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SAFETY DATA SHEETAccording to COMMISSION REGULATION (EU) No 453/2010

FH RABEKO Warszawa

SPRAY PAINT

Printing date: 19.05.2011 Revision: 08.08.2014 Page: 1/9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

SPRAY PAINT1.2. Relevant identified uses of the substance or mixture and uses advised against

A hand-held pre-pressurized aerosol.

1.3 Details of the supplier of the safety data sheet FH RABEKOul. Rzeczna 603-794 Warszawa, Polandtel/fax: +48 22 6799961email: [email protected]

1.4. Emergency telephone number+ (48-22) 425 43 03 w godz. 8.oo – 17.oo

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)Flam. Aerosol 1 - Flammable aerosols, Hazard Category 1 H222 Flammable aerosols, Hazard Category 1 H229 Pressurised container: May burst if heated.Eye Irrit. 2 - Serious eye damage/eye irritation, Hazard Category 2 H319 Causes serious eye irritation.STOT SE 3 - Specific target organ toxicity – Single exposure, Hazard Category 3, Narcosis H336 May cause drowsiness or dizziness.Aquatic Chronic 3 - Hazardous to the aquatic environment – Chronic Hazard, Category 3 H412 Harmful to aquatic life with long lasting effects.

Classification according to 1999/45/EWG (DPD)F+ EXTREMELY FLAMMABLE R 12 - Extremely flammable. R 18 - In use, may form flammable/explosive vapour-air mixture. Xi IRRITANT R 36 - Irritating to eyes.R 66 - Repeated exposure may cause skin dryness or cracking.R 67 - Vapours may cause drowsiness and dizziness. R 52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

2.2. Label elements Labeling according to Regulation (EC) No 1272/2008 (CLP)

Pictograms

GHS02 GHS07 Signal word DANGERHazard Statement:H222 Extremely flammable aerosol. H229 Pressurised container: May burst if heated.

mailto:[email protected]


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H319 Causes serious eye irritation.H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects.

Precautionary Statement - P-phrases: GeneralP102 Keep out of reach of children. PreventionP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition

sources. No smoking. P211 Do not spray on an open flame or other ignition source.P251 Do not pierce or burn, even after use. P261 Avoid breathing gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. ResponseP305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing.P312 Call a POISON CENTER/doctor/…/if you feel unwell.StorageP405 Store locked up.P410 + P412 Protect from sunlight. Do no expose to temperatures exceeding

50°C/122°F.RemovalP501 Dispose of contents/container to an authorized company.

Complementary informationEUH066 - Repeated exposure may cause skin dryness or cracking.

Volatile organic compound (VOC): ~82%2.3. Other hazards

Results of PBT and vPvB assessmentPBT: Not applicable.vPvB: Not applicable

SECTION 3: Composition/information on ingredients

3.2. Mixtures Chemical nature: Mixture of resins, solvents and propellent.

Name of substance Identifier Classification67/548/EWG

Classification1272/2008

% weight

2-butoxyethanol Index 603-014-00-0CAS 111-76-2EC 203-905-0

Xn; R20/21/22Xi; R36/38

Acute Tox. 4

Acute Tox. 4

Acute Tox. 4

Eye Irrit. 2

Skin Irrit. 2

H332H312H302H319H315

1 -< 4

propan-2-ol Index 603-117-00-0CAS 67-63-0

F; R11Xi; R36

Flam. Liq. 2 H225 H319

2 -< 4


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EC 200-661-7 R67 Eye Irrit. 2

STOT SE 3

H336

acetone Index 606-001-00-8CAS 67-64-1EC 200-662-2

F; R11Xi; R36R66R67

Flam. Liq. 2Eye Irrit. 2STOT SE 3

H225H319H336

7 -< 14

ethyl acetate Index 607-022-00-5CAS 141-78-6EC 205-500-4

F; R11Xi; R36R66-67

Flam. Liq. 2

Eye Irrit. 2

STOT SE 3 EUH066

H225 H319 H336

7 -< 13

n-butyl acetate Index 607-025-00-1CAS 123-86-4EC 204-658-1

R10R66R67

Flam. Liq. 3

STOT SE 3 EUH066

H226 H336

8 -< 14

dimethyl carbonate Index 607-013-00-6CAS 616-38-6EC 210-478-4

F; R11 Flam. Liq. 2 H225 16-< 26

Solvent naphtha (petroleum), light arom. (contains <0,1 % benzene)

Index 649-267-00-0CAS 64742-95-6EC 265-192-2

R10Xi; R37Xn; R65R66R67N; R51/53

Flam. Liq. 3 Asp. Tox 1 STOT SE 3 STOT SE 3 Aquatic Chronic 2 EUH066

H226 H304 H336H335 H411

10-<18

dimethyl ether Index 603-019-00-8 CAS 115-10-6EC 204-065-8

F+; R12-18 Flam. Gas 1 Press. Gas

H220 25-<35

The meaning of risk phrases is given in section 16.

