ZEMAG Slagging Gasification Technology...

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ZEMAG Slagging Gasification Technology 泽玛克熔渣气化技术 ZEMAG Clean Energy Technology GmbH 德国泽玛克清洁能源技术有限公司 Ms. Fu Minyan 傅敏燕 女士 手机MP:13816767002

Transcript of ZEMAG Slagging Gasification Technology...

Page 1: ZEMAG Slagging Gasification Technology 泽玛克熔渣气化技术gasification2017.missionenergy.org/presentation/ZEMAG.pdf · 2017-12-11 · Process Design Package or Basic Engineering

ZEMAG Slagging Gasification

Technology

泽玛克熔渣气化技术

ZEMAG Clean Energy Technology GmbH

德国泽玛克清洁能源技术有限公司Ms. Fu Minyan傅敏燕 女士手机MP:13816767002

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1. Company Brief Introduction and Technology Heritage

公司简介和技术传承

2. Introduction to Zemag Slagging Gasification Technology

泽玛克熔渣气化技术的特点和优势

3. Application in the Waste Gasification in SVZ

黑水泵垃圾气化介绍

4. Application in the Gasification of High Ash content and high ash fusion point coal

高灰分含量高灰熔点煤的气化应用

5. Application in the Gasification of Bituminous coal

烟煤的气化应用

6. Application in the Gasification of Lignite coal

褐煤的气化应用

7. Development of Zemag Slagging Gasification

泽玛克熔渣气化技术的发展

Confidential Document

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Confidential Document

Company Overview

公司简介PART

ONE 1

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Confidential Document

Shanghai Zemag Mindac Machinery Equipment Co., Ltd was

established in June 2002.

上海泽玛克敏达机械设备有限公司成立于2002年6月。

Registered capital reaches 100 million RMB.

注册资金1亿人民币。

Zemag’s headquartered is located in Lujiazui, Shanghai, China

泽玛克总部位于中国上海陆家嘴金融区。

Zemag is a high-tech enterprise in Shanghai

泽玛克是上海市高新技术企业。

Zemag is also a patent pilot enterprise in Shanghai.

泽玛克也是上海专利试点企业。

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Confidential Document

2005

Purchase 收购2010

ZEMAG Clean Energy Technology GmbH

德国泽玛克清洁能源技术有限公司

Subsidiaries Dalian Zemag Automation Control Co., Ltd

子公司 大连泽玛克自动化控制有限公司

Beijing Zemag New Energy Science and Technology CO.,Ltd

北京泽玛克新能源科技有限公司

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Confidential Document

1. Technology licensor

技术许可

Zemag slagging gasification technology

泽玛克熔渣气化技术

Low rank coal, waste and biomass upgrading

低阶煤、垃圾、生物质提质

2. Equipment vendor

供应设备

Proprietary equipment

专有部件

Site service

现场服务

3. BOT of Gas Supplier 供气BOT

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Confidential Document

ZEMAG Indonesia Office

Pilot gasifier in TU

Freiberg, Germany

Shanghai

Zeitz, Germany

Beijing

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Confidential Document

Introduction to Zemag Slagging Gasification Technology

泽玛克熔渣气化技术的特点和优势

PARTTWO

2

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Research & Development

Developed by British Gas with support from Lurgi

BGL = British Gas / Lurgi

BGL技术是由英国燃气公司开发,并得到德国鲁奇公司的协助BGL = British Gas 英国燃气/ Lurgi 鲁奇

Development program 1958-2000 cost USD$ 700 million

•1958-2000 年间研发费用超过 7亿美元

Confidential Document

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Notification of the Ownership Transfer

所有权转移告知书Registration Certificate

注册证明

Confidential Document

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Confidential Document

Pilot scale slagging

gasifier (I.D. 2.3 m)

commissioned in 2006

BGL中试装置(2.3m内径)于2006年运行

Raw lignite coal feed

褐煤原煤投料

Commercial Licence

Agreement for Slagging

Gasifier Technology-

10/09/2004

液态排渣气化炉技术商业许可协议-2004年9月10日

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Confidential Document

For Licenced Plant of 200kta

Methanol Operated by

YUNNAN JIEHUA CLEAN

ENERGY DEVELOPMENT

CO.CLTD.

