IFTETITOYTO TE{}AOrIKQN tg KAI METAAAEYTIKf,TN …iftetitoyto te{}aorikqn kai metaaaeytikf,tn...

IFTETITOYTO TE{}AOrIKQNKAI METAAAEYTIKf,TN EPEYNf,TNN.rr,I.A. EtrOIITEYOMENO AIrO TO ]TlOr?rErO ANAXTYSEE (X.X2f76'MEEOIEION 70. 1 15 2? A9HNA - TH'1. 210 7l gB 412 - 7. FAX 2t 0 77 5? Al I

tg}Jglirxr

ffir:*tuR;;;ffi

TOIiEAI YAATIKOH NOPCIN & NEPIBANAOilTOIAIEYoYNIH YAPOTTOAONAT

ANATNOPIITIKHYAPOTEONOTIKH - YAPOXHMIKH EPEYNA

NOIOIIKHI ENIBAPYNIHI TNN YNOTETNN NEPNNTIII EYPYTEPHT NEPIOXHT

THE AEKANHE TOY AIONOY N. BOIfiTIAI

n. nANltoYnonoY^orfSpoyecoA6fog (M.Sc, Ph.D)

ErrrornqoJm6< f, ovsovdtrn( z E. fKI NT{rlI H, X4yt x6g M41gaw rc6E

AOflvotSeSpoudprog 2008

t.28341Y2062

INETITOYTO TE$AOTIKf,TNKAI METAAAEYTIKAN EPEYNANN.II.T.A. ETIOfITEYOMENO ATIO TO YNO\'PNEIO ANAflT}'EHE (N. 272N6)sr!El9lTl !?f{r0,1152?AoHN4, 412-LrALz1a??52n1

TOMEAI YAATIKOH NOPON & NEPIBA/\AONTOIAIEYoYNIH YAPOTENAOTIAI

ANATNCIPIITIKHYAPOTEQAOTIKH YAPOXHf' l lKH EPEYNA

NOIOTIKHI ENIBAPYNIHI TfiH YNOTEIOH NEPQNTHI EYPYTEPHI NEPIOXHI

THI AEKANHT TOY AIfINOY N. BOIOTIAI

N. flANNOYNONOVAOTYdpoyecoioyog (M.Sc, ?h.Dt

Enrornuovrroc f uvgov{iln( : E. I-ltl NT{IN H, Xqp xag M4Slavtxog

AOrlvoOeBpouriprog 20O8

Jgfl#F.Dd,.os.ogdlvn

,;;.f;;,--;:.-:r;

12834 / Y2062

rIINAKAZ IIEPIEXOMENAN i T*

l. ErxArQrH ...............2

- . 1 . I . I o t opm6 ' ' . . ' . ' . . . . ; . . . . . . . . . . . ' . . . . ' ' ' . . . ' ' :

1.2 Me0o6oLoli* 6peuvaq- ...........31.3 Eulaprorteq .., . . . . . . . . . . . . . . . . . . . .4

2. IE(,,-',\OI-IKEI * YAPOI.EQ^OI-IKEE EYNOHKSE ".,........ ....".....5

2.1 fear?'crytrfq -.u6pol"r$oloyrr6q ouv&r;rceq.-........ ..... ....."............52.2 Y8poyeoloyrrdg <rur.Sqxeq - u6potp6por opf(rm€q............... ............,........12

2.2.1 Y$porpopor opi(ovreq ... . . . . . . . . . . . . . . l2?..2.2 Kivqcq rou utdyerouvspo0 .......14

, 2.7.3 Y8poi 'oyrrr i ozoryei*.qqnsproppq.... . .-. . .-. .-. . . . . . . . .". . . . . . . . ."17?.3 lrorleic ro.Iurpqg ?r19.... . . . . . . . . . . . . . . . . . . . .20

3 YOIE"TAMF,NIJ KATATTAE}I TIE NOIOTFITAX TAN YNOTEIQN NEPSTN ..,,..".......22

3.1 Airruo efu6ygori - pe0o6o1cn1irx............... .....,........223.2 Arorel€otrrcr$ Kfl,r ene{egyooi* rcov Xqprrrirv avsifoerov ......28

3.2.1 Xqpu<€g avakiaeig.. .............-.....283.2.2 Karavopfl tCIv rfprcov rdwalv..,..... .........-...,.283.2.3 Kcmvoprj r6)v r1voororgsirrrv........ ....."..........4O

3.3 Entor6rnlarl - A[roi,fyla1 n1g nopouaiog torr Cr oru undyeia vcp6............................513.3.1 fevrrd quo'u(o1qFtrd lcrporcrqprorrr* ror Cr.-...... ........-513.3.2 fhOaveg ruqyfs C(III) rar C(VD srrlv n€plolirl ....,.."......-56

4. AAIO^OTF|IH TSIN XpirrEfiN TOY NEI'ily ......_.".... ". .......,...5q

4.1. Y$peunr'{ rcurn},},q},6qr{r............... ......,..............594.2 Ap$eutrx4 xutnli4),r1cnrfi.,........... ....-..."..."..........59

5. E1'MnEPAXMATA - nPOTAXErt . ............ .........-....64

5.1 Xupnepdtoporfl....,,........ .....645.2 llpordcsrg. ..-...69

5.2.1 M6rpa np6trr1yq6 rar elfgotr ...................^,..695"2.L flporew6pevrq €pstrvlnr6q egyatiisq.........-"...-.. "...,,."""....69

BIBAIOTPAOTKEX ANA$OPEX ... . . . . . . . . . . . . . . . . .". . . . . . . . . . . .". . . . .72

IIAPAPTHMA l; Enrlepsvot l*preg x),. 1:5O.000

i: l

1. EIEATOTH1.1 lorapmdH atrporiac dpruva eqopd cirrl Dupeurrlo4 ?T16 uqrctdpn'q-< ruruoroorlq p!'&ovonq Kor orf,

udpoxlprxd xopfir(lljplctrrc 'rurv undyetcrv vepirtv rrlq errptnep'rr1q rc€pto{rlg qq }-ercavlq Tol)

Aororot n*'rupori Nopori Botc:rioE. O Aoarnoq, cto pr-yalrSrepo rpdpu tou, Stappder reprcrytl

rou N. Borartiag g,r,,{b ro v6Tro xct s.varo;trrd rou rp{trra uxoorpayyt{et rq Boperoavtrtohx6q

ano)'d{eq qq ll&pvr10a6 or onoieq unore'Loiru F6poq ror-r Nopot Arnrqq (Mo}*rr6.ou, Auhdlo,

Qpoaoq rl,n )

Irq orev4 ,'*:ptop €pnrvaq Kol oul.tcel(pr;r*rra orrp neprag{ A*}"dr.'-aq - Otvorp0rov - Ow6qg -

Eplpurnpiou uvuarfo$arsr svrovq $roprlywx{ Ku1 $wreXvutj Slruarqpt*rqrs rl oxois

rrlrncrdwetut etnb ayponrfq exerioetq uryqi,r1q nopaycrrprdtqrflg. ,:,). ,i . i

O roaap6g Aaon6q r.rr,69 trw oppptoiv u6drorv etvar oqp/* uno66rcrqq, r6rc{repcr aro trtfco pcnt,

l"upo.ro:v rcrr u.vpci:v (xno$)trlraw norri}jqq c,iot<roqg r.:o.t rpoglsu,3qq. H ff0ouc[s ogyflv(t)fttvaiv

povdOaw arxi'rqpanrrlg ene{etrrynoiag uypdru uroBl,{tcw rar BroprqXtrvmi*v }"up&ttirv an6 rqv

twptoyl, oe cruvdtocpd pe n€ oup6q waqopdg rov rc,roircct-rv po Eu0eorl uno$Lr1rr'lv unnr9ekrg

orqv rcoicq relu A$t*xrof rcuOrirg Kor E{tJv au(qpr;vcrx o-tr6wrpcboeruv per*}Jrnrv rou

rrpocriircpiorrlK$v t;r Fspov{op€vsq 6eryparo},qvt6g Dm<p6po>v qop€cov rcct t8w;rrirv, npctr6},ruocv

ro e.vSraq6pov rqg aol"rreio4 Tro plfi exter'f,orepq €.peuva rot unoqfaaroq rqg upm-r*pffqg

rccr0orao'qg prinovoqq rov uaoysial vapdw rrlg euprnep4q rsprc1.f16. To w8roqdpov r(ov

ronrrd:v nopoydvrotv rco0{oq Kfll rou n}nou eortdort1xe rurnpTpfv, oe uu(qp.ertcg firyKsvrprircreq

r$vrcr:v Xporpir.m, rptoOevrnig (Cri') rur e{oc0evor)g (Cr6*), or onoieg oe npro;r*ve6 repurrri:ac4

ump6$*rvcrv Ksl rft 6pra noorp6?qroq ro:v 50 pg/l.

To I|ME r*q upp6$roq <pop6nq r:r1; acirteiuq T1o rrlv Eperwa'rcrv unrrJeir*v vepd:v rqg XCopoq,

Sra$6'rovrug cqv e(er8metpevrl Tv/*oq, qv telwr{ uao8opri Kfl,r'nTV no}.u0eponrr1 nlqporp6prloq

aa6 qv pnrpfupovq epneptu roo os avdirliyq ror en6iecq avaidycrrv epyuauinr, xar p*&" axd

to *6nptpov Tretl a($r;itt;ot ry At$*ttvm1 Y\atav nu YilEX{}A}I, 'mpo6$q cr4v acpor'loa

Avtryvoptarrr{'Epeuvo nrJu onooKoaei orqv psl€Tq rov fiororrrrilv 5rprlrtrlpro,mri:v Knr rqg

utprcrup6vrlq rat&orucqq p{rnavoqq rcov unoleirov vepdrrv qg eup0tepqg mpwlrgq Kui orllv

8rapopeparl nporccretov yro rllv ireport6pol €pewu Ker owrpetConcq rou fipopl{F.cttCIq.

Awrreipevo qg nopofoaq fpeuvaq oe yevmfq ypapp6g f1cuv,

--;*i;-.:'':--' .. . -:it .*-..,

- tl dnqpeqjfl t><pwwp.""^asv o4ltdav ldr.aoq (yeorrpiclrq, EpF'a*) aryv tttp'6ttp4 rcpnxr1 rcat

i optilrdq etoE 6rxr{tou yeoipr1omtv \eryparc}*1wiae xat ilbiyou'

4 r.aproypdEryfirl rtl; ritrj(ostr,xp[aq (m6,gpryg] rusv woyei*tv ttpiov 6nou aztrd ipav 6vvm6,

q Kertrlpc(pr1 *at o.rcoris?ttLtfi| rrnv yta)oytxtitr* xat t:6ftoitgo]-ayxav f.apCI$ivlptdttrcd;v rTe

wpbttprlq neP wYriq *'6 w.qti;P awe g,

- r1 anoritnotrrf toJv- rn'yrnxpcisot&)v ni]v lti:tott' wt6q tt: udp*E'ptttv ttxtlymwptv Ktil TTq

e,- Tgttt:t xumvoyftq rcuq fxo xCIJpa,

4 d;WA4r1 r1jtrcdg 6r.6eor1E pe ta aacntMoltt'rd' rcor) enotovirv, cqv epptTv9ta tollq Kdt r4r)

utrtt^ovt,q "4;

rrpr*o4rtiqE rc*raaffia'* Ke1,q rcat tpor&oe$ yt& lcsp(lntpat qytxo{t:g rwt

iaw lt€xplliu i6yxor', npowuoias q / rcar qnorcot&moo4g tou xpofi)"q$ew;

Esrfv 6r0eor1 fiou arol,ouQet cn'oluirowut 6re{o6rx6 xu' yeal}"opx& KOI uEpc'ryaclloyx&

xu,poKrqprcftrxd rqq neprqgrlE ruodlg e?tisq,; KOt ro anote?rfcpnto qq uvrrr6p&) flvotryoJploruqg

6parvcrg. Ilo.pouotft{ovtat rut ctf,tol"ayoirwut tu uno1e}"S6portr to:r' y"qptrthv cvaiiroec'rv rut

aapnrtBr.wat npor*.ceig Tlo rep*ttipar epynote6 rapoxoloir0lclq r.qq pfnavolq KoL

ouyrarprpu*veq Ep6oar6 rat trr€epo ctnorotdotaoqg Kor rposrnoiag rox ulidyerrlv vepdl rqq

rueptoplg

1.2 l*tflodoAaYis tPeuvugor epeuvqttx€g upyuo'irg rippaw ro No€pppto rou ?00?, nepard$qrav to oeppou&pro rou ?008

rur Sqpraouv o.w,oirrcf rprl{ qp6po}.o1aro66 piveq. Appn6 r:rryrsvrpdo0tK0rt K([1 un€orqou'v

eae{epyc.ciu 6tro r$ Strl${;orpo orotlei.g a:t6 *polyodpeva6 pei'^*reg ror €peuveq' rcrt dircltepc

sut6 agu aqoporSv oe npoqyofu.sveq epY{roieq rcu II'ME rca0dlg rur sutd 146 El}"ryltrtiq rar

Are$voirq Br$tr.crypaqieq. Errl oweleta pet* uad wuy'*toptonx{ erdoxergq crrlv 7t€pt61{

eml,flrqrcuv ot neptol€q ndrrrpripor"io6 Kil't opirr4re $iKcuo yetltpflasorv Kst rppeft(nv

Eeirpu,tolqryiftq <crr e)"€ry1Au. To ev6taq6pov nppr* nrc*cevrprir€rlKs {ttTl $r'crp4xavrrq {dlvq

owOrpmr.,rv - ow6t1q - )Jplparuptou uild orrl auvfleru pet& urc6 uvt<pop66 Tr'a crulqpfueg

orlxevrprboerg e[go$evori-c lpcrlpiau oe napgretpeveg nspol€g err6q c4q u$poi''o1rrrlq i"rr&vqq

roo Aorr:rror3 4 6per-rvu encrt&oqrs KCt nvccol,txdcepa anryr errp0repq uDpcryear)'rryrrt'1 l"exfvtl

mrc reptq66q ArrLi$cq - A{1}"eor'

Aro ng epluaisq unoi$p,ru ouyxevrpa$qxuv cruvol.irri 8? seiryputu v€po$. Tu neproodttpu un6

aurri *dp$rlrav trrc6 lecr:rpflonq evdr cXdgraroq crprOpgq Eerypd'ta* nttp0qre un6 <pgr*trta'

E)"r1q$qoar, €TrisTlq rur r€ooepu, Eeiypuza vepod ard rov Aocrlr6 norup<i' E*ioqq 6nou rltuv

6uvaco, KOr Olyyt(sKfJrir.,h,fl eret ,5no1 endrpsrcav T0 Kd,f,0$Ksr:sfirrt1 Xg'porTrtplo&rcd Tcov

uSpvyeolrprjoecov (rnpoucio me(operpmou oolflva), ?rprryporosot{Oqrcv Kdt petp{oerg

md$pqg rcrrv un&yeuov vepdrrv.

Es 6rr aqopri oru nou>rtrcd 1opoKrqprortrd, perprl0r6av smtdnou {pCIslKoll1rrr6q nupdperpot

6ntoq rl Hl,errpmrl Ayaiyrudrrlta (EC) rou vepo6, ro pH, r'1 Oeppcrrpaolu Kcr to Auvoprr6

Ofi,edouvayffiq {&e}

Ta 6eiypura aurti o"tii).4-1{ivxsv rur cnoori}.iwruv uuSqpepciv c'ro F,pyuotfpto Avohurnc4g

Xqpduq rotr lfME yw apoo6roptop6 guorKolrltuKdrv rcpapfrpol (EC pl'i), ruplcr t6vtal (Cc,

Mg, Na, R, C0, HCOj, SO, Ct), punr:vrrr<irv Eetrrdrv (NOs, NOt, NH4) xa0doq rcut ntrrlOcirpag

eirrifey;revalv rlvaorar;eic:v (Cr,o,,, Cr6*,Fe, At, Ni, Mn, Cw ZrL Ba, Cd, Pb, As, Co, Hg, Li, Sr, Ag, Mo,

S&, Se, Be, V, Tl, P, B, SiO2) tsut Olrxag Opyrn"rcdg Av*paxa; ?i "TOC".

Tu pslpt rCopa 6ra06orpa orotle{,u ru0Cog Krlr n} anora}"6oparo, rov ;rltrnridrv ar,'ul*$err}v

ou,'rrevtp6tlqK$v Kol un*orrloav otrffri$l a{o}dyqoq rcur en{,epyaaia. Itu ezrdptuvo reg{rio-ru

avnl"*svrur 6u{o6rrn or r:rnpfpou6 eplaaicq roOd:q Kor rri unom}.6<r;raru n1q znpo{oug €peuvctg,

TAIog n*pudOeirrur eperrr4rrrig rporuosr4 K(n orlyKsKprpcva p€rpn awryetritznoqq rrlq

impcrtepru unoprl0ploqg rqq not6rr6oq ralv ryndryeralv vr:pCov Kur rrlq qr.rou<{q rot rcrdotccnlg.

t.3 EuyapwriegEtriv oloxlflproorl r{q napo$aaq fpewag a(rdloytl flrav q oupBot{ orryrerprtr#vrrrv

anonlpfvo:v Kot owspTrltriiv ororg onoioug amOrfuolrar trJv unolpfaloq vu €l(tppc$6i rtg

euXnprcrieq pou, l6tair€psq sulir.ptodeg app6(ouv.

o Iro fevirS Aiau$urnrl rou II'ME rs0. ,4. fmtpyaxoxodo ytu qv apfptcq unoorlp{t'1

rou arqv il]qp{rro8drqoq Kst srqv anp6arocq olarcffiparq rqq nupotloaq tpnwcg

. Ero Ateu*uvrr1 qq Amffluvorlq YEpoyerirl.oy{ng rc. N. KougttrtoisA,rl, Tro fl}' awa}"lny{

andyearv Kqt nq,p{otpeg sroqyfloerq tou Kot{r tq ,niwcr{r1 rqg pni,stqg

. Itrl pppxd rou I|ME xa. EL {rcnravq Tro rrl Sre(uyaryq rruv plpxrix uval,rioecnv

r Etou! epvo8qyairq toii II}{E KK. K. A. K*AAtotz(q rat H. Norco Tro rqv np60upq rat

enrpelll ouvepluoiu rooq o'rq c,"uiioyq crriv 6erypa?{ov K{rl Tqv fipoTporonoiqcrl rov

trre rprlc srov unoiOpou.

