MK-CHEMICALS EEC - SAFETY DATA SHEET - EBORX · MK-CHEMICALS Chemia specjalistyczna EEC - SAFETY...

MK-CHEMICALS Chemia specjalistyczna

EEC - SAFETY DATA SHEET acc. 1907/2006/EG

Date/Revised: 04.08.09 Printing date: 04.08.09

„MK-CHEMICALS” Marcin Kolis; 50-122 Wrocław; ul. Szewska 8 NIP: 988-018-26-69 REGON: 932952503

Tel.: +48 71 319 88 99; +48 39 916 65 70 Fax.: +48 71 722 01 10; e-mail: [email protected] ING Bank Śląski o/Wrocław; ul. Szewska 72; 50-122 Wrocław – Konto nr: 52 1050 1575 1000 0022 7642 0417

1. Substance/preparation, and company name

Trade name: Termsol EKO Antifreeze Liquid

Use: Heat transfer fluid for thermal solar systems

Company: MK-CHEMICALS Marcin Kolis

Ul. Szewska 8

50-122 Wrocław

Tel.: +48 71 319 88 99

Fax.: +48 71 722 01 10

E-Mail: [email protected]

Emergency information: 998 from land line, 112 or closest National Fire Department Station.

Toxicological information in Poland 0-10xx-42 631 47 24

2. Hazard identification

No particular hazards known.

3. Composition/information on ingredients

Chemical nature:

Chemical name 1,2- propanediol, propylene glycol up to the 50

% of weight

Global formula C3H8O2

Mol mass 76,1

Name in accordance with UE Directives Propylene glycol

CAS 57-55-6

WE 200-338-0

Classification Not applicable

Chemical name Corrosion inhibitor concentrate up to the 10 %

of weight

Global formula Mixture

Classification Xn, R 22, R 63, R 52/53

Mixture ingredient

Ethano-1,2-diol, ethylene glycol Concentration up to 35%

CAS 107-21-1

Index number 603-027-00-1

EINECS 203-473-3

Classification Xn, R 22

2-Etylohexanian potassium Concentration up to 45%

CAS 3164-85-0

Index number ----------------------

EINECS 221-625-7

Classification Xn , R 63

Metyl-1H-benzothiazole Concentration up to 3%

CAS 29385-43-1

Index number ----------------------

EINECS 249-596-6

Classification Xn , R 22 , R 52/53

mailto:[email protected]






Chemical name Tri-ethylamine, Tri(2-hydroxythelo)

amine

up to the 1%

of weight

Global formula C6H15NO3

Mol mass 149,2

CAS 102-71-6

WE 203-049-8

Classification R36/38

The product contains a biostatic – active compounds: the mixture of 5-chlorine-2-methyl-

2H-Izotiazolin-3-onu (Number WE 247-500-7) and 2-methylo-2H-Izothiazolin-3-onu (WE

number 220-239-6)(3:1) index number 613-167-00-5 ;T, R23/24/25, C ,R34,R43,N ,R50-

53 as well as 2-bromo-2-nitroprophano-1,3 diol (WE number 200-143-0) Xn ,R 21/22 , Xi,

R 37/38-41 ,N ,R50

The remaining ingredients are not classified as dangerous considering their specification

or border concentrations.

4. First aid measures

General advice: Remove contaminated clothing.

If inhaled: If difficulties occur after vapour/aerosol has

been inhaled, remove to fresh air and seek medical attention.

On skin contact: Wash thoroughly with soap and water.

On contact with eyes: Wash affected eyes for at least 15 minutes under running

water with eyelids held open.

On ingestion: Rinse mouth and then drink plenty of water.

Note to physician: Symptomatic treatment (decontamination, vital functions),

no known specific antidote.

5. Fire fighting measures

Suitable extinguishing media: The product is non-flammable. Water spray, alcohol-resistant

foam, dry extinguishers, and carbon dioxide (CO2) are suitable

for extinguishing environmental fire.

Specific hazards: Evolution of fumes/fog. The substances/groups of substances

mentioned can be released in case of fire.

Special protective equipment: In case of fire, wear a self contained breathing apparatus.

Further information: The degree of risk is governed by the burning substance

and the fire conditions. Contaminated extinguishing water

must be disposed of in accordance with official regulations.

6. Accidental release measures

Personal precautions: No specific measures necessary.