许可工厂:云南解化清洁能源开发有限公司年产20万吨甲醇

Located at Kaiyuan, Yunnan

地址:云南省,开远市

Dated 9th November 2010

日期:2010年11月9日

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Confidential Document

For Licenced Plant of 500kta

Methanol Operated by

YUNNAN JIEHUA CLEAN

ENERGY DEVELOPMENT

CO.CLTD.

许可工厂:云南解化清洁能源开发有限公司年产50万吨甲醇

Located at Xundian, Yunnan

地址:云南省,寻甸县

Dated 9th November 2010

日期:2010年11月9日

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Confidential Document

Dr. Michael Pritchard Dr. Andrew Williams

Dr Phil Burtonwood

Head of Gasification

Gasification expert

Principal Consultant

Lead Process and

Safety Engineer

Mr Peter-List

Chief Operator

Mr Horst-Dieter Kaprol

Process and Mechanical

Engineer

UK Team

(Design)

German Team

(Operation)

China TeamCoordinate, marketing, technical support

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Advantages of Zemag slagging Gasification Technology

泽玛克熔渣气化技术优势

Confidential Document

(1) sufficient study, huge database and rich experience in gasification

气化研发充分、庞大数据库和经验丰富

(2) wide adaptability of feedstock,easily to change feedstock on-line

原料适应范围宽、易于在线快速切换原料

(3) low CAPEX, low OPEX and low maintenance fee

投资低、运营成本低和维护成本低

(4) best solution to pulverized coal, coal water slurry, etc.

是解决粉煤、水煤浆等问题的最佳方案

(5) four “high” and one “low”

四“高”一“低”

(6) better service and good quality control for gasification plant

提供较好的服务和对气化装置具有较好的质量控制能力

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Advantages 1 sufficient study, huge database and rich experience in gasification

优势1 气化研发充分、庞大的数据库支撑和经验丰富

Confidential Document

Over 182,000 tons of all kinds coals gasified and over 14,300 hours of operating experience 研发过程中试烧超过18.2万吨的各种煤、操作时间超过14,300小时

Huge test database, complete developed design software, design manual and experience manual to provide better design and better solution to potential problems occurred 庞大的测试数据库支撑、拥有完善的设计软件、设计手册和经验手册,能够提供更好的设计,并为潜在可能发生的问题提供较好的解决方案

Fast loading change capability快速调节气化负荷

0

200

400

600

800

1000

1200

1400

1600

1800

0 2 4 6 8

Temperature

Depth from surface

Effect of Bed Height

5.5m BGL

7.5m BGL

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Advantages 2 Wide feedstock flexibility, easily to change feedstock on-line

优势2: 原料适应范围宽、易于在线快速切换原料

Confidential Document

Waste垃圾

Lignite褐煤

Sub Bituminous

次烟煤

Bituminous烟煤

Anthracite无烟煤

Petroleum Coke

石油焦

BGL

Source: adapted from Gasification Technologies

Council and commercial operation in China.

数据源:摘自气化技术委员会和中国商业运行。

Tested 测试

Demonstrated 500tpd+

超过500t/d的示范

Commercial Operation 商业运行

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Advantages 2 Wide feedstock flexibility, easily to change feedstock on-line

优势2: 原料适应范围宽、易于在线快速切换原料

Confidential Document

Non caking to strongly caking coals and/or briquettes

Ash : <37 wt%

Moisture : <50 wt%

Sulphur : < 6.0wt%

Chlorine : <0.6 wt%

Size : 6 to 80mm

Feedstock can be switched whilst on line

High Ranked

Anthracite

Bituminous

Sub Bituminous

Low Ranked Coal / Waste

High Ranked Coal

Anthracite, Bituminous, Sub

Bituminous, Lignite

Low Ranked Coal

Soft LignitePlastic Waste

Different kinds of compacted

plastic waste

Waste Wood

Contaminated wood

Briquette

Dried and briquetted

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Advantages 2 Wide feedstock flexibility, easily to change feedstock on-line

优势2: 原料适应范围宽、易于在线快速切换原料

Confidential Document

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Advantages 2 Wide feedstock flexibility, easily to change feedstock on-line

优势2: 原料适应范围宽、易于在线快速切换原料

Confidential Document

Zemag owns the material

pretreatment, low ranked coal

upgrading technology including

equipment of transportation,

crushing, screening, drying,

briquetting, etc.