4

2, TEOAOTIKEE - YAPOTEONOTIKEE EYNOHKEE2.1 t-twAaytKi; - udpoAt0oltoytxig ouv04xegH euptlr$pn iceptop! ev8tag€,povrog n'rriooerct yeo.nextonr& orqv [te?'u1ovrm1 el6qm

(flanuvrro).dou, 1986, K.0.). Aoptitat sno norriLtq l"r0a1'<r11x6q evdtqteq ot ozcoieq

mpri"apBdvoriv t(ftpc,tfl rou Tetopto,revorSq. tou Neoye;v'otlq (Av. Merdrcuwo) w6 ro u}'nttd

CItloflOgpo gvt&ocste 6rqv wdtqco fqq llsLoyowrrlq. I'fl.q en$trr'eveq napalpritoouq

rcrpoucndf,owat ava?rurtKd ot Lt0ootparpatorypuqmoi sxrlprrncpoi nou ouppst$trow oq

yr:roi,'6yrxri 111q $opq 6ncig urxoi snsnrnrirvovrsl ot ap6orpcr,eq rcaetir6 ril rrnl,stdraptq dpeweq

tou I;ME (f{tpyrv6q r.n. 2007, T{rto.pqq K.a... 1970, K$tom*tooq 2000, 2002, Ketflii{itcoq K-s"

19g6, Ao,uvaq lg7li evd) n xuravopfl rouq, oro ldrpo nupourn&(erur oT o Dplpa l. H raollo'rx{

neprlpaql exfiotqq ?"r0ol,oyucr1q ev6cqrrlg *ruhouseita.r an6 rqv u8pohoo?'oytrrl rqq

oupnryrqopd 6na4 urn{ nporrlaret qr6 Dre{o8txdq €pa-uve-C tcro II-ME tcou EpoY1lfira:rnrd$qruv

oro nupel,oirv ocqv supinap4 nepr<r4{ i.Aowuq r.u 1980, Mtlprprlq, i995)'

Tnag*ya$E:

O)ireanvn: Atarpivetat cre ernyfpouq s1nt^roTrcpcn4 &nrrlE tril'auprar6g ano06cete @'al)

orryx1rovor anp&rnar cr{q1rsrlopoi dgrrrw, 0wtirv tar riirg tevayov its.,sl,s),- np6oqrata aoirv6eta

upyrJ,oupgtrfrq rar apliioplyfl ulrxdl trrr rpr:xdl,e-C rur tr*r0neq nciri)'qg ofcruo-r1g rcut ;rc'y60oug

{H.sI) xa$coq rat ra}uato[ rut vf,or rriwot roprltrr&tolv rm a]spprrd |(opqtlfi?o {O'cs,sc)'

Eivrxt 2,tt,rsti adpcmtparoi asgrlpa;rtapoi pt eiaipeory u.s )amopepets apyiLweq svmpr[soe(' Ee

ywtxi:E yp1ftpt€ uvanrtsooow eku#tpouq urSpotpbpouq a{ti{owee 's"}.)rt oe p*pmhg raptwatosg

)-oyw rrlg xopryBoA4qct*v apyfuucdv evmptbotav avdl$u66owar ronrc8.wt6 riwy udparpapieq-

Illnmdravo {.Pt} llcpr},ap$&ver ramav6lprupa r{{pntu, nol} e.rr{xeiltfrt ot ofi)[rq(']\'t& 7t&v&)

srrq uflotctiip.sveg Avrrr-MelorCI.11'ffi6q tnoOdoerq. lrrp nepr,opl El4pntapiOu - Ouorp*t*:v

uirom')"nfv.rm rg6 lr4 <nryexrir& rporn).o**yd1 ro$ wslldcaovrur f"rs o.no06oeq,

xc.oravogrcopolv *ppov l6ut firll"Cov. Eqv reptqfl rqq Prt<icirvag anoreloriwst ctr6 ouverntor5g

ndyrouq rcporca?.olanrnorayrirv pe nprl,oyupprtnc6 auvSetrr6 rrix6. To suvoltr6 n*1o6 tot:

oplpanapori eivol 120-150 p€rpa'

Xap,xKfilpi{ow&t eq ilipentparoi iaq 4pmtparci sNrl!}4tl54oi- H rry*rdr4eL ntsE no*lliet

av*toya W W h1oloywq ratsq o$ocao4 Kat ro noooctd o"vtiqrtqq mtv )etwroptpioepax Edatuv

{I apo uotnio*v aofi*etg aipo rpo p ieq

Neayevtq

Ot cXqpcrnopot ror' Neoyuvcxiq ovqrotn' cle$ov 4' ohorl,4pou oro Av. Medrcuwo.

Arccpopoaorsrivrni aad neprofi cre neprold avri.loy* p€ rqv roao$eciia Kcfr fi'l Lt0c)'oprt1 rott6

rniornorl orrE ar6l"outleE evdtqteq:

Iforapoyepoa{e€ s.sof;tritt; ffiproptl€ At(}sat - Ao},i&ae (&fs.e) K*ru}.ap$&vow oi,,6KLqpq qv

ncpm1{ ano n1v Aui,t$a dc4 rrlv aeproXJr f,}prrrnoir - Maproicoriltru. Aroreloi}v rqv nlsupxfl

Kfl,r nlv npog ro rc*vr:ri pr;rdpaoq ro:v uuoxe{pwa:v papyti-rv rcar prrpyo1x{uv ucpeo'ro}"i$t*v.

Xuvirrrsvrat crn6 xporolocayrl, prKpqg rar paydrl,rlg nrvemu&rqroq fioD evsl.l,dooovrot lre

r4rup4-riceg K(r.r K{rcrrni€p0porq nq?*rfq rat apyi}CIr6. Or rpox&}'eg etvot nr'0parcrrf1q, rlratrrpttrxqq

tl rqlqnKqq o'uo?ssq€, 61ouv norrii,o peye0oq pe apyr.1"rr6, q:a.ppntx6 { rpoxoloryaptprnr6

ouv$enrd ui,Lrd rar npofplovrut sno ro npo -NeoTevEq r:n6Bc0po q6 lldpwl$cq ra$dlg rur cnd

F€rcpopgalpfr,'o ltmprirporo Kfir paOritepa p6lr1 trrw Necryevrix. To n&1og mu <rplponopot5

mripXemr repinou cs 300 p+:rprr-

Mritp$q. t*,pytkn, rryho{, rcporcd,kE xat *ppat rtpwplq Zylpuraptoo - Qwotprirav, {Ms,m,l).

Tct $nOutepc p*hq rr,u qlqp{Erropof atror5 cnotelofvrc,r ard *Lurrir$er'; p6pTsg, appotiloug

14l,o69 rar l,erff& ctpdopuru apyi)"a:v. EwS_c zr':v sno06oeorv arvrdlv avcrrulOr;ncv xorT6opc'rc

l,ryltrdlv. H 'l$*Icr"prq

ofat*oq ro:v crprrrpdr(r)1' rrrrrbv rcr-rmtl.at u,nd nepto;6ri cs nept*1fi.

B0pera ror Xp1;r*rnpioo, perapnivouv fipog rc n&vtn oe trn'6tr-sure$ teqpfg p*pyeq nou

eval1fi,$'oowar trrs nrll,o0leq pdpy€q, uptrrcrulouq fiIfor4, nL.crio8s4 pa;ryaixotiq nqiiteg. rc*r

<ptrltfub8aq Fipyeq.

Aurrndtepu rorr Eplparupiou, perupuivcuv ss uno06oriq fiou o'uvisrflvrnr ar6 wailaytg

TaJapdv rporcikov p dycpoos (Ms.c,l) ew6g rrw onoir*v nupeppriliownt nqlodlsg -

up"plodleq evcrpdla'eq. Etqv ncpiopl rcw Olo<prlr6)v, vsnoovucolmd qg neptqrlg 6nou

urorcailfrrero,r ro ov0pamrd unoBo0po snavroirv ra Ba0rirepo, p6l.r1 rcov nlfilftorrcpcbv nou

onorel.i:futcn ulr6 evu.)"kryfq rcporul"ottuy{il" rF*vrKrrxriw upyitrtn' nu.t rr1}.d*v fHs.f,c}. To x*.1o9

rou tixqptltrap:ir oto o'{rvo}.6 rou etvul rqq rfriqq ririv 500-600 pltpov

Mapyawct aof*ordltilot (Ms,mk.tv): Eprpuvi(ovtor ouvri0a;q cre poppt gaxtxr8rbv wotpCooearv

flrtt er'cerap,avr*v opr(dwatv nti16oug ano Liyc 6r.119 xar neproo$repo *ndr 100;rftpn.

,*rl;rliffi

\*i't '

,l,ri;^-i;

|eailaywdg Xaprq; qE np{xtp7E nepny1E QbvAeoa and ytw}.oywat:S X6.pttg 6rc6ew7S .il'ME}, fiI. Xdpr7 I

7

Pd'r:

l-trt ;q \ , t u ,

; l 6 t ^ " t iQ x r . p t ,li c' r"* 1

o FF-+J { * j. - r r f n t t,,!o + r'4, ,Z , \ , , J :

L - Q r : * i..j \j^/ r

lt, l-t ".t i

='. ar Frr-{ r-- '{:.: i' . . , - . ; - .M )

i. '*' lr'l ID * - :*', rat I':t ,:I ] (

450000

I2g{Fa 1.

[:,r.-',-,. "rr r3;11liJfm iH.c$.sci. nisuprK(i r<op{illsiq {or r0rrur xopr;priruv. OA4rqryo

FIfi *r.s,1. ncru'trr,rtro cpptrocyptir&1 (& ttfryrAopyrt ultrd. O]rda<ravo

-j ig.uf l. nuaupraxtg a;lo&iorq " IlpoopiraerE. O,\oRcrw

[--l lpq, fiorcpogepoaieg uno€ioug. fiAerryr6xsnlo. flAeIoi6lccnv.l'/lsoycvig

lfl! fuu.rl. fioraroxepcadeg cno8forrq rrepropig A4l,ro - Auii6aq, Av. tileroanrvo

i-l tMt.m,f;. Mdpgeg, apyrLor, n4r\oi <poxcleE,6ppor nepqrlg llq1lorspiiou - Orrrorgrlnriv. Av. M:rfi<crw-

-l (nrs.nt). llndpyeg neprolriE luxupivou. Av. Mfld(awo

f]] #*s.sc"pri). M{tpyEE, dpyrAoi, rl:oppireg, d;ryoi ror xpoxdArg. Arr. Mer$x. - Kur, l'lie?6xarvo

i-: {Ms.nrk,rv}. Mopluiroi, rFcF€p?r'roa0ri{ ospuor6i0or. A.,,. lr4n6rorw

ffi iMs.c,sli. Irilaryer* <pcroionuyriv, ,.irupyrrrirv, pqpytilv rcr rpugpriv nqArirv. Ar. Meloxorrro€v<irqra flaAayawxrlg

*._l tist. <DAuoyqq. Av. Mororpdxrro - IluAqrdrsrvo

ff 6;-t.t;. Ao$cor*tu€<:r. Kp4rr6rce

f tre.ru+. :rOnflcuratuocxo rorr$ogmo- Kprlr$rd

f tol.Fioqr{ unapgcorxrr;vncrpu4xi:rrru. Av. loupoorxd - Kqr. ?{pqn6n<6

I io.k). Aoprcrrenao,t n[Auyov|xiE [vr6( r{r}v og!o[ig{iv. Av- toupaorxd - Kcr. Kp{r}&(d

l_ I ilirn,shi" A€toxrroi cXrlpcropcs ew6g sxrsrs#otrirroK€pffoir6lrqE 6dnA{aq(. Tprqiltd - Atdon

I pim.f;. npVrAoppl$tsri rnirg.irpa:a ' Ilroroqcpliiror*parcfudrq Srfni*o11. Tpr*i5r*d - Arrloro

:.'.,'ji] pr-m.try, 1699o ew*g qrcrowFiflIor€parotuA*dq SdTrl6o{S. Tprr&r6 - Arrloao; i.*-i 1t'm .li.t4. eopa'6f€or, doiotrrn(oi sogor6tu0or xcr lroAoyiraq. M. Tgrcllrxo ' M. Ano*

w! {c-P-Ti. AeviAxoi o;por6,\€or xo rgaF}ireg. A€o\8par(W6po - i ldppro

I tc-r-r.r.l.Arrgpd(lKoirxn$arcproievr6ErarvfloAuro(rxrirvolqFcnoiltr)v nalaro{,r*o

Ev&ducon (tbvn

t--]j 6s.n".*;. oruopa6aiE oyr;panopoi. Av. Kg1n6*6

Efipa 2" Yrcdpvr1pa feailryrcctit Xapq QXqpa I)

MaAyEE ,ttptopl€ Eorcagfuou, (fufs.m). O ay;1p+.nop6q {ruroq srorq $asritepouq op{(wrsq

c,tlvior{rrtrt nrr6 lenron},.srcir$r:rq, or<iqp$g Knrordspilsrlspr.v€{ p6trfsq cr1 crroisq fipo6 re n*vo

t{€topolvow $e peiyfo,lKfr u},rrcr!. Ta *vrixepu trr$},4 tor: {xnor€l.orlvrsr on6 rpapupriveq or ofioior

wu?,L&ooovzsr ps pnpyfiIKofg aopeor6'/ut0mq (M s. mk. tv )

Mapyee. apyAo+ Va#pi€tE, fi.ppor Ksr rcpo,edJae rtproxt(€ Orlfibv - Twriyp*S - Aaantaq"

(Ms.sq, Pli\: flp6rercar yn hpvai*e ${i6ryq rtqpfinnpd o onoioq naporrard.{er cqtrffvrucrl

ov&rffo€q lrs 6$rovsg lr0ocpaorrcdq percpoMg. )Jrqv neprcXt cng T'avrlypaq aru.woiiv Selratxd

r(por(fllonoTi ?o ofioio 6ru Bflftirspo rpipCIrd rCIoq ofio, clodvrcr o,n6 p&Weg Kflr nql.olig. Xtqv

aepr*1ii rrlg Aooi?rioq on{rwofv d.grJrlc'r, nri}.iit K{n appsr51sg p*pysg ire guxoe$eig evotptiroerg

l.s?rr6xoKKCIv iy{r}rlrlrCov. To ouvolml x6Xq rou cr1ryrcrrto1rori tivm aeplfiCIu 200-250 pftpa

Ot avw#-p*s 6ytlpdrt6!)oi tou Ntal.woog ctrs ois,-oi6 toug N.trpaKnl7i{aws.t kE rlpmapmot ntrit st

pepw1S Sitret; evd.;oya" p€ tt? Ltfioioyw4 wt)e otlm{}fiq tt}€ Trpatr#cd. oitantpatot. A{nlap1

uSpoxepazdwTra xapoaofi'{otsv ot papyatxoi- rpaltprwostddg aofrsfiiltfior ot oxolot anravro6,t, oedfinrapre;qton; and tqt, nrprcy4 rou Ka.,r.dpov tatq rc, M4kct Ktdr r{) ArnpoXtitpt, at a1paptpeiEevmptitottg ra)l' Neoy*iuv Kdt $mfuepa aariE fioa avanri:coo,r,T.an og pa7ircpou;ffip@Pew]'parpttobE ap{oleg (Ms.c,l). Kardqn, ro{rco ot ercytza)),etoryq o\popopitEava;wttaoowar oe frd*t7 6;vr10oi ufryai|rtpd rosv 100-150 ys-rpuv txrt xspwytg Ey4pmapinu -

Oworpistotv.

Evdrqta ttl g II eir4owrfi q

I-l ev loTco airtqra urecvrd orqv cupirrr:pr1 reprolr] r:e 6ir1 ole8dv rng orpoporcryparprx{ 1116a"nitn ror 8urpiveror <lrouE or6trou0ouc o.ppaaopo6q:

tDltJoPTq (fg).'Iul'tcrurfii sn6 wullaco6p^sva orpdrlpcru a6ryil-rrdov r:Trorolt0arv rcut yapprrcov

lts wmpdlcretq ryoppor!1cov tcot le?ffoorpalparafCrrv aopemol.i8rtrv ru0Cu6 Kol mppcirvoopeorcrl,i0rrrv 6^m rariitr;po rrEhq. Xapa.xulpi{mar ywucd a}€ xptrxtu& adwn{pmoeoy4uanopaq xan dev axanramq ma,,iy ntpng$ winqfpovroq.

AoSeorhfuhor Kpt\nhrcot5 (K5-6.k) .' Aurplvowar oe Suc tp{pcrn, rrro uviorepro Ko1 q]ro

rardrnepo. To avdltepcl anozeieirst un6 l,etno - farg peooorp(Dpot/u6erg ror peprrdg gop6g

9ul'liode4 aopeoroli0ouq rdlcuq and e)"6grora 6a4 rcar 100 pfcpa. Xuxld wcl"Lrioocvcar prerc}'rro'ttroug ryupporSlouq Kol KpD(rul.lrrcoirq aap*orrilfcug pe culydq evorpciroeq nuptcol,i0<iw.Arenvtor'x 6s cfi)p{powic a*vo otol)E arrpecru6},r0ou6 rou rc*.cdrirepou rprqpar.oq. To rcardoreporplpa ano€L"€irar rupialq aird v4prxoriq p€ooorpoparrirfie4 Kcl rcux1i S6oagfiuxoo?polpurrirDerg aoBeorril,r0ouq

Or' aoBewd"tfiot rou rar(urepoo r1t(pmog nryoaouft{suv pteye)irrepq r}t,atdvpa arorcApot*toqsand awodq wa avtbu;pou Kat rcara owitrew, otpglarep4 adparcepacoryta. Ero o6vol6 rcqyapatct4pi(owat ary u&pontparoi o21tgtartapoi pe adt6)oy4 atouE pqyavwpoisE).tnoapyiaq xat r4v rci.v4orl rou unor*€rot) vtpois mo rcapmua o|otlpa r4.; tkipvrsfuag..Edqpoww)toiya rcorcdtoprca(Fe.rVd) ,. Avnrc$noovccr c.e rparoetiirl poprpti, rar* {i6oerq rcrrcu.rd pf1rcoq qg eEfiiPlig r<rrv Avo-Kp4rdrrcov ao'Beo"ro),i0CIv p€ rou uaorceipevouq Tprn6rrcoriq -lorrpacmor)g uopeot6)'t0oug. FI neptexctrdc4r& rr:ug oe Ni efvar yevrni x*5n1?.r1. Th rcorr*oprcroaurd uvagdpovrol Kst t,)C "nwoAt0rc6s Tpttpnvxd-rc$Xos )sryavinl;" rcq.r eivor wdll"oya ge aurdqg ,rsprox{g A*p4rvag - Aorcpi6oq.

ot p&{eg otteppaowbv *eqxopdrutv (o), K.ar ot 4pawnro{1paroytveiq oxrrpaaostoi (b.shl,airors)'oir't 'ta "H*tetJr1wrc6 Txtovucd Kd)appa" Kq,r eivar enoroqpdvor n&vrr: ax1lv npo-

Kprl*5uct1 nlarpdptrro rqq llsXu7ovtx16. Ta unep$aarrii aur& rerpdlgata anr:rslsfvrur un6

ssptrsltwuopevouq neprDorieeq, or oroior ae nolJ.6q O{ocrq eyrc}reiouv tcow&opc,rcr lsrrcoli0ou.