SECTION 4: First aid measures

4.1. Description of first aid measuresInhalation: Immediately leave the contaminated area; take deep breaths of fresh air If the person breathe large amount of vapours, the exposed person on fresh air. Seek medical advice.

Ingestion: If victim is conscious and alert, give 2-3 glasses of water to drink. Do not induce vomiting. Seek immediate medical advice.

Eye contact: Immediately flush eyes with large amounts of water for at least 15 minutes while holding the

eyelids open to ensure that the entire surface is flushed. Do not put any ointments, oils or medication.

Seek medical advice.Skin contact: Immediately wash with water and soap and rinse thoroughly. Wash contaminated clothing before

reuse. If irritation persists, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayedCARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.

4.3. Indication of any immediate medical attention and special treatment needed


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No additional information available.

SECTION 5: Firefighting measures

5.1. Extinguishing media CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

5.2. Special hazards arising from the substance or mixture In case of fire, the following can be released:Carbon oxides (CO + CO2) Protective equipment: High temperatures may cause pressure build-up in closed containers.During the thermal decomposition produced of harmful compounds.Reduce vapour with water spray. Explosive mixture: The mixture formulated explosive mixture with air.

5.3. Advice for firefighters As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Clothing resistant to high temperatures.Independent self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresKeep away any ignition source.Wear protective equipment. Keep unprotected persons away.If vapours / aerosols are formed, use personal protective equipment. In use, may form flammable/explosive vapour-air mixture.

6.2. Environmental precautions Do not allow product to reach sewage system or any water course.Prevent seepage into sewage system, workpits and cellars.Inform respective authorities in case of seepage into water course or sewage system.

6.3. Methods and material for containment and cleaning up Collect the liquid with vacuum in a suitable container and absorb the remaider with a porous material(diatomite, acid binders, universal binders, etc).Ensure adequate ventilation.Dispose contaminated material as waste according to item 13.

6.4. Reference to other sections See Section 7 for information on safe handling.See Section 8 for information on personal protectionSee Section 13 for disposal information.

SECTION 7: Handling and storage

7.1. Precautions for safe handling Handle carefully. In general handling aerosols should not be considered as hazardous.

7.2. Conditions for safe storage, including any incompatibilities Always store aerosols away from sources of heat, including direct sunlight and in dry conditions.Avoid extremes of temperature and moisture. A stable, cool, dry ambient environment is most suitable. Avoidcontamination with other products.The containers will not last indefinitely even when stored in a cool dry area, they should be inspectedperiodically during long-term storage.Note container warnings.

7.3. Specific end use(s)


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No data.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Supplier recommends 600 ppm total hydrocarbon based on composition.

8.2. Exposure controls As with all aerosols, the products should only be used in well ventilated areas, but responsible use is not potentially harmful.Personal protective equipment: -General protective and hygienic measures:Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the skin.

Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Protection of hands:The selected protective gloves have to satisfy the specifications of EU Directive89/689/EEC and the standard EN 374 derived from it. Material of glovesButyl rubber.The glove material has to be impermeable and resistant to the product.Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.Eye protection: Chemical safety goggles.Body protection: Impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

SECTION 9: Physical and chemical properties


FH RABEKO Warszawa

SPRAY PAINT


9.1. Information on basic physical and chemical properties Appearance: Fluid (paint) in aerosol.Colour: No data.Odour: Characteristic.pH: Not applicable.Melting point/freezing point: <-20oCInitial boiling point and boiling range: >65oCFlash point; 0oC Upper/lower flammability or explosive limits:

No data.

Vapour pressure: No data.Relative density: 1,03 g/cm3

Solubility: Not water soluble. Re-dispersible in aromatic solvents or ketones.

Partition coefficient: n-octanol/water; No data.Auto-ignition temperature; Unknown for blend.Decomposition temperature; No data.Viscosity: No data.Explosive properties: None.Oxidising properties: None.

9.2. Other informationNo data.

SECTION 10: Stability and reactivity

10.1. ReactivityNot reactive if used according to specifications.

10.2. Chemical stabilityUnder normal storage and use of the substance is chemically stable.

10.3. Possibility of hazardous reactionsThe mixture formulated explosive mixture with air.

10.4. Conditions to avoidExtremes of temperature, including direct sunlight and extreme freezing. Avoid exposure to moisture. Which may damage container deterioration and PH, where acidity may damage container integrity. Avoid sudden impacts, which may damage container integrity.Container corrosion may occur with time and damaged containers should be disposed of before any danger is evident.