泽玛克拥有物料预处理、低阶煤提质技术,包括输送、破碎、筛

分、干燥、成型等设备。

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Advantages 3 --- Low CAPEX, low OPEX and low maintenance fee

气化优势3: 投资低、运行成本低和维护成本低

Confidential Document

Low CAPEX

投资低.

Low temperature crude gas from gasifier(appr. 300-500℃)allows no

complicated equipment used to heat recovery.

气化炉出口粗煤气温度低 (约300-500℃),无需使用复杂的热回收设备

Cheaper carbon steel material is used for most equipment which is easy to

fabricated 大多数设备采用较为便宜的碳钢材料,易于制造

Low material and utility consumption 原料和公用工程消耗低High effective gas in crude gas粗煤气中有效气含量高(CO+H2>80%, CH4>7%)

high value-added byproducts (profit reduce the cost of main

product up to 15-25%)

高附加值副产品(可降低主产品的成本15-25%)

Less complicated and wearing equipment 复杂和磨损设备少Safe, long-period, full-load operation “安稳长满优”运行

Low OPEX.

运营成本低

Low Mainten

-ance fee.

维护成本低

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Advantages 4--- best solution to pulverized coal, coal water slurry, etc.

气化优势4: 是解决粉煤、水煤浆等问题的最佳方案

Confidential Document

1) Briquetting

粉煤成型

2) Zemag combined gasification technology

of lump coal and pulverized coal

泽玛克块粉一体气化技术

Lump coal

块煤

Pulverized coal /

coal water slurry

粉煤/水煤浆

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Advantages 5--- four “High” and one “low”气化优势5: 四“高”一“低”

Confidential Document

High carbon utilization (>97% for Coal to Urea).

碳利用率高 (煤制合成尿素碳利用率高于97%)

High thermal efficiency (>90%)

热效率高 (高于90%)

High cold gas efficiency ( >85%, even >93%)

High energy efficiency ( >60%, even >75% under HP gasification)

冷煤气效率高 (高于90%)

Low CO2 emission (low CO2 content in dry crude gas which less than 5% for

bituminous, CO2 can be used as purge gas, carrier gas and gasifying agent replacing

steam)

二氧化碳排放少(粗煤气中CO2含量低(烟煤气化时小于5%)、CO2可以用作吹扫气、载气

和气化剂以代替蒸汽)

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Advantages 6--- better service and good quality control for gasification plant

气化优势6: 提供较好的服务和对气化装置具有较好的质量控制能力

Confidential Document

To provide good and selectable design with gasifier pressure ranges from 25barg to 70barg

and gasifier inner diameter of 2.4m, 3.6m, 4.0m and 4.5m.

能够提供很好的可选择的设计:气化炉压力可选25-70barg,气化炉内径2.4m、3.6m、 4.0m 和4.5m.

Paid service besides technical licensing:

除技术许可外可有偿提供如下服务:

Process Design Package or Basic Engineering Package 工艺设计包或基础设计包

Site service including plant checking, start up guide of commissioning, etc

现场服务(包括装置检查、开车指导等)

Technical support including pre-quotation, reviewing of DED, operation of gasifier, etc. 技术支持(包括预询价、详设审查、气化炉运行等)

Technical training including theoretical training, operation training, jobsite training,

troubleshooting and Q & A training and practice in similar plant

技术培训(包括理论培训、操作培训、现场培训、问题查找和问答培训 以及类似装置实践培训)

Proprietary equipment including installation guide

专有部件供货(包括安装指导)

DCS configuration

DCS组态

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Confidential Document

Application in the Waste Gasification in SVZ

黑水泵垃圾气化介绍PART

THREE3

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Biomass Gasification In SVZ 黑水泵生物质气化

Client

业主 SVZ Schwarze Pumpe, Germany

Location of Facility

工厂地址: An der Alten Ziegelei, 03130 Spremberg, Brandenburg

Application Syngas for the production of Methanol/Power

应用: 合成气制甲醇/发电

Feedstock Briquetted Lignite/ Biomass/ Waste

原料: 褐煤型煤/生物质/垃圾

Gasifier One (1)

气化炉: 1台

Raw Gas Production 35,000 Nm³/h (biomass as feeding)

粗煤气产量: 35,000Nm³/h (气化原料为生物质)

Progress Gasifier running 7 year with on -line above 85%(2000-2007)

运行情况: 气化装置连续7年保持在线率达85%以上(2000-2007)

Confidential Document

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Biomass Gasification In SVZ 黑水泵生物质气化