Xrrl oriataorl roD o1rlprrrlopoir outr"tpsreXer fiyog Xpiopltqq o{er6ropfuoq o€ pflTvrldcr;, rdrrcor

pa^4n1riq rcot Liya o(ei8ru or$qpou. AraaTi{etar cno g}^epiira g:uo'od}"r1 rat cg0ova acipemiq.

T6oo ot uxtpfiaomoi oyrlpanopai itto Kftt ra, odrypcvrxai"nisya tcotrdn4uta 6w nuportow{oatt

drcktpo tolpoysui,.oyrci w\wptpov KeJ'!-&peffirypi{o"xat tue rylurtp{K*i ictt; npuacrtxd- *.$waipant

6f,Ipent6poL H nepardqrd. woq e{og&rat ancd rc Er:lrttr;pay*tS noprit6eq,. To avdw.Etpov 6poq

oy"eaxa pt rcu€ oprlpo,twpto$E auw,is; dvat udpo-yearyrgyxd rcan tmru{xat ma ouvodri rcouoopdra

rcar opuw& y.prtpiao ra orcokx #a propniioav ev6tryop|v*{t}g vG" ortpPdJ)ouv mov odpoyjpu<d

Xaparcrr1pa rav undyentv veprbv q; npitrcp1q nepnXrlg.

Tpw&trof - Ioopamrcot aopmtdkfior ffm-Ji.k).' Etvs,r aapeor6lr0ot, 8olopwrxoi ccpeoedl.r0or

rar 6oLa;.rits6 F-ec,o- soq nrgur:zpr*Srarri:Serq. rar<i Sfoe4 <iorpo:rcn rsr avzovil crtovropfvor.

Ndms qq Tovdypfiq r(or rqq Aac'-uriu{ finuvroriv rrlg pulovor€ppor So}"oprnroi o<ifie<n6},r0or p

rov8{iroug reporo}"ieolv. To ouvolrr6 rooq ndXog rpt6ver 6{r}g 1000 p€tpu.

O rryqparropdE amaE napouo{t{et atpfl4 oyaurc& rcailapfurpa pe CaCO_t 6a4 99Vo xan lffiVa,

|vrovo tetqovtopcS ,(xt uyn126 f*Apd Knpo'utflrco{ryoqE. Kar6. oavbren, )ppsrrqpiinat otg

udpompmdq tue nol$ udp*xepardq oyqpartopdg arc6E rou onolou tnanrchooovmt a{zd).oyot

rurytauxo i u 6 p otpd po t oSrT p*t wpo i

ElErocotepard).tllot, (Ii-m"sh): Ilp6xstrar yto fua qrltrrarropd ncru nspd"opB&ver ryapSr{re6

ptKp*K!.lot{shanuyt] xar ap,vr}"rraiq s.pct,iitooug. Eivt'r eherrppd, iietapopq$Fsvq cerpc aou

zeg),appdvet enioqc tparcoer$eiq evcnpdroe4 aopsoro),i0arv (Ti-m.k), Kc1 q<pcroreru,rrin,

oXtlg.anop/ol' (Ti-m.tfl o'nl.iteq, paodi"req ra0/r4 rar Srdqopoug rog<p{teq.

H oTwnttyapprcorcepcro)"t0m$ 6*niam7 anctn)ai ro rpaxnx6. a.inniparc trn6$o.0gt tav

nporlyo{tpev$v o4ryparwptbv zo oi':oia ava*i}$ar mo fihperq xuparphq u1E trepnyg; evEtap$powoE,

ircat tppa,*i{xat ma Bdperc ryi1pa rcu 6pouq Krxrdq taE qv $sptop( :x1S Pnorhv*aE Kat rqi

.Yalxi&aS. Tonw4q qp(rr.i'or: $poritapteE avosnfiooovzan rnrdq mtv avflpurcwt[tv maq *orp&aeav

ot onoitq atwyi;owai rcard, pfTrnE pq{ryevtbv ('avrbv xat 6wppri$*tv

iluJaw(arrcf ont$a0pa (C-P-T): flepr"l.crp$dvsr s1Tlp{rfi$porig rlirriug Av. Ai0av$ptrrcorp6pou

Cr.riq M6oou T'prnSrrou. Xuvia'rarnt ar6 apro(eg, ypaou$&reg, agyrlmofg opor,5l,r0orq Kcu

yappire6 cre eval.l"cl6q pe <pul).ireq rar Xol,o(ruxd, rporal"onay{. Kqrd O*aetg nepr^},crpflCrva

av$parrxfq evo'rpcbaerq (C-P-T.*)

t0

IvsTlioiiio I'ur{ryrrrr & MtrnLlmnrurt fpeuvriuBIBAIOOHKTI

Oi,tpmar$ Xr*prd - OparoparE6dvrg13677 AXAPNAI ASIINA

O oyqpartopdg awdq ano$]ai n tpatancd, adtaantpaw unoBa9po rctv Tpnltrco-lovpaowtbv

o,s$emoli0*tv qq IleAayovwqq rcat a,*ad6erar st avrsclwwi popqrt xmd. pryeoq qg apooupa;

try; l7d,pttl9uq aaore),risvraq irot rcan to vdrn u6pusltrc6 6pn qE u$poyxai.oyuc4q krcuvqq tor:

Aot;rott rrvapo6. Yilpoyttoloywi ev*|wrgtpov xapo*otd{u t1 na.pauot* avfipanrccisv ny4lmrwgri,*

t;fre oe ptsprpri Earco*iriw *mprboeatv 4 autdvop*tr; Eltqldv-t6€@v 4 oroia ot ovv6uaop6 pe vt

pqtryevii retctowrcq eivw duvard cnpfiaJ},at oq &rypwupyio. utipopdpuv opt{dvten' rowrciyq 6paE

oqpaoiaq.

Tcxtovtnri: H eupriteprl rcsproXn laparqpi(ernr rnn6 $n+"/su'rl Kor nru1nsryeq rer,rcrvr.rrq. Or

mrpotl.opq/rrrrcG6 qd,osrq roo o6{yrlcav orqv nrt}X<rrorT€v{ rertorzmrl, Snrrpivovtor os rp€r;

toulcltotov rpdaeq, pw nul"torepq pe roortrrveiq rrnrlciroerg BA-NA, Ereu$wrrqq, prc $einsprl gs

ttfyfiIq notrltria lr*1ioo*xol Kfir lru xptTrl F€ Sopdg 0pnr.roryevo*q r0ruot ?Eor] ilvrnrpoarr:nefsrcr

oisorlsroflx& un6 pi'fporfl rur Etarl.daeq.

XX{prr 3. Katav*uft prTypauov oqv ary$ep4 rryroy"i7 {MiwoE, 1992)

Xe 6n arpopri mrq rcrrpieq pq{ryevetg dr veq (IXJipn 3) Erarpivovr{rr or rpeq lrupreq flur.$twoerE

(BA-NA, A-A rut BA-NA) or oaoleq uwrotorX.ouv, or 6$o npureq otq darreprl rp&oq rrlv

rwufocr"r*v sv6 q rclueurcr{u (BA-NA) e.ivryt nt0nr,{t6 llletoroxorvrrflq qlrriag rar ouveli(er va

etv'at eveplil 6co,q adpepu. Ero t6lcq ror llLeroroxuivou uxaiori$rl$*v Kil,rrrK6pupeg rcn"{oerq

TsvlKrlg 6e60troqq BA-NA 6ar,; A-A rou oSfylqaov orq Snipprli{ r(}v Ar}.omBrcxCov

r<porcaioralciiv rs,t talv aalatotfpov ncrp&)pdtcrrv rcr oq 8qproupyic tou EoBoxorl r6lnou.

l t

2.2 YfipoyewAoyrxig ouv€4xtg - ufipopopor opi{owtg2.2.1 Y6pop6por opidovr:gA16 rr1 oirv0eoq rar ene-{e6ryaoiu rrov $ro6rtoprov morlgeiov (Aotivcrq x.a, 19?8, M6pg'q6, 1995)

rs,el6g K{lr un6 eni rriaou nuparrlp{o*; nporrSrcret dtr ot u6porp6poi opi(ovreg fiL'\t}

crvcrmioaovror o?rlv nepro/1 eivut or orc6l.ou0or:

Y6pog6por api{ovreq Tai.aptitv o}loa$taxdv atro06ceav rm rpocT<rtotuv. [)r aro0€<retq cutfq

cvrrrri:<loovrnr r:s tpetq Sragopenrcfq drirvsg r:t onoie6 crivOr3touv Knl rouq ovrimotloog

u6pogdpo ug op ldor.'rcq;

e Exadpa** xrrt rcrwd. pqrcoq rqe Korrrye wu Arnxro$ *omlntt a*lv repffi wv Otwp$ratv:

Or ano06oerg ur.niq ruspouord(ouv prrpCr oT.erurd ndloug. A{r6loyr1 rppe&ttu tr'opotpopiu

nupouor&{ouv rur*vr.q {avotoitn*) qq E0v$$lg o$ori q onoic u<ptcrturor nepmpropfurl

er<per6iler-r6q Trc up5r.urrrfg KuprCIg Xprio€q 6ra peoou rppe&rcov. }to rpritrn 6rnmd qg

E$vnrig O$cnr q erpet&tr.leuoq e"tfl niiov psra$ei oe pa06tepouq u6po<p6poog opi(ovreq,

unorcei;revov ocporpdr*tv (Neolevriiv xar rtrprrcutdrv). O rpoolrotrranrdS awdg u8pogdpog

$pto-rarur as dpeori uEpuuhrd smro$o]vis. irs rov Aoarr6 norupd.

t Ajrkttfltarco - ftN(T(operuco redio rco Qpano{t: Etr6g rrrw o;rrovfparv cl"}.ouBrrtxdw

cnogdo'ecrry Kol ro)v npoqgcloacw ovom{osF,ra,r e}.eu$epog ufiprxpdpoq G'{qpottopdg o oaoioq

otpiotarar exper*tri'2o'q yil cp8erntr6q Xpto&q 6upecou nl,qOdlpug gpe&tr*v rtril

yeartp{oeov. O u6porpdpCI€ curoq Bpiorcerar ce *peorl u6patiucrl enrrotvrrlvi#, 1lE rov Aaaxd

aorap6.

o AiJotsfiaxcd - npoox3ttpunxd ne6{o ntptoXryq Ba06oq - @d.pott A&i6aq: Eqv reprc;g{ aurd

cvurmicoowar cr$.arr$ra<6g unci3€oc,4 or orccisq <pr?,*gev<niv e?'sri€epo t8poodpo cpi(ovza o

onoiog ttpimatar ercpet*il*uoq fituprdoou gperirorv yra ap8erxtr{ rupirog fpioq-

Yilpoqti,poq opt{owaq rav fiI}ewn}a.mortawrdtv ,y&ltflrtowf}axs}otaytbv: Tu (r1po.ru aur&

naporiod{ouv oqpovrlKfl uvdntu{q ortg 2"ctp/u6eq nsprol6(" tirrlv neprofl petuff Auii6ug -

Clpclnou -Kul.&pou ra0d:g Kur 610 [iopeia rpdorre6a rrlg I lrtpvq0uq ocqv tlepmfl preta{6

Owogriraiv xcr Aukiivog. Ewirq torv uno06oec.,rv ourrirv uvarsriooovtar u6pop6pot opi(ovreg or

ocoinr 6aouv oaooret clpwnr{ expetriL?,erlsq yttr qv r<&}"uyr1 u8anxtilv *vayrcdrw opt<rp€vcov

neproldtv t8r.uicpa otrl (Ctrvq Autr"i8ag Ogurcof - Kul,cpou. flpdrcertcr r,otp[o4 yra eirriQepo

u$p*g6po oplpanop6, o cyroi.o urpiorcrur exp;r*.tr1c;usq pt yecotprlc'urg p*.Oouq yeyotrfuepou

t2

ro>v 100-150 psrparv unop$d.(ovrcrq o-uv{Oarc rr1 md.Sp4 cotr ur6yerou vepotl se efi{ne6u ax6pr1

rq,r rcdrrrl arir rq odeprl r4g 6fi}noo*" {n€ptr}fi Xpucioru4yflq Qpa:aof).

YdpoEdpoq opdovraE taw Nmytvcbv t{qpdrrav Or rr1Tllr{r.rlapoi an'rci c'ra arivo}"6 mug

lupctxnlpi(ovrol rrlg qpurepcroi svo o'e trrepmdq 06oerg avd')"r:yu p* q irOoioymq roug oriocucr4

og rpoxrtrd, c8runfparor A{t6loyq u6poarepordrrlca nupouor&(ow or papyalro[-

tpa$epnvoer$eiq a<rBeot6lt0or or onoioi oncrvtoirv oe r5r*.onopcq 0i:crerq cn6 rqv repropl rou

Kui,6;roTr €n4 ro h'hi)"ecr Kflr ro Acnpc/opr, or u$potrrepeiq worprirerg raw Neoyevtirv

cno06oertrv Kfl.t t$tuitepa u.urfg fi()u cvunnio<rovtnr os $aOrnepotq orpeiil{rrc'ypagmoriE

opt(ovreg (Ms.c,l). Kat6nw roftou or ercpeml.lsfo4reE dporpopieq ovunrfcoovrcr oe pd9rl

ouvr10a4 peyulrSmpa r{Lrv 100- 150 pfrprriv mrg aeprc46eq Xy4prelrnpfou - Owopftov.

Ko.p*zlxi a$popdpo o{o-qpa Tpwduxbv - Ioopaoucrbv tf&r Kp4adrcdt aofr.ozo}Iilav

flpdrcetror rarrl pdarl Tts ro rrrpceix6 ufipog6po c'6oqpa rclv peoo(crrrxcbv uo$e<nol'..i0crw rr1q

BA llttpvrl0*g. To a0orrlpu rtuv aoBeorol.i$rrw nurirrv {n1v nspro1fl wfitugtpowoq Eev

nepu4ri(emr p6v* orq BA II&pvqGu lrl}"$. ant:r'efu;i oe :coi}6q 06oeq ra uadrBc0po rrov

Nr:oyevi*v <igripactopdv oqv eupdrepq nspn1q ev$r*.g6povtoq. Avu8rierar xar rctrpouota(er

ertrpcweur{ av&nru$q crqv repqg{ rox Owocgrirorv, orTlv nepnpl WstuE0 rqq Tavtiypflq Kor

Aoon{ag naOdrlg ror $6peru ourg vd'neg napvqt; rou 6poug KrrrrcdE. Eprrrrflprara firr*q q meavrl

qlotKfl rnr u$par-r}"xii <iuv€1eto pera{6 r$v €pgnvi{rs{$\, cu'udtl, 11 uadryeta Etocr$v6ec{ roug

rcu0trlr; rcur q cv*aru€i rmq rrco lerrrho'yrxd urcripaOpo qq repLoX4g mr0opi{orw uvric'cor1n r<rt

rry frcrooq roi-i lurOcvoi.oyofpevou raporrro$ unop&0pou rrrrv Neuyevdw rqg rcptogflq r<ar $q,

ex rorirsu nopouo-rd(ouv o4 pavnrir uv$rug6pov.

O rrfiporpdpoq ou6q eivar an6 rot)q oqpcvrmorcpouq rqq reptcXrlg. H rlpra reprol4

rpo,godoofaq rou eivat or t?nqflvarorc€q ror ep<pavrrserg orrq $ripereq rup'ugfq rqg lldpvq0cg

rc0rirq xur prrpdrepeg ep<puvt$srE rou orrp zupfreprl nepnp!. H pot Tov uru6ystcov vepdtv

raceu06va"rot rpoq rrp,neproyjg r4g MaupooouBri?,a4. tla*u nnsvrd Ku,l ro re6io yecr:rpqos&)v r{E

[iYAA|I, r*r 11 telrxfl rou ex<priprol yivcror oflq u<pd,Lpupe..C 3rqy6q rou Ka].*prou {A*6vag rc.a,

1978, M6pqqq, 1995). Xe 6tr ugopdr aru udaarcd roo anoil{1tara, aurd a,zore}arh, orgnqyrc&

oxtyem ono06para aqoi oe rcpu66ooq )*wuEpiaq Wryaporoui0ryxw Fa rrlv *{ayaa1 qq

itdpmoq q ro0 .)*ntn *x t6iou.