Environmental pre- Contain contaminated water/fire fighting water. Do not dis-

cautions: charge into natural waters without pretreatment (biological

treatment plant).

Methods for cleaning For large amounts: Pump off product. For residues: Bind the

up / taking up: liquid by using a suitable absorbent material and dispose of

in accordance with the regulations. Wash away spills tho-

roughly with large quantities of water. In case of release of

larger quantities which might flow into the draining system






or waters, contact appropriate authorities.

7. Handling and storage

Handling: No specific measures necessary.

Protection against No specific measures necessary.

fire and explosion:

Storage: Containers should be stored tightly sealed in a dry place.

Storage in galvanized containers is not recommended.

8. Exposure controls and personal protection

Respiratory Protection: Respiratory protection in case of release of fumes/fog.

Hand protection: hemical resistant protective gloves (EN 374). Recommended:

nitrile rubber, protective index 6. Manufacturers directions for

use should be observed because of great diversity of types.

Eye protection: Safety glasses with side-shields (frame goggles, EN 166)

General safety and The usual precautions for the handling of chemicals must

hygiene measures: be observed.

9. Physical and chemical properties

Appearance A clear, transparent liquid

Colour Depending on the version green or red

Odour Odourless

pH 7,5 - 9,5

Boiling temperature for version-




ok. 104,0 C

ok. 105,0 C

ok. 106,0 C

ok. 108,0 C

Self ignition temperature (glycol) >

Critical temperature (glycol) 500 -

Crystallisation temperature for concentration

33%


38%


42%


52%

-

-

-

-

Explosion borders (glycol) Lower: 2,4% , upper: 17,4%






-

-

-

-

1.030 ± 0,005 g/cm3

1.033 ± 0,005 g/cm3

1.037 ± 0,005 g/cm3

1.040 ± 0,005 g/cm3

Water solubility Complete

10. Stability and reactivity

Substances to avoid: Powerful oxidizing agents.

Hazardous reactions: No hazardous reactions if stored and handled as prescribed.

Hazardous decomposition No hazardous decomposition products if stored and handled

products: as prescribed.

11. Toxicological data

LD50/oral/rat: >2000 mg/kg

Primary skin irritation/rabbit: non-irritant (OECD Guideline 404)

Primary irritation of the mucous membrane/rabbit: non-irritant (OECD Guideline 405)

Additional Information: The product has not been tested. The statement has been

derived from the properties of the individual components.

12. Ecological data

Ecotoxicity: Toxicity to fish: Leuciscus idus/LC50 (96 h): >100 mg/l

Aquatic invertebrates: EC50 (48 h): 100 mg/l

Aquatic plants: EC50 (72 h): >100 mg/l

Microorganisms/effect on activated sludge: DEV-L2>1000

mg/l

Inhibition of degradation activity in activated sludge is not to

be anticipated during correct introduction of low

concentrations.

Assessment of aquatic The product has not been tested. The statement has been

toxicity: derived from the properties of the individual components.

Persistence and Elimination information:

degradability: Test method: OECD 301A (new version)

Method of analysis: DOC reduction

Degree of elimination: >70 %

Evaluation: Readily biodegradable.

13. Disposal considerations

The product must be dumped or incinerated in accordance with local regulations.

Contaminated Uncontaminated packs can be re-used. Packs that cannot

packaging: be cleaned should be disposed of in the same manner as

the contents.

14. Transport information

Not classified as hazardous under transport regulations.

(ADR RID ADNR IMDG/GGVSee ICAO/IATA)






15. Regulatory information

Regulations of the European union (Labelling) / National legislation / Regulations:

Directive 1999/45/EEC („Preparation Directive“): Not subject to labelling.

Other Regulations: None.

16. Further Information

Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3: Xi:

irritant. R36: Irritant to eyes.

Vertical lines in the left hand margin indicate an amendment from the previous version.

This safety data sheet is intended to provide information and recommendations as to: 1. how

to handle chemical substances and preparations in accordance with the essential requirements of

safety precautions and physical, toxicological, and ecological data. 2. how to handle,

store, use, and transport them safely.

No liability for damage occured in connection with the use of this information or with the use,

application, adaption, or processing of the products here described will be accepted. An exception will

be made in the case that our legal representatives should come to be held responsible and liable by

reason of intent or gross negligence. No liability will be accepted for damage indirectly incured.

We provide this information and data according to our present level of knowledge and experience. No

assurances concerning the chararacteristics of our product are hereby furnished.

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