Schwarze Pumpe, German

Coal/biomass to Methanol/Power

德国黑水泵煤/生物质生产甲醇/发电

Confidential Document

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Biomass Gasification In SVZ 黑水泵生物质气化

Gasifier 气化炉(垃圾气化):

—System data 设备参数

Diameter直径: 3.6m

Pressure压力: 25bar

Double jacket water cooled双层水夹套冷却

—Operation data 运行参数

Throughput 处理量 35 t/h

Gas quantity合成气产量 35,000 Nm3/h

Temperature 反应温度 1,600 ℃

Oxygen 耗氧量 6,000 Nm3/hr

Steam 蒸汽消耗 6-9 t/hr

Gas outlet 合成气出口温度 500-700 ℃

Operating Parameters 运行参数

Confidential Document

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Biomass Gasification In SVZ 黑水泵生物质气化

Result of biomass treatment at Schwarze Pumpe

黑水泵工厂生物质处置效果

FUEL燃料

HEATING VALUE 热值

(MJ/KG)

MOISTURE

含水量(MASS%)

ASH 灰分

(MASS %)

METHANOL OUTPUT 甲醇产量

(kg/t Waste)

REDUCED CO2EMISSIONS

CO2减排(c.f. INCINERATION)

(%)

ENERGY EFFICIEN

C能量效率

Y %

POWER SURPLU

S(MWHR)

Used Plastics塑料废料

33.7 1.5 7.8 596 32 47.5 0.23

Contaminated Wood

木材废料

16.8 1 11 357 34 50.4 0.21

Domestic Waste

生活垃圾(RDF)

18 4.5 20 392 31.5 46.6 0.23

Shredded Material碎料

11 7.5 43.8 211 24 38 0.04

Sewage Sludge污泥

11 8 43.5 160 21 35 0.03

Confidential Document

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Biomass Gasification In SVZ 黑水泵生物质气化

Gas Composition 气体组分

Items

项目Unit

单位Fixed Bed Slagging Gasifier

固定床熔渣气化炉

Operation with high waste

addings

气化大掺量垃圾时

Operation with coal (start up)

气化煤(开车)

H2 Vol, -% 18.0 28.0

CO Vol, -% 33.5 56.0

CO2 Vol, -% 16.0 2.8

CH4 Vol, -% 18 6.0

N2 Vol, -% 10 6.0

O2 Vol, -% 0.3 0.1

C2H6 Vol, -% 2.2 0.4

C2H4 Vol, -% 0.6 0.1

C3H8 Vol, -% 0.3 <0.05

C3H6 Vol, -% 0.4 <0.05

i-C4H10 Vol, -% <0.05 <0.01

N-C4H10 Vol, -% <0.05 <0.01

H2S Vol, -% 0.2 0.3

BTEX-Flavours Vol, -% 0.5 0.3

Density 密度 Kg/Nm3 1.1 0.9

Calorific Value 热值 MJ/Nm3 15.8 13.0

Confidential Document

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Biomass Gasification In SVZ 黑水泵生物质气化

Waste materials processed at SVZ From 2000.06 to 2007.05

黑水泵工厂处理的废弃物量(2000年6月至2007年5月)

Solids 固态

Used plastics 塑料废弃物 900,000 t

Sewage sludge 污泥 120,000 t

Contaminated wood 木材废料 225,000 t

Treated domestic waste (RDF)

生活垃圾二次燃料295,000 t

Pellets from tar and sewage sludge

污泥和焦油渣造球160,000 t

Shredder residue 碎料 20,000 t

Others 其它 95,000 t

Fluids 液态

Contaminated oils, Oil-/water mixtures

Mixtures from solvents

废油,含油污水

1,300,000 t

Confidential Document

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Confidential Document

Application in the Gasification of High Ash content and high ash fusion point coal

高灰分含量高灰熔点煤的气化应用

PARTFOUR

4

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Client Longmei Tiantai

客户 龙煤天泰

Application Syngas for the production of 300,000 t/yr Methanol Synthesis

应用 为年产30万吨合成甲醇提供合成气

Feedstock Lump Coal 原料 块煤

Gasifiers Two (3) gasifiers, 2 operating, 1 spare气化炉数 2开1备, 共3台气化炉

Capacity Raw gas production 84,375 Nm³/h for 2 gasifiers设计能力 2台气化炉的粗煤气产量84,375 Nm³/h