2.2.2 Kiv4o4 rou undyatou vcpotlt'I ri.vrloq tou undysrou vspoll orouc earp6poug udporp6pouq $glirortapofq rpotcuat€t curo fil

oriv$eoq Ku,r sasdepyuoia norrcitrr,rv yeo:i-oprciw, u8pvyeallaytrCov Kst u6poulrrdov

Irip{irffriptorrrlov rorq. Aro ra pt€1pt tr'irprr otorye[a nportrrnouv tu ur6]'ot-,0u:

Or u$poqopor api(ovreq nor auv06torru ro u$pcryerrll,cryrxo ouoqpo tou Aoarnoti opwOeto0wet

Bilperu uru6 ro peoo(rrltrcd sxroroqopp,rnxd undpa0po nsl) epEr:vi.{etut nani F{KCIq rou 6polg

Krrrnd,g xsr vdtta ar6 c1v Kopueoypopprl qg [Idpvq0oc 6torr nvu$uerot st wrtx]'wucl Eopfl to

nuiurc{rorx6 uaoBu0po. 'i'qr

iiutrxo rou 6pro 5w eivat pa urpt$ei* yvaicrd rr}"la cruppa:r,fl $r€ to

enr{,otrretpxd 6e6opfva 6urrpa{vstai 6c1 &rfpletnr B6peu eou ri{ovrr Xllpucopiou - Trrvdypaq

ror oproOeref to uEpo<p6po arioqpo rou Asorori pe or;16 rou Bouortroti Ktlqtooti. To oforqpa

rou Boxorrrori Kiliproo$ erpopt(erar crro EupoTr6 r6lno Slup*aou cnE Y).txqq Kfll rqq

flcrps.iipvqq writ ro currtqpa rou Karcpelttott 1ro1) ovofiTuoo€.tfi,t ounKo€e,po TOv

rgxxrvuqp{l*vrrov, ertpopa{er atov Koprv0taxd rc6}"no" Eqv neproXrl svfitirpdpowog q rivrloq tou

uadyarou vepof Eurtpoporuomitur rcutcx6prxgu rur opr{6wto pera(0 trrrv ernpdpoug u6pog6p*nv

opr(i;vrorv.

Ee &rr orpopri orouq u8poqdplug opi(rwceq ralv rmmeailtitv N*oyewbv tc&t r$v II],tw-

rktotoxatwmbv aro0{6eav rqq nepoTriE Ey4parcpiots - (}tvoEt}r*w, ro, rne(operprxd

8eSopdvn Setlvouv (IXipa 4) 6n q amxparf<xepq KrwI{I{ rou ondysrou vepod eivar BA

5lerifiuvaqg, Enio'4q 8r;tutdr rarv Orvoqrkcw rcporqpeirar pt& "rlsrorrl" xti*ar1 qq ne{opetpicq

q onoiu snotelret pw "o6pau)"xr1 xaraP60pa|'. Extrpritot 6n 4 o-uyxrxptpfvq rutup60po

nporirarer ond rqv wu,06l.ara4 rou unoxstlrr,-vou xo.poarcof urop*Spou rarv Tprc.iitrlnv -

loupucrrrdrv uo$earoli0ov trl onoior capauurd(ow sngaverar{ uvdrru(r1 orrl 06oq "Il0pyog

ArlolordE" rarv O ivorprirrr.rv.

O raxbttpoq rcapalrrdq uipotpdpoq rt)u Tpta,&xtitv ioupaoxtbv aafeora*ifltuv,

tporpoSoretrcr cn6 rmaodriovrc 6pppra ri8arc mrq p6psu6 napugEq qg tlfpvq$aq rccOcbq rcat

oe snupuvnardq eprgavioeq rc:v oopearol.i0olv aurrirv rm6E rqq l,e**vqg mu Aoomou. Errp

rpouv*qep6Ucvq f{splox{, $uctt<* torv Oworprlta:v, $pinrer&t sE u6paufutr{ snrrcrycrv{c, }rs rov

unepxeipevo ronxdo$n uOpogdpo opi(ovra rrov Neoyevd:v rcrt fll,eroriueiororaivtxarv t{qp&tcuv

Tc undyec vepd tou rcpoarof uSpoq6pot o'ocr{pr,ntog and trg neprolfg tpoqo$ooiag toug

p6ouv ovaroirr& Trpoq nlv neprofl rqg MoupoootBrilaq Kot tt(gopri.{cr:tat mq utpri}"pupeE

tqye.q rou Ku},'ipou (IXrlfn 5). Ag orlireriri0rt 6ft cs oprop6v* tpqpotn, rrvctoltr& qq E0vtttttg'

o Aorrrrog nocap6q ppiorerur oe d,preo'q uiipcu?,rxt1 ectrorvsrvtn pt rov t*portrd dpogtipo

opi(ovru.

l 4

)

CJ

c)

a{q

F

Es6 6 b *3 \ } ( b

* c s> r->.xd *EarE , * rP & **lP s6F*Y - :

-

rnBs t *

3:Fls

465000 470000 475000flrc(epnptrc1q rc*.prfru;g xat pofi roo ttn6ytt,ao vepa6 ozooE rcorxaiug t'EpaEdpoue $Nqp&rtoptsilq (rpwrcy*r1 6p.6otttva and loitva x.a i978)

15

475000

siEaruuff is\ I rOlupmnxd Xtl* id' 6Pu xr:P*re$dveg

136;? AXAPNAI ASHI'{A

aor\c\

v

s

\Nl3

c) 7-( f " ( t r' 8 *F- oi(

3A

Es(,

.p

sfr13it

B(,

tFsv

ro\

lJr

(r).s'a

o t aP H

F kS (s'

i)G

b

of

an=Fil

s

a.(5v

c'(

H

if;<k

)a

8s( } t uE*tf

\jriD

: l

It

.r\Fr, ' - } i- I^l

" "''"' Opra u*poAoyxrlg AexdvrlgEr

''id-. ' .--.+j. " r- i:r--

lid_\jt -__ "rrur*,

*r*o'Or"*1.,,,, ' ..7Ji s ;It 'r$*lp4;r. ::,F-:)'T,,i;q$i:,1pi:?-:).,fi1.",1, Flrptcxoeclnrli,vu.poe6puvdmuaiouir.,E|.'*t, i;ii.i*, "iti*[.i$,,:i::ftf i!{i-ii,!,.;!i':i1it. .-*;ff#;*iiffiH'l[H

i\+:i,fte ,liffitr;fl*Iffi

';,iJ t5;il#. ri.,,,

* {:', :iilt.rr, qayrsxoropo

'l ii' ,ii:: x.";,; .r-ljriJ i ;rtii;1l

';i:;*i,ri ,

} r:' :{;;,' i,,'. l*'.t*';,,-,}-, : -t';i

_ti ;i :1,,;ir-r j;ijt.'i ili';i*i :t ;ji;.1 ;;:. { : ixlti'1,:}, * j}+.;1r,*r.

t*ti'ffi7":,;.{$':. :. . ff;j'{'"' t-'*::*:' i' !

"-l:t--'i'i*' ''::;

.f37.),|;rj" i.-)i', -l,il:' \.{^ . a'' r l',

, .- '-, ' i ;2'4';/{! 't:,-.;r ' . - / ' . ' " ,_.ect ' , . :-

- )qg'+^,'[*ffi, i,.I,;:i.-l- 'i, ''

" *_f;,'.t:+; =-,jrilr.;l-iil;#lt l\

:;::*+') 3"r.' i,; ,l*t j-_rjJ., \j\^ . ..). r

""

..;.,,t/. i*

.,f*;:ffiffii r-;' j--i...:,{'. #\. : '.i *

)

EXr{pa 5. Por! rou ondyenu vepo6 mauq rcapmucottE thporpdpotsg 6grlp(xu$l}oitq (np*noyev$ 6tr)optva, and lo$vag rc.a 1978, Mdp,prtE 2005)

r6

)

P

:r: F!'

' - : ; b 6 ,

3\ za rq'

.;l +"''n

: . t<Fxd r*L 6,"-: 2 . ' v> * ( D AH 1 : } L I .

a s f o

C#rf,FExF e r '

ia til

3: ).t.'lYt

ir\

2.2.g YdpoAoyrxd ororleio rqg neprol{gO roropdq Aoo:a6q ul'roq ror.l crccriou ppiorerar rcor q neprc1i Aperruug 6y-er drcmorl 678 km? rur

Erarpfvetat o'uvri0rog ce rp{a entpcpou-c rpflpratu mw &v0}, priaCI xar icdrrro pou. H u8poioyrrcfl

rou lexd,vq 61er erripqrcs6 - srpCIrffoet66q aplpa ro.l erreiverar Strrrrd 6o6 rqv aeprop rou

Kanape)"lcu svt'CI uvsto]dr'3 erprii"]et oqv neprcXri to'u {}p.rml: (lXnps 6i.

E*ppr-':vu pe BtBi"roypu<prxd 6e6oprfua (Aorivag x.q 1978. h,{6pqqS 1995} ro peoo etqon iryog

Fpo;mq rupctiverar uno 4AA nspinou mrn osrlv nspr,o1t'1 rou flponoir 6ro9 rar nspioodrepo an0

tCI&) ffiK t(opil{peq r4q lIcpvq$aq q oruoiu unomlei Kor ro v6no quorro 6pro rilq lex*wg {74.."7J

fl{vrrn*g t. de&optva t$ilp*vtwx*q anappofyq rcu dva port qS krcdvrl; rost Aowrwi) {EylAn,

l

It'/ipro3+ }995i

YDpJfroq NOF AFK IAil OEB ilAP ANP MAI o,\tKtlETHTH

1971-72 192,000 714000 621,m 1,839,000 1,648,S0S 938,100 253,r00 6,4'9,1m1972-73 216,000 740.000 603,000 1,286,S0 1,770,800 691,500 61,700 5,369,9S1S73,7{ 197,000 6,94,900 1,606,000 818,000 1,516,000 570$00 42,000 5,553,9$,1974-75 221,000 r,226,000 972,000 628,000 8S3,10C 477$00 51,000 4468,1001975-76 420,000 r,407,900 787,000 1.592,000 t,932,000 1,390,000 44C,000 7.9r7.9{Nt1977-?8 513,000 955,000 t.378.200 2,164,000 t,14S,000 38S,000 24,000 6,569,2001378-79 540,000 r,477,00* 1,453,20S1,367.400 913,400 228,000 35,S00 6,014,9001S79.80 5S7,0S0 l,s05,000 2.004,500 1,744,000 2,183P001,756,5m762,80010,s5$.000r980-81 't77,000 984,00S 1.563,100r,520,000 1,808,000 1,309,100 113,0007.47{.?00rs81-82 -159,00t) 852.000 1,1S0,000 752,000 1,878,0001,250,000 ffiO,000 7,181,000f982-83 296.000 505,000 1,312,0002,055,000 658,000 s57,000 874,000 6,657,0q,1C8344 632,000 720,000 1.134,0001.784,000 2.n7,0w 888,000 657,000 s,022,0001987-88 267,000 890,Ofis s74,80fJ 45S,700 1,498,000 398,500 424,800 49{tS,g61S88-89 127,100 1,114,7001,073,40CI 5J 1,200 609,400 250,700 222,2fi4 3,908,7{X)r990-91 212,000 1,202,5001,023,700 $4,m0 1,368,70C 865,5C0 300,000 5,906,{{XlfYt{o,\o 4,966,1m15,498,ffi 17,SS5,901:19,3'fG,200zaffi500 12,355,9005,1?0,S1097,066,1m

i'EEET TIiIEI 331$73 1$33,200 1,179J27 1,?SS,747 1,4.S8,Str] s23,727 344,7m 6$?1,073

fl[vuxcE ?. Yfiaruso wo{$yto nepwXcbv kxt*w6 Aoano{ nwo,6,a6 (lufi$ppqq, ]995}

OPEINH ZONH AOSAAHT NEAINH ZONHAEKANH ANOPFOHE Avgpcxrroi':xiluqr$uol frlrr:ve.vric *'lcrsriovsvtit sxnilsrr$ilrJi

EropofE {mrxlQe) Exooic imtxl*6] Elorxli( {mix106} Expolc {m3x106}

Avr* Poug P * 46.67R 2.33 59d

P = 110.47n 27.62 25V"

E 21.00 45''!, tr s6.28 E+/o

23.33 tu ib I 16.29 r5%

Mfotrr Poug P = 176.84B.84 5 %

P " S8.90R 22.22 25%

79.58 45'/o F 53.34 60%88.42 50% I r3.34 15Yo

lduru Pougn

P =24.475.11 25%

E r J2.28 $0 ?4I 3.10 15olo

l'\.-

. , \*€A

a

I

t : i

- - r rJEt - A

t4t*i '.*:rr4l \;\'

f'{a

#:1'I ,,r1:' i r ' :

1 8

sg

W{i ' ,

Eplw.6. Y$poypaE wd 6imto )"uedv1 g Aoamoa nompot

ilrmnotnofu$SIB

Ol.tprtar6136?:

EH$Aa

aEI4F{r0p{ov

hwnstkries:BIB

Olt;irnard,36?

r-1'.i

+ ?i

-t-"=-t'\ -

4-*/' ,l-i- A\3Q: C">zoo* 'i- \

:tKoud!E\- -i

Ey$pa.7. IoabineE tca.pntleq ).sxdvr1E Aoomaf norapo$

19

\.-'*.-'\.r-j./

Tn pdvu 6ra()6crpa ototXeftr ertqulcmrflq unoppoqq rpodpXovrur aiio pctpt'ls€lg sqq EyAAnnot agopotiv aro rivctr rp{po rqg iexrivrig rorr Acronori (06oq K),sr6ii K$lrrlv nepio$o lg?l-90

{Iltvcrrcaq 1)

A16 tu oror;s{a aurd npox{mta pqfie,nni an*ppo$ rard, toltq F$veE Io{fuo, Atyooarc rarEetrip$pn O 316oo9 errloroq ouvtel'r.mf1g onoppori6 nlc Eetrt$Xrlg rou Avr;r potr iopewq de'rvr1)q orcoia olctmorlei aw 24Vc a6 ouvoirxrts fKroortg qg l,erdvrlq rou Aoconorl, , yrc rrlv repio$o1971-90, ur'€lryetot cre 5.67o. svd n roteioEuoq a:.rt 5OVo rorr uvrlrrrorXou grBoou riryor.rq Fpqffts ft4Sx1$6 m3' lMdp,pq6 i995)- AveiozorTgo orc 116oo pou q ouvoirrrl enlora racaio8uo1 uv€ppuroro'e 101x106 msror <rcw r0ra: pou ss 3,r106 m3 (flivrrxug 21

2.8 Erot;p;ia xftAuWnE yng'ooarg

nporcdrmer enh otoryeia roo eriparuoirori npoypdppcroq *corine,,

) 4 eupftepq ne-progt'1 rou ArrruncrrS rsilifitatsr

ono trtx0sru auonlpara xal}"rfpyem,g, eiar/uveg Kol cl,i\eq ra'irlrep-ryereq i)*Xr1pa B).Xupurcqprorrrri etvsr erfor1g q rapouoia Brog,rylavtrdov rcai epnoprxlov (awcirv wdr or igg$serqrn opetv{ rr*pu}Xeq ru}dmrovrur u4 eni ro r}sisrov un6 oxhrlportu?rirrrl B}udorqtnlEe 6rt nrpopdr orqv srltKputo$a'$ rtrScr1 trre ral6rro 21t (pq ap$eni6p*rq updorpq yrl) an6grnrctnou eriorcyq npor*:rret ort oalv nepioltl aur.4 crncrvrcrx xulJ.r*gyure6 rr:picug teiit),oiv ror

Bo?.Br;:v ot onoieE apSerSowat un6 undyerc vepd.

?a

lwfli0tn0 I'f{rri,ryflrdfl & ll48t0,ufiaf (llr $nrlri)v$iEAIOGHK. I{

Ol.t;rrt ard Xoprd - 6paruirrreidveq136?? AXAPNAI AO}i} iA

6 BF ' 3

HEI Ef g ; s

sEi$g5 S F S Fgr$ r

(N

UuSNr-\}

t]E\\)' tt a

(n\ S

$;\rH(n*>s

$(.ff

(,FLr'F3

.t

(J.

Fts).St , :

oa

I..f^l

Tq,j',.. ; ' "b":i.:(:&.

.'tr- ! ' :

I E

$ i ' : 'ri-';-....j':;":x i ' : ' 'F

.f , r i'ffifl :'/'r ,,u,']i;'t1 ",, g i g $ *Iftt;il bffi' * s u' "\ -*'"r,

;lig* ffitll;li-."ti$' ''. ''3:, I j-i.,,'

i- *..1 :;'-i _'. l.i'. .; | ' ':,

'ii#s;*Hffir$fi#t-'Ti$ ii:t{ &i.'='.':-t'i I }."i::''c'

-'tI$ i#\$', :1*; r, "' t: : i . ' * . , , , f1 l i , . i \

" ' t ' i , . . . j . . '

fi1r,i-lii '-{#i ' '',..-*',*ji*

**ilffii l:7j7J," ;t,, r.'' y{ ***-,,,,t-i:-iI('r

i'rSi;'

't t . . \ ' '1.- - . - ; 8

-z,',,:_"'i. ,.r'T ;ii.J.\"*,,i,, t, ' * ? ;,li Ei5.-, .,"it',,t:'"';i::,i.i.,..;;irg'-ii;.ir ;

i$E' ;;iii:i'" 1 J,ili,T{#- *ffi ,.'-l+}.,ifl;Y,i l'i'f;-{ ,' ,, t*l .t'ffi:'{:i.;.{ -j;{r,:,,,;

., ,,' ,' "i'}, ,:i . ,: ,#i' o l,ltpi :1tt$-;, ',,, ,i, **.1:.:':*ir;i*; ,,il;'

ffifi?f" '*

r' . l-Yi

i : \ - i

:...-- t.

;t''"#t'

;' ;;i,.x.ii 'li'.*'

..''fl]/'Ei; ,-rl,'t;"rr' iil. , li, u''"

,li- ,,*i tii.ii,r.i,"tir1,: tm, t .,-,i; i: * 1'l

, :ffi,.*--,: iltl,H.,;'J; i"''n\,::i 1 , 'o * .i =j*.-SjZ.,$i.--3i,

' 'l i' i'o :".,

'1':i : ,i ,,*{.g.'.f;SJ4:"'T,.-;ii'-1!i;;tffi '',t r,: ,'', ','"t,*. i'::;

;: i ';,r|..-;tfli .:, ' _**.'. : i:, ",

.. ' x, i-

" ,-,i:i:

ir,a,un!.'ii:: :," ,r,1*',1:' : ','i.., '' ' ', :,r. "'c I ,,i'';".,;:;,#i:E;'iiid+-i*'','.' ..,, ,'.. i.; .1 ' '. ' 4, tr ,'l

: .r1 j -- ,'-,,- -- t'.

