - (KE)max = 1.04 eV

    (c) E = hc/ 

     =19

    348

    106.19.1

    106.6103

     = 6513 A0.

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    Q.61.  (a) The wavelength of emitted radiation is given as

    1

    = z2R

     

     

     

     

    22

    21 n

    1

    n

    for the Lithium atom z = 3

    1 = 32R

     

      

      22 4

    1

    3

    1 = 9R  

    144

     = 2.08  10-7 m(b) Relation orbit of the electron

    r =qB

    mv 

     v =m

    qBr  = 1.18  106 m/s

    KE of the electron =2

    1 mv2 = 3.96 eV

    (c) KEmax =hc  -  

      =

    hc - KEmax = 2eV

    Q.62.  a) n=4 --------------------- E4 = 1.125 eVn=3 --------------------- E3 = 2.0 eV

    n=2 --------------------- E2 = 4.5 eV

    n=1 --------------------- E1 = 18eV

    b) Excitation potential for state n = 2 is 18-4.5 = 13.5 V

    c) Energy of the electron accelerated through a potential difference of 16.2 V is 16.2eV At the most, it can excite electron fron n=1 to n=3The number of possible wavelength are 3

    22

    21

    19

    n

    1

    n

    1

    hc

    106.1181x

    For transiton 3-2, n1 =2, n2 = 3.

    32 = 4970 A

     

    For 3-1; n1 = 1;n2 =3

    31 = 777 A

     

    For 2-1;n1 = 1;n2 = 2

    21 = 920 A

     

    d) No

    The energy corresponding to  = 2000 A

     is

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    E =

    1478

    106.1102

    1031063.6hc34

     

    = 6.21 eV

    The minimum excitation energy is 13.5 eV.

    e) Minimum photoelectric wavelength is

    min = 690106.118

    hc19

       

      A

     

    Q.63.  The nucleus reaction can be written as

    n1 + C12   Be9  + He4 Q value of the reaction

    = - Tth 

    projectiletheof massetargttheof massetargttheof mass

     

    = - 6.17

    12112

    MeV

    n0Be

    He4

     

    [k1, k3, k4 [mn, mBe mHe is the kinetic energy and masses of n1, Be9, He4 then corresponding

    momentum is 1nkm2 , 3Bekm2 , 4Hekm2

    Conservation of momentum

    1nkm2  = 3Bekm2  cos   . . . (i)

    4Hekm2 = 3Bekm2 sin   . . . (ii)

    From (i) and (ii) we getmn k1 + mHe k4 = mBe k3  . . . . (iii)nn = 1 mHe = 4 mBe  = 9k1 + 4k4 = 9k3  . . . . . (iv)conservation of energyk1 + Q = k3 + k4  . . . . (v)From (iv) and (v) we get,

    9

    k4k 41   = 41 kQk    

    k4 =13

    Q9k8 1   

    = 2.2 MeV.

    Q.64. (i) E =   +2

    1 m 2maxv  

    = 1.82 + 0.73 = 2.55 eV

    (ii) En = - 2n

    6.13eV (for hydrogen atom)

      E1 = -13.6 eV, E2 = - 3.4 eV, E3 = -1.51 eV, E4 = -0.85 eV

    clearly E4 – E2 = -0.85 – (-3.4) = 2.55 eV.

    Hence quantum levels involved are 4 and 2.

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    (iii)  = n    

      

     2

    change in angular momentum = 4 - 2 

    = (4 – 2)

     

      

     

    h

    2

    (iv) If P = linear momentum, then

    P =c

    E = 1.36  10-27 kg ms-1 

    If v = recoil speed of hydrogen atom of mass M, then from COM,Mv = P

    or v =M

    P  = 0.85 ms-1.

    Q.65.  (a) For 1 = 5000 A0, E1 =

    4500

    12400hc

    1

    eV = 2.75 eV

    2 = 6000 A0 E2 =

    2

    hc

     = 2.06 eV

    and for 3 = 12000 A0 E3 = 1.03 eV

    The energy of excitation of H atom (n = 2 to n = 4)

     = 13.6  

      

     

    22 4

    1

    2

    1eV  2.55 eV

    The work function of the material = (2.75 – 2.55) eV = 0.2 eVThe maximum energy P.E.'s have energies of 2.55 eV and 2.06 – 0.2 = 1.86 eV and 1.03 – 0.2 =0.83 eV

    The de-Broglie wavelengths are9.110

    124003  A0 ,

    86.110400.123  A

    0 ,83.01000

    12400  

    or 8.99A0, 9.09 A0, 13.6 A0

    (b) All three wavelengths will cause photo emission.Number of photoelectrons /sec

    NPE = 1.44  102  

    3

    1 0.2  1  10-4 

     

      

     

      03.1106.1

    1

    06.2106.1

    1

    75.2106.1

    1191919

     

    The photocurrent = 1.74 mA

    (c) If the work function was 40 % lower, the third wavelength would also cause photoemission.The stopping potential = (2.75 - 0.2)V = 2.55 V.

    Q.66.  (a) According to the problem,  – decay is given by,92X

     A   zY

    228 +  

    i.e. 92X A   zY

    228 + 2He4 

     A = 228 + 4 = 232Z = 92 – 2 = 90 [1]  

    (b) Since  – particle moves in a circular orbit in the magnetic field

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    Bqvr 

    vm2

     

    v = m

    rqB 1.59  107 m/s [1] 

    From law of conservation of momentummv = myvy 

    Ey =y

    22

    m2

    vm   [1] 

    So the sought energy E = E + Ey 

    E =

     

    y

    2

    y

    22

    m

    m1

    2

    vm

    m

    vmvm

    2

    1  [1] 

    = 5.342 MeV = 0057.05.931

    342.5 amu

     Applying the principle of conservation of energy, mass of 92X

    232

     = my + m + 0.0057 amu= 228.03 + 4.003 + 0.0057 = 232.0387 amuSince 92X

    232 contains 92 protons and 140 neutrons , binding energy = mass defect= 92(1.008) + 140(1.009) – 232.0387

    = 1.9573 amu = 1.9573  931.5 = 1823 MeV [1] 

    Q.67.  (a)2

    2613

    n

    Z.En

     

    Excitation energy = E = E3 - E1 = -13.6  (3)2 

    22 1

    1

    3

    = +13.6 (9) [1 - 1/9] = 13.6  (9) (8/9) = 108.8 eV.

    19

    834

    106.18.108

    1031063.6

    E Δ

    hcWavelength

      = 114.3 A 

    (b) From the excited state (E3), coming back to ground state, there can be3C2  = 3 possible

    radiations.

    Q.68.  (a) If x is the difference in quantum number of the twostates

    x 12then C 6

      x = 32

    2

    z (13.6 eV)Now, we have 0.85eV ...(i)

    n

     

    2

    2

    z (13.6eV)and 0.544eV .. .(ii)

    (n 3)

     

    solving (i) and (ii) we getn = 12 and z = 3

    n+3

    n

    Smallest  

    (b) Smallest wavelength  is given byhc

    (0.85 0.544)eV

     

    Solving, we get  4052 nm.

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