Domestic Reference Plants——LMTT龙煤天泰业绩工厂

Confidential Document

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Domestic Reference Plants——LMTT龙煤天泰业绩工厂

Gasification Constructure in LMTT

龙煤气化框架

Confidential Document

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Domestic Reference Plants——LMTT龙煤天泰业绩工厂

High ash content and high ash fusion point coal gasification

高灰高灰熔点煤气化

Ash(dry basis): 21%~31%,up to 38%

灰分(干基):21%~31%,甚至高达38%

Ash Fusion Temperature: >1500℃灰熔点:高于1500℃

Ash Composition,%

灰组成,%

SiO2 Al2O3 Fe2O3 CaO MgO TiO2 K2O

66.03 20.28 2.75 2.88 0.98 1.23 1.62

Confidential Document

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Domestic Reference Plants——LMTT龙煤天泰业绩工厂

Unit单位Design Value

设计值Coal Throughput 投煤量 kg/h 34600

O2 Flowate 氧气流量 Nm3/h 10200

Steam Flowrate 蒸汽流量 kg/h 9500

Product Gas(dry)粗煤气(干基) Nm3/h 49933

Gas Temperature 气体温度 ℃ 170

Gas Pressure 气体压力 barg 38

Gas Composition气体组成 mol%

CO2 5.67

CO 58.9

H2 25.54

CH4 8.56

Effective gas 有效气 Nm3/h 42450

Methane 甲烷 Nm3/h 4274

Coal Consumption 耗煤量kg/kNm3(CO+H2) 853

kg/kNm3(CO+H2+4CH4) 581

Oxygen Consumption耗氧量Nm3/kNm3(CO+H2) 252

Nm3/kNm3(CO+H2+4CH4) 171

Steam Consumption蒸汽用量kg/kNm3(CO+H2) 234

kg/kNm3(CO+H2+4CH4) 160

Confidential Document

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Domestic Reference Plants——LMTT龙煤天泰业绩工厂

1)Successfully gasify coal with high ash content and high ash fusion

and can run for a long time.

成功气化高灰高灰熔点煤,并可以长时间运行。

2)High value by-products, tar, oil and methane, are produced

successfully.

成功产出焦油、中油、甲烷等高经济价值副产品。

3)Low consumption of materials as coal, oxygen and steam.

原料消耗少,如煤耗低、氧耗低和蒸汽耗量小。

Confidential Document

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Confidential Document

Application in the Gasification of Bituminous coal

烟煤的气化应用PARTFIVE

5

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Client China Coal

客户 中煤

Location of Facility Tuke, Inner Mongolia, P.R. China工厂位置 中国内蒙古 图克

Application Syngas for the production of 1,000,000 t/year Ammonia (1,700,000 t/year Urea)(first stage)

应用 为年产100万吨合成氨(170万吨尿素)提供合成气(一期)

Feedstock Lump Coal (bituminous) 原料 块煤(烟煤)

Gasifiers Seven (7) gasifiers, 5 operating, 2 spare气化炉数 5开2备, 共7台炉

Capacity Raw gas production 295,000 Nm³/h for 5 gasifiers生产能力 5台气化炉的粗煤气产量295,000 Nm³/h

Domestic Reference Plants——China Coal中煤业绩工厂

Confidential Document

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Photo of China Coal Gasification Plant

中煤气化装置照片

Domestic Reference Plants——China Coal中煤业绩工厂

Confidential Document

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Visit of Indonesia Representitive Group

印尼代表团参观

Domestic Reference Plants——China Coal中煤业绩工厂

Confidential Document

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Domestic Reference Plants——China Coal中煤业绩工厂

Items

内容Units

单位Design Value

设计值

Performance Test

Value

性能考核值

Mt,ar

全水分(收到基)% 8.74 11.64

A,ar

灰份(收到基)% 9.1 5.16

V,ar

挥发份(收到基)% 28.31 30.46

FC,ar

固定碳(收到基)% 53.85 52.74

ST 软化温度 ℃ 1118-1500 1167

LHV 低位热值 MJ/kg 25.33 26.38

Carbon 碳 % 82.3 76.84

Hydrogen 氢 % 4.8 3.08

Nitrogen 氮 % 1.14 0.92

Design and Running Coal Specification

设计和实际运行煤质

Confidential Document

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Domestic Reference Plants——China Coal中煤业绩工厂