3 YOIETAMENH KATAITAEH THE NOIOTHTAT TrIhIYNOTEION NEPON

3.1 Aixruo eAiylgou - pe0o6oAoyidKtrrdt n1v **up{tl 'cr*v epyaodlv lrpfiypororort'l0rlxe o.\,flTv(Dpt$rrxf1 untoceiyrl a"rqv lr$plo1ll yls

o;}"),r:y{ xat c{ro}"oyqoq Ee8opev'rr:v olenra }rs 14 enndnou o-vr,04reg ovrtnru{r16 rar

erperd?"lsucrlq ro:v uafueurrv vspriv ra06g Ko.l rn€ racavopflg rarv praoydvaiv eortCuv.

Eq ouvflero fipoypflronorl$qre aroypugil yerorpiloearv xar qpeorcov Trs rov 61,eyXo rcw

un6yerol vepriv crcr1v eupirreprl aepmp p"e $uorro o161o tr1 y"rrlprr{ Erepr.uvlr:q rdno rorr

rorrdu$ot4, r4genrd pTl1oi) tppecd.al r$p*tpdpou ncru ovsiraJs$€Tol ernft tnrv fllerorcrc.rvrxri*-

qg4panoyd:v 6oo ror ruu pu&trtepou K{rpmil(oti u0pcq6pou opi(avra.

Ta u6pooqpei* elfrylotr *orr ta)"x* uroypfr<pqxov trpr0proirv ouvcrirx*, -122. H lriipmfl r.ouq

xatavcpfl Sev rdhurye pdvo qq atertl iuepr.qt'q rol p€oou Kfir rou rcarrrr pou qq lsndvrlg rou

Aanoaou alld rot rqv nopoKs{gew1 iuepropl rrlq Aul"i6ng. Or 06oeq rrrw yr,rorptls€{riv Kor rrov

rpped.rruv eX,€ylou nou re]*rd unorypdrpqxos rclpouord(ovcar Eplpa 9 eviir ru ernpepoug

/"c{p}olirqpi$r1rd, rouq 6nroq or ouvrercypevegr, rl atff}pq rou rmdryercu vepof rcr o.i"r',o

XopuKrqpraflK&, nnpouoid,(ovror cvcl,urrni srov lllrara 3.

Kord 14 8rdprcera filq onsypoq{q npayparoruor{0t1rov, 6ruou orn6 rJtav eqmro, perpfloeq

<nd0pqq nrw urcoysicov vtpdw, *,6t perp{Oqruv F-rrio.qq enwdrrou 'rfl rp)$u(oftt1iur6. rouq

Ipp(rrrqplnrucd 6rrr:g rl qA€.<rryq ayo:yttrrdrqru (EC), rrt pII, 11 Oepporpacriu afpa (da) ror

vepori (dv) rrx to 8r:vairmd afet8oavayalyqq (E?). Or perp,loerg auciq n*pcucr*,{owar enioqq

o'rov llivaxa 3

Tt;),oq, ei.iyp$qaov 8eiypara vepn* yra Xlprrf-q nvatrrioe4 rnrpirrw rdwrr'rv Kcrl r$ronrorleirrw oa6

ra rcsptoodrepu uiipoo'rlpeta nou snoTpd$rlK&v K$.1 ouyrcercprpf,vu o.rd ta orlpeiu our* daau r1tov

6uvn'rr1 4 SeiypnrohrlVru. AE orlperal0ei im sner$q q ou?Ksrcplpevq Eerlpurotrrpyiu €yrve ae

Icl$rsplr!'"rl rlepio$o nolldq und nq lerotpqaerq. ror-) r)fiqp?fov o'filv rsp{.o1l rlrov uvsvopyfg xar

ouvcmrilg q rr:rardrepq 6erypuro)"r1iyia ri:nv 6ua1epr16,.

Erxo].rrtl elrlqOriouv Eeiyptmcr wrO 8? Eragopetrxrfi cqpeia el'c'ryco. Ta Ssiyp*lu vepoii aou

inp$dvownv ;retcrgfpotruv raflqtrtepwd oro tsg1omr'1pro .{va},ondg Xnpeiog ror }fME T1o rlg

clenxuq, trvaLf<rer6. L-)r spyscqpraxoi npooiiroprcpoi rorv uSpopipxdrv nupa;rerpctw nor

zpr:.lpatonorfl0qrav aapouoniiovrc.r uvofurlrx0 otrg cpdoroq erdpeveq napayparpotg.

' ()t our"retalpfieg mru avcypfi0ovrar s,lov rll'.,src 1 elt'1g0rpCI" pe tpopqtl ouoreurl GPS

22

Iffvaxnq 3 Aro,vpaEtrcd" Xapa*4ptmxbv trllv yl.anp4otaw tmt qptm -e,i6

3 5 1 1 4 . 5 1 t 7 . 3 i i 1 4 2

ilhorrfiqg

Kow

4,.I_g!qgti-.- -*-

l6tor'irqg

j f95

25

nry_6.yquit_g liSyts'lg

Iwruo{nof *airy&b&,Usrfrlt$}fl r#F+mvaivBIBAIOSHKH

OX,tpmard Xoprd - Sparopare06ve61367? AXAPNAI ASHNA

?5

ngff fi XOlgli,gTlt({il&r!1t10Lt$Xlr*I{t$ilJv{ln

BIBAIOSHK}TCIluprcrard XCIptd - Sporatrrure8dveq

136?? AXAPHAI ASHNA

r*al

oid

E,^t

00@ezt

l

I

It

i

I

I

:{.

{L.,

3.2 AnorcAiopard rar srrsfspyooid ruv 2141ttxtitv drtsAfioewv9.2.1 X4prxig uvaA[oarg'Oncoq rgxrova<pfp0qKa ol ?Cn,nrc6g avu')*roerg rTou npoTpc,ronorrJ0rlrcv aep*}.*Buv, etrwfnan

Ferptoeq grlou(cnlfti{$t nopapf*pw ifia, 0v, EC, pH, Eh), npoo8toptotrioti6 ttupto:v rrwrciv

(:Ca2*, Mgt*, Nan, {, Cof^, HCO;, Cf, Sot2', No;-, Nar.Ks.tNff4). ratkirg rnrrxrlOdopnq

rgvoctcrg.uir*v {Cr, Cr6+,Fe, Al, Ni, Mn, Cu, Zry Ba, Cd, Pb, As, Cs, Hg, Li, Sa Ag, Mo, Sb, Se,

Be, V, T{" POq, B, SiOz} ttat Okrco$ Opyavu<o$ Av$p*xa 4 fOC-

H aapouciuorl Kor rre(epyuoia r{nv o,rroreleop*roiv aurcivv aro}cuOe[ se E6o erapepouq

ropayp&gori fior) s{popofiv, q pev *pdnq rqv K{rr{r1ropf1 rr*v r{prcr:v r6'vnrrv xat q Esrl*prl rarv

rlvoorr:rXeir'w:

9.2.2 Karcvoprl rsJv Kt}pr{^ry r6vrutvH fperrva rqg fltl"{gvrp$o-qq Kst Kuflrvupq-c raw r<6ptrnr tfurrrw (C*'*, Mg'*, Na*, t, COi',

HC{}i, SOaz' Cf rur A.'G3-1 anoce},si fiaotxd egyol*io oq fiiepaxq{tr} toiv u6ponge*igqpr<6v

8tepnyaordrv xur yevxucep(r rrrx prpguvropiuv )enoirpy[aq rc'w u6po<poprr}v s1q}ulrtopCov (Henl

1992, Lloyd and Heathcote, 1985, Appelo and Postma 1993 r.o). Xqpawxf epyolstu oT qv

$DTrcsKplFswl rnrc$Suvorl uivor 11 apoBol[r1 ra:r'lqpmdov ovtr]"riosrlv os 6r&gopu u$poplprri

Droyptippara {.Hper, Expanded Durov) r1 76fipmg {Stiff patterns, \raypd,ppma "rk&€'} q ox6pq,

uvaloya p€ rouq trt61*uq rrlq €p$lvo6 rat q 7pr1or1 noll0nloxrov vdpoTrypncrisv opotwp&:ruv.

Ero tr1ripa l{} rapr:uor&(rrnr. 11 npaftrkfi xw prlprxCov nvs.li)$s{*v ce Suypnppa Piper (Piper,

1945) wri: ora Ey;ipa 11 q npo$ol.f1 toug oro e(cr$rreuy*ve &dyparye FI(tt6 ylnrco$

fiafutsswa vepot (Appelo and Postma. 2005). Eric{q trro Eplpc 12 or pqprxdg uvairSoerq trrw

rcupCIv t6wrov rpoB&l"l,ovtar oe Aveirruypevo A*irypapp* Durov (Burdon and Mazlosm, 1958,

l,loyd and Heathcote, 1985i

T€Lo9 rro EXrlga 13 snsrrcnri{mo.r trgupcoyparprrd 11 ruravop{ zalv i$pogqprxf':v avu?draearv, rrlq

npdrrqE *epts6ou Serlpraroluqyicr6, ps rri po{0ao 8roypaptruirarv rrnou "Tlragu (fi Fie charts}.

Aq oqp,arar$ri &t or rcpopolteq cro ouTr(€Kprpwo 8uiypappc "nlrfi,g" 6ywuv otSpgc':va p,s rtq

rpoEroypc<p€E nol cp(er o IIe.m (19E2). H Odgrrpoq rcov nrrc)omdrv rolr6arrrr si\fd."LSlp}jpTq rou

TDs, *$";r:,,'',,4lt6 rtq rnpar*vo: ngrpoi*g xa0dlg rq.r firti rov fiivara 4 tcov;gr1prr6v avui$oeov nporarrrow

ta or6'tror0u auprep&opurcr:

28

ll{vanug 4. Euyrctwrpcitotd rchptuv tdwuv

Iqpdo'Y&noS

0n Eh EC 6r lN0 l{a K ccg HCC3 cl stl4 NO3 N02 I t&r{ :rlmimro

mV F'SIem2sc)

nrdl OI|16 11qoo6. ldfunnngtC*O8

Ooto iroorudrnrcc-> 25{t0 2m 25{t zfi 50 05 0.5r1 r21 I i85 D t . t r08.0 1.3 U.U 391.0 149.0 46.5 A 1 <$.05 <0.26 318.5 gr*.7 n.812 -7,5 150 1281 72.5 5t,u t le0 1.3 0.s 412.0 1S.0 49.7 12.2 (0.6 <0.46 409.6 #7p 70.6t 3 J . 5 75 s46 4S.5 J 4 . E 100.0 L2 347,0 101.0 4S.5 <s d.tE t.$ 258.2 n4s e.0t q t - J 131 1033 74.S 53.1 498 0.9 *_s 430.0 91.5 27.7 V A .0.05 <0.a 4m.4 360.115 T3 zff n37 208.0 106.0 z.o 8.0 409.0 4fi.A r53.0 9ts <0.01 {0.2{ -o51.0 335.4 615.5

16 7.2 24 576 101.s 7.8 1.3 0.4 0.0 326.0 r0.3 9.6 <3 <c.s <0.26 284.d ?sf|.4I I 7-3 1E5 i t " i a { n 81.2 81S u.g U.U 585.0 120.0 38.5 6t.a d!.05 <0.2e 530.7 4793 on,v

rB 1 . J r05 163r ss.0 67.1 t5e,0 E,a n i l 4:t3$ 255.0 125.0 r8.3 <0.05 <u.zo 4S$.d 355.1 14t.4

I Y 2&. 1717 90.6 652 17t.7 0.8 4m.* 200.0 e15.0 { { d <0.05 <0.2s 4S4.4 JU5.' 10s.3rlt 155 1065 7$.4 37.0 u-9 o n ss7.0 101.0 t6.0 93"S <fi.26 458.6 $?5.S 13?Srt l 200 oA7 69.7 57.4 42.1 0.s 0.0 421.C 6S_1 1S.0 62-A <0.05 1.0 410.4 345.3 65"1

n4 f t 1gil s78 81.8 4{1.8 40.9 r.3 0.0 408.0 It.0 t b . c e0 <0.05 <s.26 408.5 s,tq-D 73.SF l t 8.2 -lA oRo 25.4 #.4 Its.5 0.9 0.0 354.n 125.2 3S.4 <5 <0.05 2.4 23S.{ r90.1 0.0116 7.9 145 1 196 34.5 63.7 11L7 0.0 384.0 136.0 43.3 80.6 d.05 <0.t$ 348.$ 314.9r17 7.7

't55ts85 43.3 1V2.4 1 5t.g 1 7 0.0 500.0 208.8 I 2S.$ Tttt d!.0s 3.0 530.0 110.1 1m.6

118 7.8 1n 978 3S.3 584 1 A ' $.0 3??.0 116.0 42.7 {5 <0.05 <0.26 338.6 $5.r tr.J

119 7.3 21? ,|413 19P..A 43 s2.0 U. n- 0.0 455.0 184.0 oz.t 12"4 <0.05 <0.28 4S9.7 373.2 126.5

12G r55 1 15? 130.0 113 98-g n o c.0 469.0 121.0 3€.5 <5 <0.05 d]:8 sE{.3 384.? 0.1

rui '1751 130 '!29.0 tg.0 101.0 456.0 I4.U b3.i3 <5 €u.uo <0.26 400.4 JI J ,Z

rz2. s.0 5113 1c,Bt 22.0 t{a 2{Xt B u.+ u,u 391.0 145.0 <5 <f .0s <s.gc | 15.9 t00 t 0.s123 7.6 4U zns 90.8 125.0 ?ar* 23.9 0-0 432.0 5x.ij 'lil$.0 12A 4J IJ5 <0.26 711.$ 37fr.7 370.3r24 I-6 1ffi 2ml A t 1 89.0 4948 1.3 0.0 5t8.fJ 4y2.4 184.0 't2.1 <0.05 <0.?$ 4?0.6 424.8 45.8

125 . , 5 197 -lz.Jt! 101-0 r18.0 271.t) 0.4 4t9.0 423.9 163.0 49.6 <0.05 <s.26 7 r t a 532.3 2i3.4126 270 1294 68.9 14.1 zn.a a 7 0.0 4t2.0 2n-a ss5 <b <0.06 d.26 2fl.1 937.9 0.0t27 t , 9 s95 6?d 25.S 55.4 11.9 0.9 $.0 3&.0 60.0 zt).u 248 <0.05 <0-26 27'e I 250.1 n.9r28 7.5 249 565 20.s F-i.2 12.5 0.4 0.0 3b3.0 19.0 ti.i 62 d.05 <0.2s 318.4 302.0 15"8

12g 7.4't&

804 72.5 45.7 18,1 0.s 0"0 409.9 35.5 372 8.2 <s"s5 t.0 370.3 tj30_5 33_7

131 73 109 | 1S€ fid.6 3S.0 tsi9 6.1 {].s 354.0 an.a 70.0 <5 <0.05 <0.26 s64.5 290.3rus 7.3 212 8S6 194.2 r a a 26.6 0.s 0.il s53.S 48.6 J 4 R o,a <u,u,: <0.m 316.2 ')41 t 25.1

i d n 7^8 ts 18S0 40.'! !m.5 201,2 L2 n ^ 50s.0 3' '0 139.$ 24.8 0.9 <0.26 338.7 417.5 1 t t j

ffi4 7.7 2CS t?0t tt0.1 1n.3 128.7 1 1 0.$ 4S.0 18S.5 Ita n t2*0 <0.05 <0.t€ ff07.9 398.0 20s3f36 205 1779 66.1 1S.1 ta7.s 1.7 0.0 598.* 2n8 86-1 a0 <0.05 <c"2s sr.1 4S0.6 1S.6

m6 /,U 105 I r68 31"3 883 74.7 tJ.iJ 4S9.0 98.9 44.8 93.t) <U,U5 4),A 441.8 335.4 1 n R 3 -

rc7 2C6 1888 '!2S.9 86.6 r01.2 s._o 0.0 360.0 %.8 1 1r.5 ,24"8 <0.05 <$.26 5 W J 45.3 303.4ru8 190 1523 48.1 l0?.3 t0P-3 t .7 0.0 4W.(J 2.?3.8 87.5 62.u <0.c5 <0_26 5@"0 s60.1 201.9rcg 7.1 rs 1412 922 820 92.fi l 4 0.0 509.0 { * n 10c.5 6.p <0.05 <0.2f 587.9 {t7,5 160,5

7.6 20s 1557 47.', ts3 5S2 U.Y 4?S.0 { ? f S i05.t) 93.0 <0.05 <0.2$ 70B.s 390.4 313.2t 4 t 8.0 r02s u.a 63.1 92fi u.9 u,u 4?1.0 13t.* sss <$.05 <0.26 4#.,5 3C5.3 0.0

Zg 180 1068 24.fr 635 s5.4 1.3 0.0 414.n 125.5 32-2 t3,3 <0.05 <0.ffi 3#g{. :r.'i{6tr i , E T

rq41 7.4 2S4 'i38ti o d n 56.4 :,N,0 7.8 0.s 4*4.! 4t8.0 211.0 t<.s <0_s <0.26 ,r insc,.,.lili.4 60.2

f4s 7.4 2& 'tB5i r28.8 632 t81.6 t,3 0.0 47S.0 284.8 18't.0 9.3 <0.c5 <s.26 580.7 '$sd.4 190.3

' fof,e rdxnrvo Xffupa s'nir$qlrryi"r'{iw$1 or. wd}rmr4 "nnpap*prrsf" rqrf.q evrii pe prll$ or "r:vie*artq"ur€pdurwrlq xmtn'&1"{os'yiq {Sf"K 630/812642007, 986/B/1 S-6-07).