10.5. Incompatible materialsAvoid contact with water, acids, high temperatures.

10.6. Hazardous decomposition productsCarbon monoxide, Carbon dioxide.

SECTION 11: Toxicological information

11.1. Information on toxicological effects DME The Occupational Exposure Standard is 550ppm(1310mgm)Used correctly in aerosol form. All components can be considered to have a low order of toxicity (LD50 oral rat 500mg/kg,skin 3000mg/kg).deliberate inhalation may cause severe pulmonary and breathing difficulty, dizziness, drowsiness(narcosis) and headaches (but this is unlikely in normal usage) and would constitute abuse.Primary irritant effecton the skin: Repeated exposure may cause skin dryness or cracking. on the eyes: Irritating to eyes. ingestion:


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gastrointestinal disturbance.inhalation: Vapours may cause drowsiness and dizziness. sensitization: no data.Delayed and chronic effects: Danger of serious damage to health by prolonged exposure. Cancirogencity: Not available.Mutagenicity: Not available.Reproductive toxicity: Not available.Narcosis: Not available.

SECTION 12: Ecological information

12.1. ToxicityToxicity to fish: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Toxicity to daphnia and other aquatic invertebrates:No data.

12.2. Persistence and degradabilityDegradation will be relatively slow though ultimately almost complete.

12.3. Bioaccumulative potentialAccumulation is unlikely once physical breakdown commences.

12.4. Mobility in soil Mobility will be very slow.

12.5. Results of PBT and vPvB assessmentNo data.

12.6. Other adverse effectsShort and long term effects should not be considered significant. Very short term damage to aquatic and soil organisms may occur in large spillage (1000+containers) though this should disperse quickly (especially if absorbent material is used).

SECTION 13: Disposal considerations

13.1. Waste treatment methods Product:RecommendationMust not be disposed together with household garbage. Do not allow product to reach sewage system.Reutilise if possible or contact a waste processors for recycling or safe disposal.Waste disposal key:The European Union does not establish uniform rules for the disposal of chemical waste, which are special waste. Their treatment and elimination of the domestic legislation of each country. So, in each case, you should contact the relevant authorities, or those companies legally authorized for elimination of waste. 2001/573/EC: Council Decision of 23 July 2001 amending the list of wastes contained in Decision 2000/532/EC.Council Directive 91/156/EEC of 18 March 1991 amending Directive 75/442/EEC on waste.Uncleaned packaging:The containers and packing materials contaminated with dangerous substances or preparations, have the same treatment products.Directive 94/62/EC of the European Parliament and the Council of 20 December 1994 on packaging and packaging waste.Recommendation:Disposal must be made according to official regulations.Packagings that may not be cleansed are to be disposed of in the same manner as the product.Wash with solvents to be incinerated.


FH RABEKO Warszawa

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SECTION 14: Transport information

ADR/RID IMGD IATA14.1. UN number 1950 1950 195014.2. UN proper shipping name AEROSOLS, flammable14.3. Transport hazard class(es) 2 2 2

Hazard label 2.1

14.4. Packing group III III III14.5. Environmental hazards --- --- ---14.6. Special precautions for user Not applicable.14.7. Transport in bulk according to Annex II

of MARPOL73/78 and the IBC Code Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulation (EC) No 1272/2008 (CLP) of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (REACH).

REGULATION (EC) No 1907/2006 OF THE COUNCIL of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC.

COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)

COMMISSION DIRECTIVE 2013/10/EU of 19 March 2013 amending Council Directive 75/324/EEC on the approximation of the laws of the Member States relating to aerosol dispensers in order to adapt its labelling provisions to Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures

15.2. Chemical safety assessment A Chemical Safety Assessment has been carried out for this substance/mixture.

SECTION 16: Other information

The meaning of risk phrases from sections: 3H220 Extremely flammable gas.H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour.H302 Harmful if swallowed.H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation.H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects.


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R 10 Flammable.R 11 Highly flammable.R 12 Extremely flammable.R 18 In use, may form flammable/explosive vapour-air mixture.R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.R 36 Irritating to eyes.R 36/38 Irritating to eyes and skin.R 37 Irritating to respiratory system.R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R 65 Harmful: may cause lung damage if swallowed.R 66 Repeated exposure may cause skin dryness or cracking.R 67 Vapours may cause drowsiness and dizziness.This information is based on the present state of our knowledge, they are no assurance of product features and shall not establish a contractual relationship.• Abbreviations and Acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage ofDangerous Goods by Road)RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)ICAO: International Civil Aviation OrganizationICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)PP: Severe Marine PollutantGHS: Globally Harmonized System of Classification and Labelling of ChemicalsEINECS: European Inventory of Existing Commercial Chemical SubstancesCAS: Chemical Abstracts Service (division of the American Chemical Society)Note to readersThe information in this SDS is based on our current knowledge and the current legislation. The product shall not, without first obtaining written Instructions for purposes other than those mentioned in Section 1 purpose be used. It is always the user's responsibility to ensure compliance with statutoryProvisions to ensure. The information in this Safety Data Sheet describing the safety requirements for our product. Safety data sheet was prepared by:Przedsiębiorstwo Ekos S.C. 80-244 Gdańsk, Ul. Grunwaldzka 205/209,Web: ekos.gda.pl

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