Design and Perf. Test Parameters

设计和性能考核参数

Confidential Document

Item s U nit D esign Perf. Test

Coal feed kg/h 42160 42270

O 2 feed N m 3/h 14090 12521

Steam feed kg/h 13450 14023

Crude gas N m 3/h 70560 72870

Tem p. of crude gas ℃ 170 180

Press. O f crude gas barg 38 37.07

Com position of curde gas m ol%

CO 2 4.77 4.19

CO 57.52 59.24

H 2 26.02 27.31

CH 4 8.14 7.47

effective gas (CO + H 2) N m 3/h 59140 63069

effective gas (CO + H 2+ 4CH 4)N m 3/h 82116 84841

kg/kN m 3(CO + H 2) 750 681

kg/kN m 3(CO + H 2+ 4CH 4) 513 498

kg/kN m 3(CO + H 2) 675 613

kg/kN m 3(CO + H 2+ 4CH 4) 486 456

N m 3/kN m 3(CO + H 2+ 4CH 4) 172 148

N m 3/kN m 3(CO + H 2) 251 199

kg/kN m 3(CO + H 2+ 4CH 4) 164 165

kg/kN m 3(CO + H 2) 241 220

Carbon residue % < 1 < 1

Cold gas efficiency % > 90 > 93

Coal consum ption

O 2 consum ption

Steam consum ption

stand coal consum ption

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Domestic Reference Plants——China Coal中煤业绩工厂

1)Gasifier was successful in feeding coal and ignition on December 31,

2013, with the first running period more than 60 days

气化炉2013年12月31日一次投煤点火成功,首次运行超过60天

2)Single gasifier continuous operation lasted more than 218 days,

multiple gasifiers co-production can meet “stability and often

excellent” requirement. 单台气化炉连续运行超过218天,多台联产满足“安稳长满优”的需要;

3) Less water consumption, low steam to oxygen ratio, high steam

decomposition rate, less phenolic wastewater.

耗水少、汽氧比低、蒸汽分解率高,产生含酚废水较少的优势;

4)multiple successful cold standby start-up without emptying the

gasifier.

多次不挖炉成功冷备开车。

Confidential Document

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Domestic Reference Plants——China Coal中煤业绩工厂

5)Successfully passed the gasification performance test in December 2015.

2015年12月成功通过气化性能考核测试;

6)During gasification, economic advantages of pyrolytic by-products such

as methane, naphtha, middle oil, tar and crude phenol can be obtained

with higher added value which put the effective utilization of coal into true.

在气化过程中,可获得更高附加值的甲烷、石脑油、中油、焦油、粗酚等干馏副产物的经济优势;实现了煤的有效梯级利用。

7) After treated, waste water approaches to no drainage.

废水经处理后达到零排放。

8)For its second phase, another 6 Zemag slagging gasifiers will be used

to provide syngas for 1,000,000 t/y methanol plant.

二期100万吨甲醇项目继续使用6台泽玛克熔渣气化炉。

Confidential Document

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Confidential Document

Application in the Gasification of Lignite coal

褐煤的气化应用PART

SIX6

Page 47: ZEMAG Slagging Gasification Technology 泽玛克熔渣气化技术gasification2017.missionenergy.org/presentation/ZEMAG.pdf · 2017-12-11 · Process Design Package or Basic Engineering

Domestic Reference Plants——New Gold 金新业绩工厂

Client Hulunbeier New Gold

客户 呼伦贝尔金新

Location of Facility Hailar, Inner Mongolia, P.R. China工厂位置 中国内蒙古 海拉尔

Application Syngas for the production of 500,000 t/year应用 Ammonia (800,000 t/year Urea)

为年产50万吨合成氨(80万吨尿素)提供合成气

Feedstock Briquetted Lignite/ Lump Coal原料 褐煤型煤/褐煤块煤

Gasifiers Three (3) gasifiers, 2 operating, 1 spare气化炉数 2开1备,共3台气化炉

Design Capacity Effective gas(CO+H2) production 119,000 Nm³/h设计能力 有效气产量119,000 Nm³/h

Confidential Document

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Design Coal and Running Coal 设计煤质与运行煤质