29

qpeg vr4.o6

? '

i

.. .:

!f{ €h EC Cr lilo lle t( c08 HCel el snr il'le t|t}t llti Irlna6mn

Oturt Ildao6. llforsn

f57 2& !554 103"0108.S 70.1 22 0.0 524.0 188.0 97.0 e2.a <0.t)5 <0.26 ?{2.0 423.8 272.2

r58 , . 5 n1 1794 156.0 olz r40.0 L8 0.0 s&1.0 zffi.0 '138.0 4{i,5 <0.05 <0.26 658.r 417.5 240.6

rtr 7.3 206 173S 1{8.0 75.4 124.1 22 0.0 4S.0 afi.0 16.0 49.e <s.05 {S.?S $ss.1 4{8.4 t t t - I

165 7.6 t50 r39t 57.9 lss &,8 3-S 0.0 52S.C 137.* 5g.fi &.2 <0.s5 <0.26 554.8 4?6.5 138.3

f79 t . 4 219 1967 90.2 126.0 150_6 J lo 0.0 588.C 2&.# 172.* *.$ <uln 744.1 4S2.3 2S1.9

rs1 eft 1727 703 ?3.6 t 3 0.0 459-0 14S-0 303 12.4 <0.05 (0.26 4B 1.S 376.5 105.4

ta2 8..tr ?10 2C4i! 5e9 114.0 |fi.t 2.6 8.7 400.0 9nI) zJe.0 12.4 a8.05 <0.26 $t1.s 342.4 2$*.t

r828 I .tt rOt 3 1$5.0 7S"4 244.1 c.0 411.0 354.6 zOa.0 ts.€ <0.s5 <s.?s 57S.8 337.1 239.7

r83 t - 5 276 95_B $.s 6.4 4"4 0.0 017.0 I t . 6 123 (5 <0.05 <0€6 264.4 t60.0 1,4

r84 25S 5i8 89,4 15.1 8.S 0.4 0.0 3S8.0 128 13.7 <c <u.uit <0r8 28S.4 2n2 *t

i-85 7.3 ?4S s4g s7.0 l ? o t n I c.4 0.0 3&.0 2t.0 I /_b 8.2 <0.06 <0.28 2s0.3 8.9

t d o t86 863 75.4 co.t ?J.U u,u 323.S au.$ 4S^S 't8.€ <0.05 <0-& 380,8 2S4.9 r15-?

l 6 t 7,2 216 1573 201.0 3t;.7 89.4 $.4 0.0 695.0 1&1.0 t52.0 r83 d!.06 <0.26 6n.1 106.0 ?n.4

r88 72 246 s32 1t_$.* ?75 l3,D 404"0 64.9 54.6 6.2 <0.05 {026 412.9 t'r{ Q a t (

t8s ?ffi 1931 ;fd-u 93.6 101.0 65 0.s 50d0 268.0 95.5 24.8 c0.0$ <0.s 790.0 487 2 3C?.8

r90 7 J t 2{S 32't5 280.S 120.0 2*0 2.fi 0,0 639.0 M.0 35gS 34.8 <0.05 <0.26 10s8.3 524.1 544.e191 2S3 1212 145.0 48.4 319 f i 0 n f i 452.* ge5 543 a.a <0.05 <G26 581.4 na.7 r90.7

7.3 t7E 2380 144.0 13S 2ift.8 0.0 024.C affi-B 178.fi 24.8 <0.05 <0.20 663.9 511.8 1$?.2

f9c" a e 324 t535 101-0 81.0 2740 11"7 0.0 631.S 4&"t 196.0 3jJ'4 <0.(F <025 745.S 5175 21*I

rg4 v,? 167 2991 1?l n s59 g?c0 26^1 0.0 fi52 1) #8.t 35i.0 1?.4 <0.6 <0.28 6S.$ 5M.7 163.7

r95 a 2 276 1?s7 89.8 59.0 / \t.O 1 .3 s.0 453.0 1&3.3 a(,4 12.4 <0.05 <0,2s 460.7 371.5 tB_l

rs7 , - i 2y2 1045 83.4 613 26.4 J-U 0.0 4fr1.0 '121.0 18.3 12.4 <0.05 <029 4&.S 3i!5"4 1n3r9s 214 2057 '!64.3 1 D A 7 a n A n o 0.0 329.0 3n.0 i4s.5 ffi.i <u.Lqt <0.2e s32.1 ms.8 6e-sfin0 l l J ?41 1848 *zt ? a ( 1 73.S 4.3 0.0 {90$ i l9 .4 &2.4 l o,o 10.05 -n# 551.S 352.7 205.0

r101 7.0 203 ic54 t6s.r a 7 0.0 418.0 88.6 55.0 t8.6 <0.cb s0?€ 46S.2 t07.4 1s1.8

n02 240 l7s4 A t { 120.4 I s3.s 5.S 0.0 att n 151 .02&.0 15.5 <0.*s <0.28 65S.* 517.5 f 33.4

rlgS t . 3 204 144S 14ts.4s78 379 0.0 8fi !38.3 209.5 89J <3_U5 <u.zu ssl.s 240.3 4m.7

fl04 t , I 217 ts02 t([p c a , l 17L4 2-2 0,G 483.0 2n.0 212,0 24.8 <0.05 <0"s s14€ 996.1 218.8

r105 zffi 't500 61.9 10s.0 89.5 0.s 0.0 491.0 164.S 1520 21.7 <r).05 <026 810_s 4tr2,7 ffi.3

rt06 7 E 260 i707 685 138.0 t 15,$ r_5 0.0 7?fr.* JS.0 t53.0 18.8 <0.05 <0:8 701.4 590.5 1i0.s

r10f 7.7 280 1228 40.r 68.1 11ZS 2.2 384.0 154.0 1020 1?.4 <0.s5 4.26 380.8 314.9 m.o

rt07B tq, 1dn{! 72.1 499 ta? f t 4,,5 36S.0 26.0 60.5 4 t . t 03 t 7 385,6 ?,ff}.2 85,d

r1il8 t . t ?ss 1C6S s3.0 s6.4 ?8.7 1-3 0.0 536.$ 5{.6 n,0 31.0 d}.05 <0-tr 5ffi.7 438,8 oo.u

rrss 7.4 ?56 1W7 JOE.O 52.5 31.0 1"3 0.0 389.0 5S.9 3G^8 t06.0 <0,05 <0.26 4r0.s 31$.0 r51.9t1 1C 7.8 270 1osE rql.0 49.4 4i|.4 0.s 0.0 3S1.0 6S.1 {3.0 r05.4 <0.e5 <0.?6 480.7 xn.7 140.0

r l r i 255 1t22 s9.4 R n l 4{t.4 0.9 $.0 442.0 75.5 3L7 62,0 <0.05 <&,x 4&1.6 w.5 92.B

| | t 4 17? 101 1 1ts.0 40.5 31.0 t . J 0.0 376"0 BS.7 24.7 741 (o.05 <0.26 4*fi s08.4 145.S

fir3 t .o 257 t07€ r38.0 33.3 ?s.4 s.s 6.S 366.S €$.8 s0.s g0 <0.0$ <{I28 481.8 300.2 18't.S

n11 7 a 257 8C4 100.0 34.S ts.1 0.9 c.0 3?0.0 +2.2 I 1 . , 6tt <0.06 ({.20 3fr1.5 9S.6 90.0

n15 7.4 87 783 t01.0 5JJ t ? a 0.9 0.0 3S7.0 35.1 z J . v 49.6 <0,05 <0.28 8S.0 p5.8 7t.2

16116 7.8 245 2!BE t3a.o rs0 271_0 3_S 0.0 618.S ,tn.0 x2.a tgi-c <{i_c5 < u 6'1021.5 506-9 514.6

nfi 7.4 258 2087 1m-0 51-6 244"4 4.8 u.u J53.U 446.8 98.0 12.4 <{.c5 {*.?-$ 512 2 2St.4", .217.7

ff1S 7.3 2S0 815 n8 516 163 t a 0.0 423.0 43_4 €.05 <fJ.?E 406.8 .3rs0n20 214 783 5e9 64.3 e30 0.4 $40 24.8 6S 43.4 <s.05 <*.9$ 308 #;

'iin r f r .2 ,

rPr21 -o 1022 rm_0 48"2 17.3 3.0 0.0 16?.0 80.8 69.7 <5 <t.05 <0.26 4*ii, .r383:0".,?il.2,

rH22 7.9 167 25ffi 1t6.2 632 376.0 9.1 0.0 510.0 495.8 1S9.0 $ <0.05 <0.26 sfi{i4 :.)wis. 's7.6 , 'x' l l' I' '"/',:tt

30

TDS {rngtD oe

-a F 3

Ll3i_i_iScde of diarneters

h

(os

F

s\%i

+,8

lu

*srrk * 'P .f cr as,'aAvr6vraKsrr6wa

Ep{pa 10. npc$"hti l4p,ucdov cvc?"r5o'eav rfpmv rdwcrrv oe fir61p -,"rrr }

31

.. . t ' ' ' . * ; ,n

)

)

+ fl + f40 {' f115o 12 0 r5l o rQ110tr r3 tr r5s g l"117a 14 a 164 a r11gv r5 v 165 v 1120o fS o r79 o rP121x f7 x rE1 x rP122* 1 8 r f 8 2! 19 | r82B€ f10 t3 f83E f i l s r 8 4s fr4 a r&9E r'15 5 f86rr f16 { r87Dl r1? tr r8co r18 0 f8SI rJg I r90r I?0 ^ fS1v f21 r f$lv l?2 I f!3+ i23 + f-94o f?4 0 i-esfl r?5 s rsla r2s a f999 r27 V f100o r?0 0 1101x f29 x f102I r31 r n03I l'3? | n04cr 133 ct fl05s rc4 a 1106o m [ o n 0 7B m6 r 11078{ r3I 4 fl08D r38 D 1109o r 3 S o f i 1 0r f{0 r rJllr 141 ^ ft12v 142 v 1113s rQ47 s fll4

rS, "o

Er{pu 11.

*c" *o

Kqrt6vra.P- ., €-* s

Avr6vra

9

npofu)"{ plprCov aval,r5oeov nipuov rdwov or e{er6rranpevo 6litypap4ra Piper, pi(ryqilfiuo{t * Aa},rtoottru tepo{t32

I

%.t

F

%xt

Fs'H IHg

$a;FFgla$$H$FEx$

RES'F F,

1

\I.

CaTTC#3

*4qb

)i,;:-'l:)i,"-

r%F

otleI

I

9 0

x{o#1

" oF . E

" "ouJF

's dl; A

+ g

II

a 9 +X O

cl

+ f 1 + [ 4 9o r2 0 r5-tB f 3 t r r 5 8b 1 4 A f 6 4v 1 5 e r 0 5o 1 6 0 r / 9xn x rB1* r8 i r 82I 19 0 r82Sa f10 o f836 r11 H r84o r14 Q r85E r15 e 186

A , a € 1 " 1 6 { f 8 7D f17 b r88o r18 0 r89r r19 | fgC^ r20 r, f91v f?1 v f92y I'22 c f93+ t-?3 + r94o t24 0 r95rJ t?5 t r ru7a 126 A fpgv r n

" n 0 0o rzE o r$1x r29 x rJ02x rul r 11030 rc2 r 1104r: lSil o l-105H rc4 n 1100r m 5 0 r $ 7s rs r 11078{ m7 < 1108s r38 D 11090 fN o t"110r r40 | r-111^ f41 t l''112? r42 v f113s l-<l{7 z l'114

+ 1115o 10116tr 1117a 1119e t'.|20o rPl?tx rp122

EXttpct 12. fipofufur1 lg4prrrbv avolr.rloeo)v rc,uprov r6wcov oe uve*tuytrtfvo 6dypo14la Durov

33. )

rwl{ruuru r ut}lupillJf d ultiur tl4t[w rtLljyil,v

BIBAIOOHKHOlupnurd Xetprd - Sparap,are$dveq

136?7 AXAFNAI ASHHA

Y 8 *SggHBa

FI[]TilI Wffii ,#:. "

:L_. ,i .l+Flli .{

] , /LBi : '': i,

t+t

e.FF{

ll

g*g6FH3.$eEFH

F$=a\t +Fr ftFZ . ' Y t v

F€ fi$sng"R*

ffi1rcM, Karavopq otynwtptrmrlg.lf0j' rdwuv (ppm) 6rryv et)p{}r€pr1 neptoyfp

) 3 5 j/ !

Ivoato*ro ltr$r1trdv & Msrailflnrtfu lpeuvd*BIBAIOOHKH

Oltpnrcrd Xoprd - Spcropaxe0dveqT36?? AXAPNAI AgiTHA

oo o e

3 C 5 s _r F €

H' ' l l

.F

xrH*RH\oR

b

E

*t!

*

i l \ o- i a

$"!,3lr(>i

T3.**>IJl"iel

u

lat

atLF

:-thI

iwuttra isdrg$v & itnuimr'uttl r{Ll"ywBIBAIOOHKH

Oltrpntsxd Xoprd - $puxopc,rt$dveq136?? AXAfNAI ASHI{A

'dFi

It

\F

LT

i ls,3!

e*l

Ot acwposfortpot t6poy4ptro{ nwot (EXrtpa 10-12> eiivat Ca-HCOj, Mg-HCO1 CI-Na

rcr0Cog rc,t prntor3 flinou vep$. O rirncq Ca-HCOt *vrro'rcrypi as un61'em vepri *trreoqq

quoucrlq tporpoDoo{oq {'fesft Waters"} xur s,ficwrri }cupi$g n'u{ruq ap6;rc{ieg rrlg lldrpvrl0a4

cn6 tov i\po Orrlpri 6og rrry Aukitvs. Ag o4peuo9e{ 6a w rilpoyrTpwd. Tupamrypwnrcrbv

tcov vspov aur4; rryE Esptofllg, o,??11' nitctoytrloio. roo;. axorelnuv o4gda avatpop&E c4g

oitmaq; rnsv nrdyerctv vepcitv rrlE eupia:p'yq rctptayryq. Xra 6raypdpporq nttuq (E2gr1pa 13)

ti1/ot XopcKtqptorti$l q $lrcpn 6*ip.etpoq ralv 6ruypcFlrd.nr:r' curdlv q ofiotc, eivor wrifui'yq

tqlv cwo}"tKd, 8rui.alupevrov nid,nw (TDS) xa0rirq Kor q ooqriE enucpdrrlor'1 tiov

o(uavOparmrilv (HCOil fvuvn cro1, urolo[rrov r6wcr:v. ]I nnpouora rou o-uTr(€r(prpevou

u8poplprxori ainou a*iv neproyp r.rnpe$ar6ver ra nopiopcr{r ovogoprK& pe rqv rtvqoq mri

trndyeuu vepaii Kst rou€ prlXnr;rop.o{q l,aroupying corv uSpr:rpdpov c6rlpcaaprbv ;rou

avol.rl$qrmr oe npoqyof pr^e'vq nupdypfigo (rop&T p. 2.2.2.).

Toso r:uc& Frtra6 ra.l er*cipo:0rv rou Acror:ori 6{Fo rsr cn'cro?-irdrepc ocrl (Ctryrl

Owoc'rrizciv - Xgqpazapioti - AtliEcrq raparqpr:r:.'ar oza8taro1 tr.ri{riar1 rou TDS caw

vffiy,feuuv vepdx xa$Coq ror gcrdpa,an oe prrrori ninou Kcr $r trSaou Mg-IlCA3 vep&. To

rpcwdrperra sur6 anodr5€rol 0)-q eni Tco ni,e"nrsr" oa punoy6veq eo-rieq wCo o"rq nnprirnsg

(oveg qg Auii8uq Kfl,r rou Qpc,:noir unetafpyer$r rr{lfih.fov Kor o trrq76o.wop<ig qq

ugcl"puprriarl;.

Edpgolvc ps ro e{er8rKsupsvo Eutypappa Piper - pi6rc GXrlpc lli 6ncu F€ oufKeKprps\,1i

pe$o$ol*yin npoB&l"kvuftr oro rewprxd ns$i,o, oe avuo'patrrrl 1rclpgt, ot y1tr"nrdq

avntruosrg rer:v riiput'v rdvt{'rv {Aprpelo and Postma, 2{}05}, rars6eus/risr$1, lr?,r"1v a}.ofarcor,'

efo.tp€c'sr*v, 6ct S€r' )*.ppiive;r Tgilpn o ply"avmpdg rr"1c urputrpirpo)o-qq n}.iLrl ri zomrtrrl

xatdotaorl ratv tnoyeia:v vepdrrv c'e 6n uoopir aru. y]*iprowc eivar anor€leoiru rot &Mcriv

napoy6vtt*v peta{u tov cnoilnv rcur, 11 piwavoq. Aq ,i-nFem$ei Sa oe Selypura vepof

gpeu, an, tu. onoiu rlrav os drpeoq u8poulrrrl emKolovitx lts rcr\r Ar:alr6 or ouTr(svrpioourg

ttov f'copdvtcrrv r;rav q8q uyql,sq Xcipr4 va untipTpr Sovut6npa u$pou},rrqq earrcorvarviag

pe rq Odiaroaa.

Xe 6n ntpopri orrl ouyxdnvpatml rotv dto.rpitptty ttlvrotv oe peprr6q nsprntCooerq

napualpotfutat uqrqldg npe6 nou l-weppuivoilv ra Oeotrro8sqpeva 6pra m'0pd:arvqq

rcravdkoa4q t1 xoorp6'rqrdt. Or $ripcvflxd€psg rrrepFdoslg ?rCI.psrrulofvtar rrcr, vlqpm6

tdvro. (I$ip$.l,4) rcar ora yl"rrtpr6vlra (E$lpq 1fl sv{i} a{rdiofi eivflr rcr.r q ?rst}ctg[g

38

@orrysu$rqE-EsprcxfE-$tgk-qsl=51'{u vrcpzxti. Ksl ts. EaoEapwd, r6vrn c.aotehrrfu 8ei.rueg flTponpu$lE { aocxtlg pfnwoqg

evCD ro $roprfura Seixreq uonr1q prinavorl6 11 uqo)"pripaloqq. H ugal.pripoorl

napatqpeirat a'rtq nuprirrreg neplolfu rou Qpirlrori Ks,r crlq Au)"i6cq sv{b, 6narE

rpoavu<pfpgqre, onq ux$)"c'rne6 reproy"eq q au{rlpevq napauotc tov fuarprdvrrov sivot

m0wirssra anorfleapa aonrrlq q BtopqlmnrrlE pincal'o16. Ee 6rt oaopft orc vnprrd

tdwa nu.pcrqpofwar cruyrcevrpdloeq {rrlq rcur 6ry}*ioug nnd ro 6pro aootpdrqraq r{ov

50mg4. Or oaryrcewp<boei'; urrtdq aapar4pcriwcr oe 6?ir,; oXe8dv rqq lr€tjloypg lropig

r$ro.irepq uufr1oq rcov fii7tesvrpdaeo:v rou€ ss uEooo'qtrieiu ercudprr:0ev rqg rotuqq tou

Aoorno6. Erov r&trlno cr6 Aul"r6ctq raporqprl0nKs Tl uryql.drepq m4'rcfurpo>ot1 vrrprrd:v

r6r"rarv 1$t'i ps 186 mgll 11 onoic sxo$i8er&r ae ircrr{leq eodsq pdaavorlq. To yeyol'69 drn

ot uo[qpaveq trtxiic <ni,vrevrpdrrcst4 ro:rr vrrpwii>v r6vrarv Sn' cruvoDeilovtnr orwfl0o:E un6

a'u(qprveg ouyx*rurpdaelq tru;rnvril(cilv Serr:drv, 6norq, ra vrrpr'o6q {NOz) rc.r a;rpo:vrurcd.

it\rH4) rdwo, o0qyei ato anrpnrlpuolro 6tr outfq aro8i&owsr rcupirr4 oe aypoux€g

8pnorqpr6rqtsq.