Items Unit 单位 Briquette型煤 Raw Lignite褐煤原煤

M 水分 ar, % 6.9 32.8

A 灰分 ar, % 33.95 25.26

V 挥发分 ar, % 13.31 10.02

FC 固定碳 ar, % 45.84 31.91

C daf, %wt 73.52 -

H daf, %wt 5.17 -

O daf, %wt 19.75 -

N daf, %wt 1.13 -

S St,d %wt 0.43 0.27

LHV 低位热值 ar, MJ/kg 14.32 15.51

注:设计以型煤为原料,实际运行以褐煤原煤入炉。

Domestic Reference Plants——New Gold 金新业绩工厂

Confidential Document

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Design and Operating Parameters 设计与运行参数

Items

Unit

单位

Briquette

型煤Raw Lignite

褐煤原煤

Coal Throughput 投煤量 t/d 1244 1059

Limestone 石灰石 t/d 73.92 73.87

Oxygen Consumption氧耗 Nm3/h 13649 7500

Steam Consumption 蒸汽耗 kg/h 13050 8560

CO+H2 有效气量 Nm3/h 59659 32514

Gas Composition 粗煤气组成(dry, mol%)

CO % 52.0 39.2

H2 % 26.5 32.3

CO2 % 8.2 15.5

CH4 % 8.2 6.6

Slag 渣量 t/h 6.9 4.6

Domestic Reference Plants——New Gold 金新业绩工厂

Confidential Document

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Domestic Reference Plants——New Gold 金新业绩工厂

1) Gasifier running more than150 days continuously.

气化炉连续运行超过150天

2) Startup from cold standby successfully without emptying gasifier.

实现不挖炉冷备开车

3) Successfully commissioning with Chinese hard lignite briquettes

成功用中国硬褐煤开车

4) Continuously make gas more than 280 days by BGL.

连续制气超过280天

5) BGL has much lower CAPEX and OPEX with value-added byproducts.

能够产生高附加值的副产品,有更低的投资和运行成本

Confidential Document

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Confidential Document

Development of Zemag Slagging Gasification

泽玛克熔渣气化技术的发展PART

SEVEN7

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Development of ZEMAG Slagging Gasification Technology

泽玛克熔渣气化技术的发展

Direction 1: ZEMAG Combined Gasifier of Lump Coal and Pulverized

Coal

方向一:泽玛克块粉一体气化炉

To feed Lump Coal to the top of gasifier and to inject pulverized Fine coal or

Water Coal Slurry to the combustion zone through different tuyere?

将块煤从气化炉顶部送入,而将粉煤或水煤浆通过不同类型的喷嘴喷入气化炉的燃烧区

Direction 2 : ZEMAG High-tar-yield Devolatilisation-gasification Combined

Gasifier

方向二: 泽玛克高产油干馏气化一体气化炉

Increase the tar production while gasifying high oil content coals by all kinds of

methods

当气化油含量高的煤种时,通过各种方法提高焦油产率。

Confidential Document

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How to deal with Imbalance of Fine/Lump coals?(coal mine

production: 20-40% lump coal and 80-60% fine coal)

如何解决块粉不平衡的问题(煤矿产块20-40%,粉80-60%)?

How to deal with dusty tar in fixed bed?waste water ?

如何解决固定床中的含尘焦油?废水呢?

ZEMAG Combined Gasifier of Lump Coal and Pulverized Coal

泽玛克块粉一体气化炉

Confidential Document

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Solution to above problems:

解决以上问题的方法:

1. To briquette the pulverized fine coal and gasify the briquettes and lump

coal

粉煤成型,气化型煤和块煤。

2. To inject fine coal directly trough injection tuyere into Zemag Fixed Bed

Slagging Gasifier

在泽玛克固定床熔渣气化炉中通过喷嘴喷入粉煤气化。

ZEMAG Combined Gasifier of Lump Coal and Pulverized Coal

泽玛克块粉一体气化炉

Confidential Document

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ZEMAG Combined Gasifier of Lump Coal and Pulverized Coal

泽玛克块粉一体气化炉

Pulverized Coal/ Water

Coal Slurry 粉煤/水煤浆

To feed to the top of Zemag Gasifier

型煤和块煤从气化炉顶部进入

Briquetting/ Lump

Coal

粉煤成型/块煤

To inject through tuyeres into the

gasification & combustion zone

together with steam/O2

与蒸氧一起通过喷嘴喷入气化区和燃烧区

Confidential Document

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ZEMAG Combined Gasifier of Lump Coal and Pulverized Coal

泽玛克块粉一体气化炉

Pulverized Coal/Water Coal

Slurry through Injection Tuyeres

通过喷射喷嘴喷入粉煤/水煤浆

Lump Coal / Flux

块煤/助熔剂

Confidential Document

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ZEMAG Combined Gasifier of Lump Coal and Fine Coal

泽玛克块粉一体气化炉

Conclusions

结论(1) to utilize the coal resource mostly and have the ability to deal with

various issues including imbalance of lump and fine coals, waste water,

dusty tar, and so on.