Au{rlpeveq apdq ptnavrmdw 6errr<bv fifrporqpouwut rcupimq Suarcti" tr1q ndl,rlq tr*r,

Orlogir"urrrv oq yetiltprlcl f3 qg rcproyglq Xpuoomln$ Oprrrruori, 11 oroiu ot4

ouyrxpryArl reprofl efvcr rcr 1 ni4orcorepq orov Aomn6, rs06c Kfi,r ss nspropl rco

Xy;iprrapiou. H neprcA4 Srnru'er*r, Otvorpinrr.rv rca0<bg Kcr rl 3rpocvaqep0eioo neptoiltl

rou (2parrou anorsl.oirv neprolaq urpq?,r1q pr.xccrv'nrcflq emrierrrrdrqrflq Knr gou.ivsrnr vu

eqpe&(owur &peou, un6 tov A<rclad wCD ?l nepnyilrou Xlqpompiou ppiorcetur nlrlciov

tou opriwupoir XAAA

Or *uft1pfvsq oulqtsvrpd:oeiq qampoprnirv nivr*tv rdoo oe fteBupqp*vo nor*srr* vepd rou

Aoono$ (,Try122) 6oo rur st $ufKr:Kplprveq yurotprjosq rdao rl.qoirw tori Aoo:noli (t'94)

6oo rar rovrd o-ro Eplparip (f36), xarsEerKvfouv 6rr ro ol/fKeKprpfva rdvrq, sivnr

aacr6l,*o'pur ucinrcr6 rcr propry;avrrrlg prin*voqg.

3.2.3 Korcvogq r{dv rxvoorol;aiwvXe fur opopo oro l1voorory*sin, or Xqprx€g ervokloeq nm ?rpoTuoronorq0{ruv *qopo,{ioav mc

Crroo Cf*,17e, Al, Ni, h{n, Cu, Zn, Bq Cd, pi,, A-s, Co, I:Ig, Li, Sr, Ag, Mo,Sh Se, Be, v, Tl, poa,

B, SiOz, xar Oltrco$ Opyavzrco'{t A,'Apaxa tt fOC. Ta u.irors}'6a}rilrs rov plprrdov ovul0oeolv rcov

rvrrxf pu: qryooroq6eiorv napouor*(ovrol crlov flivaro 5.

,{116 nq avq,Litoeti aurriq nporfa'rer axea.xd pe q ouyrc€vrpool tarv 6roq6pov lf,voororleic].r,,

6rr oe oprop€v* nnd cr:r*. aapaqpoiwtar apfq nor: unepBrxivow rfi iietrpo0erqp.rvc, 6pru vspo6

uv0pri:nrvqq xactrvd.l,coorlg. Ot ngfg aurdg acrcqpa[vovrcr p€ olryKsKplp6vo o'upBo]"rop6. Me

r6rrcrvo XpbW enr.oripaivavro.r cr cvCorep*g t'rapn4t€-Fpuctq" uyi.c evdo pe pcol3 ot mlrixepeq

" Ftt 8 uxr tx-E -c" trgif 6 UP E K 6 3 fi / B/2 6 -&20 07, I 86/ Bl I 8- d - Z $ $ n.Xe 6rt cpop& oqv rutavopq r{rl\r enq.r.*1pouE rXyomorX.eiraw rp*xficrow ro ar6}"ou0a

o'upnep&opurn:

- Euvo'trxd ytcbpto (Crtoi : II rutcvopr! ccrw ouyrnrcprirosow Trou rpoo6ropiorrlrav

rapoucrd,(ovt&t $To tr-eprtl tou Eplprroq 17. 'Onct,; npor0rumr sno ra off1prr o.urii, or

rrryrl)"<xe peq ttgri:g napgrlpoulttll crrip' neproxrl rqq Aul,iEoq (1S0ppb) r$r {,roXou0oriv or

trsprcL€g eicatr4po0ev rou Aoconot q etpucprl reptopl roo Qpcxrori ra0C'r6 rur q reprofl

vorlo{w{r.roltxrl cou Aoarncnl fun6 r4v r€pr*/Jl n16 Au}.drvo6. H o'uy<:rp4rr,vr1 rcuravop{

ernpliret rTlv sKrtploll 6n orrq neprcodrepeg aeprnrcbs€q or a.u{qp.sveq &Drrq np€E rou

o?'irot pralpiou eivur cnot*l*ctrxr Brapqluvrrrlq pfxo.vorlq. Au{qpfii6q rrwq

nupurqprl0rlKsrl Kctr oq lerbtpqorl fi07 1 orcoia Bpioxetar rlr,rlo{cnr c4g xoi.qq rotr

Acoraof p6perr tou Ay. @oFa. )Jupnepaiverur enicqg 6tr or oriycyrpd:onc ror) o),rxori

S,pcpiou ?to1l 'ilaps,T1po*vrar or4v nepropl v6rm Ksr vo?toffv{xtc\)urrd .rou Aac,trou ti on*ia

taud{erar ps rI Buo-rrr] Ere60ovo1 Tqq pot€ rc)v r(cporuciv undystrov vepcbv rar 6p

aver."rq aurqE 6aoq q neprofl fuparo8trtr& cou Aoroao{ ftia$rl q nepro,gt] Orv6rlE -

Eygpatupiou.

- Or cruyxeepdtoeig rau tfaohnt*rlq y.pt*pto (Cre, napcuord(ouv Ksruvclpi av&itryrl pu uurq

tou olrrori lrcrrp{r:tr (IXqpa 18). Ot pqno-reg 14169 ncw perp{0qrov ovipXownr oe 156

pFb $rq ysdrtprloq f10?, q onoiu ppiorcerur nlqoiav rrlq Koirqg rrru Aoonuri pdpau rou

Ay. Ocr:p6, evib svdl,oye6 np6q napouonl(or;v Kflr or "ycarrprlceiq KC{r {fr cpp6nra orqv

nepwy\ cr16 Au?'i6ag. Yylifg erna16 npsc ruriryp<l<pqKsv Ket oe yednpqori riL,rloi.or qq

rcoitqq rou Aoeunof (f89i rccOri:q Ks1$"qv anpfuepq rrepmxq qg Aul6vcq, tilz0) ' ,t .'

4A

Illvottog4. Etyrcwtptboeqtyvamorye{wv

InpdoTEmoc Cr Cr_6 Fe AI lfi fn ql Zn Ba cd Pb As Co Hg LI 9r Ag lilo $b $s Be v ]t P04 F 9im mc

||glr msrOfi6 flioo..) s0 200 200 2A s0 r000 I 10 10 I 5 10 1mr l 85.0 30"0 1gao 1S0.0 <5 t0.0 300 60"0 72.0 {1 8.0 45 <5 <t t o 5S0 <5 <5 <5 <5 <5 <5 40 1 1 0 88 <0..9

r2. g0.a < lc fn sfrfi,4 <5 140 <5 48.0 86.0 <l <5 ".5 < l $90 <6 <5 <5 € <5 <5 (o <5 1 1 9 o o {0.3m 63.0 <10 EAA0 17f .0 {5 140 <5 7.0 54.0 ( l q5 6.0 <5 <1 1tl 470 <5 <$ <5 <5 <5 <$ <5 hJ

'1.16 8J <0.3

3$.0 14.0 r00B 63.+ 5.0 10.0 <5 52.0 J?R N <J <5 d <5 <t J K 560 <5 <5 <5 <5 r5 A <5 450 s0 1ts1 4.44i5 39.0 2S"r) 300 180$ 7.S 400 $.u 110,0 170.0 <1 <5 d <5 <l 14 900 <5 <s jil }F <5 <5 50 73 10.6 0.86

16 5.0 <10 <100 320,il <5 <5 <5 120 <1 <5 <s cf (l t20 (5 <5 ,45 <5 <5 <5 <l] (5 "14 <5 0.511 t 370 14.0 500 125.0 10.0 1 1 0 45.0 r05.s 1s0.0 < t <5 <5 {5 <1 n 720 <5 <5 <s t \ <5 s * 50 95 15.1 0.48Tfi t2fi <10 5W 90.0 8.0 11.0 <5 20.0 140.0 rtl <s N7,A <5 4t ts 840 <5 <5 <5 <5 <5 <s <5 s0 t 5 1 9 4 1 .1$ro <5 <,|0 <100 t3,0 n,a <5 5.0 14.0 73.0 {1 <5 <5 45 <1 1?. 400 <5 <5 <5 zA <5 6 <5 50 36.0 1.42

T10 40.0 40.0 <100 00.0 5.0 <5 <5 14.0 53.0 <1 <5 <5 <1 10 s70 <5 <5 <5 <5 <5 {5 80 56 38.0 0.37

r l t 47.0 $s <100 38.0 cE <5 <5 1000 66.0 <l :f, <5 <5 <t I t $e0 <s <5 (S <5 45 <5 <5 1!0 66 37.7 0.36114 v2.0 48.0 27AA 165,0 r0.0 14.0 r5 20.0 79.0 <l <5 <5 .$ (I 1 l 380 <5 <5 c5 {5 <5 o <5 50 60 37.5 0.3?

r15 <10 i00 3{.r) <5 35.0 c5 5.0 01.0 <l <.5 <5 <5 t0 210 <5 <5 r5 (5 <5 <5 <5 zfi ?00 10.s 0.75

r18 23.0 2S.0 440 100,0 <c 6.0 <1 <5 43 <5 { i 590 <5 <5 (5 <5 <5 o t00 193 21!. 0.62r17 t3.0 ts.0 6AA 47,A <5 57^0 63.0 <i 1lfi <5 <1 38 1S00 <5 sF <5 <5 <5 <5 (5 180 278 33$ 1.00i-1 8 6.0 4 1 0 c100 f 1.0 <5 <5 {5 12.0 68.0 < l d5 (5 <5 <I 5S 1200 s <5 <5 <5 (5 { (5 il0 114 43,8 0.4sr i9 <10 *(ffS t6.0 € <D {5 24.0 120.0 e1 J . (5 <5 <l 13 560 <5 tE {5 <5 <u <5 t00 109 28.5 0.33

r20 {5 c l0 <100 MIJ {5 17,0 <5 12.r) 76.C ( t .8 <5 d <l 540 c5 <5 q5 <5 <5 <u 100 190 208 0.41

r21 zr. <10 <100 48f <5 6,0 <5 11.0 $4.0 < l {5 <5 <5 <t 1t) 480 <5 <5 {$ -R 22 <5 <5 185 20"8 0.5{l

rn <5 c10 6UJ $1.0 r3,0 (5 10.0 43.0 <1 <c <5 qi <1 t50 <s <5 (5 rS <$ <5 ca 174 8m 17.3 0"7?r}j <b <10 900 8S.0 4?.0 45 1s4.0 P20.0 <1 ..5 <5 (t {1 s2 t3m <s {n <5 cS <b (3 & w 360 15.0 t^s5

. r24 t&0 140.0 8$fi 5S.0 16.0 (5 lM.fi 47fi {1 <5 { l 31 570 <$ <5 <5 <s <5 T c5 140 410 r6.7 0.6$

r2r> ,ffi,o 1s5.0 7efr 84.0 sS $,0 so 270.0 101.0 <l 6.0 <D {5 { t 1100 <5 $ <5 <5 .r5 170 s7t 178 0.fil

126 fii0- <10 c100 453 <5 ct <5 21.0 65.0 <1 <5 *5 <5 <t I 5 {?0 <5 <5 <5 <5 (5 <5 <5 3S0 510 16.7 0.Bt!

r'7 i5 r i0 <10t1 04.0 <5 € <5 1S.0 74.8 <i (S <5 <5 <1 12 s40 '$ <5 <s <5 <5 100 104 25,7 0.50

a8 7.0 c10 1tA 63.0 <5 6 <5 59.0 18.0 <1 .(5 <5 <t <l 10 t40 c$ <5 (5 <5 <.5 <5 m 3? 505 035

res <^') (10 <100 67,0 <5 <5 qS s0.0 ?5.0 <l <5 s <5 <t 1 1 200 <6 <5 <5 {$ <5 (5 <5 * m 13.7 0,7r-r31 rF <10 12N 180.0 <5 42"4 {5 BC"0 27fi <1 <s <5 <5 <1 1T 274 <5 <5 <5 <5 € <5 {5 165 10.1 <0.3

[ ,

il

t

l

I

\:

i

I

I

i

Ii

))4 l

f.!!f,

-lI

lr$fllwru I ulnuJKiltf fl lr.fl{rin&ut[trv qrt't Yu,v

B IB AIO SH KHGltp*r*r$ Xoprd - Sputtopcre$6veq

136?? AI(API{AI A$HNA

o o o- F o

s ' ' l l

xo*HF-:tp'{):5qJ

>sE

.$

-.{s

iJ

*.4.,-{

s $9 X S

F*srtr

$x{x?^-

o.F

it->s.sv

b-Fi

t5!L

\lfhtn

Iwnro{lto lerr$qrrtrh & Iileffitlsunxr? igttivtfuBIBAIOOHKH

OXtptttcxd Xoprd - 6paxopure66vrE136?? AXAPNAI ASHNA

*

.FF4t;l

a- --- -. -:,.-- -r,-l*--

F5*E3FSardg

FgTEll' e1n RoZ , I V >

FE NFst€'f i *

, ) 1 } * o \ . " o ' t . .

".r ,{trj\ \ -.:*r'- '

*J,rf .:i,tii --i{*, :)

' '' i-:,\. ;;\- .r''-1ftu. .' ,t,1.,. r,l)-i.::,^

''"'?,E

,**s4:-:.*:

Efipa 19. Karwopfi mtyritrpaoqE Oixoi ErdrTp*u (ppb) ortw xtp$mpq neprcgq )r6

$E',tl1L-t{{J i ffi*{IlldtgT { tyt"r0srltlttrixgty r+Ht}lljv

BTB AIOOHKIIOl"l g.nraxd Xa:prd - Spuxopure$dveg

i36?? AXAF}{AI ASHNA

o o g6

z'.lo

*o--HF

R.trRq)

;l

F-s-a

'tsF<({t)d

r-11 .+t]

$.g:}d

t}.F

*asHq l

j

(\I*

rg

Or ru{qpfusq suyKsvrpdro'eiq,rot s(uo0el'or:q Xptr>piou 7io? stpo$v{ripfpOqxuv errrp.&wr ;re

Bepur*rqra 6rt eivur atqv nlero4ryqia tou6 anotfleopa prnpElgavmtlq ptnavoqg'

H xuravopri rms Ohroti Etdtfipoo {Fe,'|, rapouord(er av&loya ,{gporrqptofird QXtlpa

19) pe trg rplyofpsv€g Korovoprsg sMn Kot pt aaqei'g 6rarpoponoqoeq' Yyqlfq np6q

napaqp{0r6uv Eurrxf ruu Slporrof orqv euprfrepq nepro,.6{ rrlq Xpua'onqyrlq (f1-f3, f4,

I'65) oe ouTreKprp.svq ncprc2grl rqg Au',\rilvc,q (186), v6trc tcov Owogrirorv (f12, f114)

rugCuq rot perofu X26rlpatapiou xor Auliffaq (f23, f82). H uu(1p$v4 oryrfvrpootl ottlv

negot'q rqg Auldrvcg (f86) 0o pnopofoe ernnp6o0era rru c';ged(etai pe rliv napoucrir tou

<rdqpornre)'rotl2gou ron&a'paroq rr: onoi;o tpEwi{erar eirr<pcveurri: vt}tm r1q AuAdovug

{Xeprqq 1) wrn or cu{qpn'eg rtp.s€ crnq un6},omeq reprogfq extqrd.tar 6tr crqv n}atoyqgirr

touq eivtn anorfloopu Bropryavm{c prinuvoqq oeoi otrvc$eirovull K{tt trrr; dtl}'ouq

purrurnrrori Seixte6 rur at{qirevaq auyrevzpri:oerq grr&}u}'rrw.

Au$lpev.eq qttqUueellou {Ni), napurrlporlwur ernrfpr*Oev qq roitrlq toti Acsr-onof xa0drg

rcrvotro8unrd rqq Orv6qg (Eplpez0) svdl Esv nopuapfl0qKev $116 neprol6g tqq Atl.i6cg

Kfrl r$) Opavrnir ot oaofu6 uwigera d6er{av oyqldq urq lfrnpiorr,r xai dl"l.rrw

r6wcrrv. lI mrgmercprpev4 raruvoprl ror Tropouolfl rou vu(slviou acnp6rur pt pepcrdrpa on

olerl{eru d,peo* pe prcprlluvrxig eodeq p}n*vaqq

OfuKd _s Opyaw*6g Av*parag (TOC): I{ napoooi.o Kct Korevopr! rorr O},txo0 Opyaurcnl

Av0para ano'telsi Eskrq punavoqg rov un#geiciv vepri:v oad *pynvtr$q evdloerq. AE

oqperoOei *rr 11 avilvzuorl rtrlv empdpoug cpycrvrr6v svriroe**' ora vepd umorsfusi 6re$vd:q

pur v€u mer).f1 11 onotu oe no)"1J6 nepmr/ooerg etvnr q Fcaucft urticr ryxat&letyqg

ysarpflc'ecov rifiparorlq (Appelo and Postma 2005, Miljoprojekt, 1998). Xap*rct4pra'nr6

or,,arpf,p*ar 6rr ato E$vrxo rm Euparna?xti Oe<lpmd n).n{<no (OEK 630126-+2{}07)

urprord,rar q npocofi Tro nlv aepouola 11 earrfuA$vCIv opysvu{d}v ouordvv otott6 u5urtlcai}q

a6pouE ev6 q USEPA (hnp://wwev.epa.qovlsafewater&onteminants/index.bFnl)

emorltrrafva rol' riv&wc napouoiug oTo undrysro vep* trrtoq l,iotaq neprooor*porv unir 90

evrilseorv 11 arcotr uuvel6E au{*veu Or pro6q ruepinou and audq efuor opyuvrxAg evdraetg

Kar6nrv rorlrou sro, nisiora qg nuporSoag s/oyvioplcrrr{g p*ii:r4q rpt0qre or6arpog o

lut' upptv 6Xep6oq rqE rropoDofag opymnxtiw wriros(r)v ma rin&yetc vspd qq fisplo1tig F.€

tov npoa8ropffip6 qg cuyrfutp$oqi rou{ ss TOC. Or petp{aeq f$srf,uv u.pqMq.'npfg,

6cog rur 7.5mg/l oro vepd tou Aor':coir, ruOti:q rcctr nu{rlpeveq lp$'yrtorpIafi{

49

erodpalOev rr;6 xoialq ro1) Kol erio'r1E oe Teoxprloerg ot ciroieq 65er(av cvcimorlo ut1lr1l*q

otyc6r'rpd:oeiq rcar dr,Lkuv ptraoydvcu:v ;rerriM,c';v sar rcvrov.