最大程度地利用煤炭资源;能够处理块粉平衡、废水、含尘焦油等问题。

(2) to make the gasifier available to Lump coal and pulverized coal/

water coal slurry lump coal by self balance through different tuyeres

可以通过不同的喷嘴喷入粉煤或水煤浆的方式,自平衡气化块煤和粉煤或块煤和水煤浆。

Confidential Document

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ZEMAG Combined Gasifier of Lump Coal and Fine Coal

泽玛克块粉一体气化炉

Confidential Document

Decrease in coal

throughput and tar/oil

production,increase

in effective gas

投煤量减少、焦油/油产量减少;有效气增加

lum p

100%

lum p+ PF

70%:30%Total Coal throughput (t/day ar) 1011 955Lump Coal fed to locks (t/day ar) 1011 668Coal fed to tuyeres (t/day ar) 286

Crude G as Production Rate (N m 3/hr, dry) 70790 67653

Cold G as Efficiency (%) 89.9 89

Crude G as Com position (m ol%, dry):

N itrogen 2.40 3.49

Carbon dioxide 4.77 5.87

Carbon m onoxide 57.52 55.29

H ydrogen 26.02 29.43

M ethane 8.14 5.08

H 2S, CO S and CS2 0.27 0.31

CxH y 0.85 0.49

N H 3, H Cl and H CN 0.01 0.03

Total 100 100

N et By-products (kg/hr):

O il 530 149

BTX 309 244

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How to get more tar from oil rich coal?(Oil content > 5%)

如何能够从富含油的煤中获得更多的焦油?(油含量>5%)

◦ Solutions to this Task:

解决上述问题:

1. Design with Increase in the height of coal bed

提高煤床层高度

2. Revamp the top of gasifier

改造气化炉上部

ZEMAG High-tar-yield Devolatilisation-gasification Combined Gasifier

泽玛克高产油干馏气化一体气化炉

Confidential Document

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ZEMAG High-tar-yield Devolatilisation-gasification Combined Gasifier

泽玛克高产油干馏气化一体气化炉

Revamp the

top portion of

gasifier

改造气化上部

Increase the retention time

and improve the counter-

current heat exchange

增加干馏的停留时间和逆流换热效果

Increase the

bed height

增加床层高度

Change the gas distribution

and countercurrent heat

exchange into intermittent

heat exchange

改善气流分布,变逆流换热为间接换热

Confidential Document

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ZEMAG High-tar-yield Devolatilisation-gasification Combined Gasifier

泽玛克高产油干馏气化一体气化炉

Confidential Document

Vertical cross-section of semi-coking zone

半焦区的垂直截面图

Revamp the top portion of gasifier to change

the gas produced in gasification and

combustion zones.

改造气化炉上部以改变气化区和燃烧区产生的气流分布The gas is separated into two streams: the

one goes up along the central chamber to the

hot gas outlet and the other goes through the

cold fuel bed then leaves from the cold gas

outlet.

气流分为两股:一股向上经过中央室,由高温粗煤气出口排出;另一股向上流经冷的燃料床层,然后由低温粗煤气出口排出。

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ZEMAG High-tar-yield Devolatilisation-gasification Combined Gasifier

泽玛克高产油干馏气化一体气化炉

Confidential Document

Horizontal cross -section of semi-coking zone

半焦区的水平截面图

Hot Gas

高温粗煤气

Cold Gas up and fuel down

冷粗煤气上升,燃料下降

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Development of ZEMAG Slagging Gasification Technology

泽玛克熔渣气化技术的发展

Conclusions

结论

For Solution 1: it can increase the tar/oil yield to 55-70%

percent to some extent.

方法1: 能够一定程度上提高到煤含油量的55-70%;

For Solution 2: change the gas distribution, maintain the high

throughput of processed solid material and can reach higher

process thermal efficiency with tar/oil yield up to 80%.

方法2: 改变气流分布,维持固体物料的处理能力,可以达到更高的热效率,焦油/油产率高达80%。

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