A)J,a pfra),).*, apotv**} (As), pdiaflhoE Fb): Au-Eq$sveq crp6q cnryrewpd:oeov

uponnron3 rnu iro?"up6au napurrlpq$ryav oe p€povolpfveq yea:rpll$EtE aiqolov rou

Aoonof ro0dtg Kor o'e neprol€g Eg4pn:apiou Oworlinr*v Kol Aoldlvoq. )Juyxerptp*u ottq

yearrpfloerg I-8, tr'3fi, I.39, i'61 xul 1 94 aopaqpfl0qK€ oo€qpgq $rft(sr.'rpt:or1 upos',uca*

evr": acrg yeanp{oeq T17, T87 ro:t I-92 nnpoqpl$qrcsv otr(qpeveg ouyrewpCoo'eq

pokipEou. Or neprarriroeq uu,dg s:uo$iSovrar ofllv rrXsroryqrpic rouq ds oqperar6q rm

Erdgumq earieq BroprlX*vrqg prinuvorl6.

3.3 EmoxdrrqarT - A$ailfyryoq rqg napouolo'g rau Cr ara urbysawpa,

9.3.1 fsyrrd gustKoxqpmd yuptrxrnptfirxri rou CrAoya: tqc ar:{i1prev4E Sqporitdr4roE Kfir tqq uvuprev6psvqi atiara^0qoiag rou x*w*6 olenxd pe rq

pinavo4 u6po<ptipr*v olqtrraacp.Crw arui t{w#i;r,i; yprbpzrt, otrc unopsveg atrpuyptrtooug

napariOevrat opiotrrfva BrBl*rryparprrd Es8opwa Kor ovCI,pop6q olecm& pe ra em.p.*poug

quc, Ko1rlpuc* lapcrrr4prcrrxd, Kfir aq fircrt4re6 r*u.

Tu quotrcoy.tiprr* liapaxtrlpro,urd ror: lpcopriou ae it?*;6 rfii rt€ trr.optpf:6, q ro(rxorrlrd 'cou. or

lre0o8oi"oyieq unorcurfic'ro$q6, raOri4 ra,r 6il.s <r;erir* cu,',*gi{ovtfrr s€ pu npdatnorq,

aitdioy4 epyaa'ia ci$v Guertin et. al (2005). And qv epyaoia autrl ra$drg rur arc6 *ltreg

Bftwypotpr.r*q'Erlye; {H*m, 1992, De.utsch, 1997) r:q;rsdovowtrt o'uvoncucri rtr *x*?uoufi*.:

O€et&orwiC n*aractdoef: -fo Cr efvar yva:err* ce $r*.rpopeq rovrucriq rutufirdoer-q rucu nomilouv

ufi6 4 6coq +6, olfi& mr1 fliorl o-uf'{Stog cnovr& pdvo cng o(erSanurfq xurnr*ooerq

Cr{0), Cr(NI) rcat Cr{VI}. Tt: Cr{$i ascn,Ta sn{ivra orrl Vf$q rfir s.nd na},ioiiq

up<oto'fhiteirtr axopq Kut rl imap\i1 rou. Xuvrnoq ro ev$rnrpepov DrrlKilnp{,bveru1 oro

Cr{{I}) KilL nro Cr{V'i.). To Crfl$ anryvr* }is rq liopqfl 1pcopr,or11er:v o{*dirriv ({Jr2#3i rut

uspo{er6{rov (Cr{OFI}) raBt'rrg Kur $,; 6talrlr& rsndvrc CrOHZ* rat Cr(OH)2* srrir m

Cn(VI) pr rn irop{pq -gpoi:*criv {Cr?r2'1rar Srgrcuprxttv {Cr2Of I astt*v-,tw 11 *r6p.q rar

coq lpc:pmri l3&pic {BaCrOaj ri $r1p*:prxd vrirpro ( NzCrzoil.

Ilpoileuoq - Oumw{q Eqyeq Cr(IIil rcat Cr{YI): "lo cleifro rau Cr({il) unors},€i pru rl;rd aq

Sfrs rno Sra$r,Sapfueq oucteq oro 9l,o16 rqq ?qq $acobs and Testa, 2005)- Xro

yeo:3."oyir6 nep$&l^lrrv ug$ovei oe ?xuprTsvrl ruerpfopata (yf,$par, aepr&adrcq. Souvtreq

xcr m:p6{evor) rat $s qgs,rof,erurcd (f}ao6}*egi. Evtoai(erar cw40a4 ce unepBaomd

?ruprysv1 aerpri:paru {x.1. ogrdr}"rOor) xcx,(}cbq K$1 orfl, per{rpop$iopwa rco8rivapit Torg

6ncog enicrlq Ksr $s Suqdpoug rrinouq ogr+rcri"i{}rov.

Tesglrqrd;q - avfip*sxoyrv*fg rrrlyl€ p$xavsry;: Or pnr;-rr6*peE ipflosrq rrriv fru.ql6prov popqCrrv

1pa:piou eivar {Testa, 2S05):

Cr({}}: napayrrryrl rvo{eiSanou X6}'uFs, xpapdtrrw K{n yanni perol"lougprfl

proprllaviu

Cr(III): MeralJ'oupprfl pmpqlnvio, arrxd,fuuyq Sourrrirv uX,ncdlv, earpercD,rboeig,

Bupoc,6ery{4, Dgu.r'rooFryifi , x. c,.

Iwffs{ro lrll$qtreh & il{mad*mrrrw FpewabEIBTLIOGF{KH

Ot upnard Xoprd - *puxouare6dveqI3[77 AXAPNAI AS}IHA

1.0

0.8

zH o.txa

Ct{W}: Emgeta}"Mooa4, $upoo8epin, uqmrcoupyiu,, fi}ner palrocumrcrbv prllovrirv rc.c

Ifepoaoia ora ordyeta vspa, pryXnvrapot o(ei6a6q€ - avay*y$E: Oarr.rg npoavotpfp0qre, ro Cr

c,ic*vr& cra uxqrenr vap& 16oo arq C(Itr) rar Cr(VI) oe Srdcpopeq pop,+6q rcrr u$po{ei5ta-

Bsorxoi rop&,vovreq nou pu$pi{ourr rr1 mo0epdqrd:ou (Efnpu 22} eivutw pH Kol ro

Swrrprr6 o{erSoerv wtrryhq @h}.

0.{

Ig o.au

-{.3

E3 -s.eclUJa r .

-s.s

{.8

pFl

EXrtpa 22. Ilt6is. ma*ryorryra; rct ouawqparoE Cr - O - IIrO oe hwytrtagpu Eh-pH (Hem, 1989,Motz,er,2005).

iMe 6uroopol)l y€ct1llrffior)€ lrqy"rntop*irq evilloe4 rou rprosevodg 6mpiotr (Cl*)

o(eriri>vor"rur oe wciioeq cou e{oaOevorig lparpiou {Cr6") ro.0dug xor avtimpoo& ps ro

plypvto;ro r4_q avolcrry r1q.

Ket& rotig Early and Rai (i9S7) Kur Fendorf and Zasoski, (L992), q ofei8omti

tpro0evofE gpc:priou oe si*.o0sv6g p;ropei va orp$si as rceptpfil"cv pe oteiDt* rou

uorynvionr {napoAotoizryE fr-MnOzb}, ttntpvwftrle 6-MnCIz$), rcpomolttilava6 a-Mnotb))

<--$;roaiv* irs rev avct$p*crq:

Cl* + 1"56-b{noz+ HzO = HCrO,l + l.5Mn2* + rf (t)

Eoictt-c o{eric'rrr:rccg nap&ywrnq eivcr rqo,r ro Ern?rtrpsvo o{uydrro s$"6 oe nsrpd,pata nou

s'),wov an6 roug Fendorl xs.r 7-azosls. {1992} Sramorio6lxe 6ft etvst e?rouordfio,-rg

otlFtcotcq.

Xs fin orpopd crqv rwqrucfl rov o(erfioovoyaryrrCov awrEp&asrov (cnprtrlra Ste{nycrryrlg

qg avrifipuoqg) avupdpovrc{lru e(f1q (Motzer, 2SCt5):

- To ((In/ o{er8doverat ot, Cr(Vl), o'rntiea;g p€ "rp'

rco.zalucrxtl smi6pao4 o{cr$ir*v

rou rcrpoo0wotiq payyavtou (Mn(lV)) pn aleru<& apy6 puO1ro t172 nw npaivstnr

utt6 $,58 hr:>q37,2 tcq.

Awio"cpotpc, r1 crvriipuoq avuvaryr'1guno Cr(VI) oe C{III) civflr Eal.6 ofr.'copr1 p*

ttn :rou eivu,r o'ur"qOalq wcapmi.oq taq 53 1;ubpaq oe cvuepdpreq { av*y$yrrcdq

ouv6{rsg. Ee aepdBrsg ouv'0r1re5 owr]Oa4 nipaiverc,r sn6 llnin twq?l.5 qpipeq.

Tofircrirqral H 8repeuvq$I ro1.) prx8poii cqq to{uc6rqroq Sw sno€\4i arffirsf[r^{'.!'o niq a{r$e1}qry6

sg€lgg alJd yrn l,oyouq ripeorc avurpopaq, ncpcriOwrar otr1 or:ve1elo, cuv,c?nir{l.

peprxti aupnepdopsru un6 rrl 6u0v{ prp}"roypcrpia. To Xpiopro, uvdiuyu ps nTV

o(erliartrrcj rou xur*orcor1, ert<pdper Oenxfc q upv4nrfq ernzcrci>oeq cr,q nv0pduminl

uyeia xcr orrl Erurporpri Tevrr6tepr

Ee dn *'popd, mo rpw?evtE ytrbpro, Cr(tlIi, m BiBl"roypu<prrdr Ed0opws <Seiprouv

6s xarrf ro pecupo?,,rou6 aaswo{t'ror pxporoo6rqteg g:ctlpiou cog rXyoatorleto.

Xupd;qparpoard pr.e r4v rvoc'uiiv4, ro pxiipro o.'';vetcrof:pul orq psit*ol rou

amru*6oD 1trtr.i(r1-c oro uipa Kor lprlorpoaornitnr Tro rrp crv"npsrii:nror1

ouyrercprpevrov popgriw 6rupqq. To grrbpo sniorlq Aypt 1.pt1ot1tonarlOei orq

pf,{CIon rqq 1o}.r1orep6lqq pr.erdworraq tqv nvenr$0ir{tsg, Isp'qfuq6 mrrv$rqtcg,

Lurorpt.*r*;tveq {LDL.I oro aipa. Anorei*i olortr"nrd uprcerdlv tJxrqrhv dnri:q"ron

p,rpdrco3,ou, q6 poyuiq r\t u;r':1pu* rou ouKcDttori, tr'-u ruprori, rc:v $4p4tprardlv

r.a" H elfT"rorrq l1r€p{als anaworipevq noodrqto oc4 Srntpoqr] ropaiverat un* 50

6oiE 200pg"l iJacobs and Testa, 20A5)-

H to(rr6qro tou e{aa'0er,'r:rig y,prrl;ri.oo Cr{VIi siapriitni oe ufi6 rcv rpdso

np6<slqryr16 rou Ko1 rlg s1errlceg ouyrs'vrpdcetg Aev r:n*pger apqr.polfa fut

rcecprfi xsr firKr'& $ut{rpatc ef,cn8evofq gparpfuu eivcr cprcetri rof,rxrt rar

s?rrxivfiilva yrd fllv m0pdxnvrl ugain. Et4 otryrevrpd:crer6 6poq nou ancrw* sra

urdye.wvepd or an6rpe6 e 6n arpop& oqv ro{ucfrqt0 tou,6tiottwrut.

Erov uvOprirnvo opyavrapd ro e(,uo0avfq gr(opro ptrop€t va erc6f,0sr and rpeq

Sffiq0pe,nr*q SrS6oug ('ufKtt(pwro, ond ro ndcrpo vepd rar rq frarporp{, an6 qv

em$epp{8a xar crnd qv avanvofl poluotrrAvtiu arpl}s{pfitprxori cxapu. Ilpdoo*reg

${t}.r*ypurprxf6 ovngcp€c {WHO, 1988, Guertin, 2005) $*ilvouv &rr q p6vq

enrxfv0uvr1 xar $]anrtrxr{ eioo0oq arov ogyovrop6, e{verr T ovorweDcttr{ oESg.

Eu;rsrprpfva:

I Eso ndaqro vepo rcr arqv Etuzpotpyl, to e{aa$ev66 g:d:ptct petttpFnetct

ar6 to yflrt[pswsi]rttr6 or'lorrr*;:n, ol6e$dv crraptrrta x-ur e{ oiiorirlpou, oe

. rpc0ev6g Tpdlpro ro onolo oe lapr1ld,g noo6qreq eivat ar<pdl,tpo Tto rrlv

avOpc,:a*t1 rryei* rcrr <ruvanrbg nurlervc eivat ro(rx6.

' Kfa av&Lcryo cuppatvet Kq,t ps tqv etoo8o on6 qv eafeppi8a. Ilapd to

Tsfovdg &n ro elco'0ev€q ypcopto etc6ple, *t alr6 aur.{ pe tc,Xtrqta 10.000

qop66 pryal"rheprl ond ro tpro$nr$E, Kot ctrlv nep{crcocsrl cucd avdletcr

srr;6 & c{pc ae rpro0evfg npw ond rqv o.nopp6grlsq.

H p6vq ealrivEtvrl eiooDoq $rov ogycrwop6 eivar lrs rqv nvarwofl. Ktrt*

{ry offs.7svcq po}.rrcpdvou adpa pe e{uo0ev€q 1pt'r:pro, nopd ta yeyat6q 6n

6va ncoomd 53 6CI-c 85cle e{uaOevo'r1g Srttpiou "rc0cpt(erctt" 4

anotrroxpfvetor sro cipu,, to undl"ouuo 15 6<19 47Vo nupep.fver or4

rurye}.{ieqTcriv rcvzup6vov Kot anotelet to(rx6 - rccprway6vo nupdlort*.

T€lo6 oc 6rr flqop.i arqv $opi6c or €rilntlpovrr6q o?rrrpq ouyrHvcrw

orc otpn*pilspo 6rr ro e{oc0eveg ?Cpd)Frrr Eev pnapst vs uv€},O$ aro

urf,gyew miar4pcl tw <pmril.

To 6pro roorp6rrpoq fior) €;gti reOsi an6 6u0veig opyuvtoporig, ugopd to owo}-txd

pdpro xar ov6plerur our.'f1Orog ota 50 ppb flpirotporu 6pe.oq q USEPA xptvowuq

6c'co e{ao0ev*E XpC*pro 6w oupnepr.}appdverar rMov sr$ Keprivirydveq ouaieE

nou oncvroirv cro adcrpo vep6, air{qae r* 6pro rootp6rpaE tou o},txou Xpmpiou

umo 50 ppb oe 10fupb {hup://www.epa.ggvr/sqfeyaater/contaminants/index.hunl}.

l$prgo:vo W 16 otorleia m:,d or Drnnlnr*g enrntrbcer6 oa6 oufrlpfveq ttp$g

?gpCIpfoD oro n6ot;x: vrpd nepr*pi{or"r*rr aqv n}.Lc1ryrrr1 Eeppct{cr8b :

F.t

t

r-t

iT

r-r

r'1d

M&pa- fiuwttrq@ worcmdtr*aqt' Ta pErW crcorurd,orooqq eto,gtbvzw ndvzoa ad rq

g6oq rcar c4v 6rcreot1 raa npofltiparoe ffol s,*mredv oaryfi xat )anopcptl yvdtq too

enftmore tfipopa)CIyueod reprf6J,),ovro€, noJ tuv aandr phnavoqg. Ta enavop0a:'rtrf

Fsrpd olvoryi(ovrat 6s rpelq EraEopunr€q rtt?€lsu\rserq, se p&pa rspwpwpa$ uyE

to{tx6t4*g, (fxq\t erop*rcptsvot7 rco pisxou ei a$ po}roopev4E pa(aE Kfl,t ss rqtnrctE

mp wp zs po6 xat arrc,udv wn1 g r4g poAtolttwtg 6xras4 s -

Ilepnptopls rrt6 ro(rrdqra no p6roo: E:nnrg&vsrot p€ perorpozr{ cou

ro{mori e{*crOavorig lparpiou oe cpro0ev6g, pq rofir6 gpdlplo 11 pe reproprcpd trlq

6rdpxao6 er0aoqg tou rclr,q0uopoti c,q pXartrx€g ow€rertq rou e(co0wofq

propionr 6noq yra ruapu8erypu p€ $sproproFd Xp{ong tou poluuopiuou vepo,il tr>g

r6orpou ft T|tq sr0eallg rou oe po)''uopavq epyoru{rcrr] ctp6orparpa. H cvayr*yq

tou e{ao0svorSg prop{ou oe cpioOev€g trrnope{ vc erntcug$st p€ Xptictl avoyrrrymdrv

ouad*v 6reo:q evCooe4 Oeiou rcat a6{pcu. And tq *ta'ir4 uadq lopurt4pronr&

uvcr<pe,povru,r ro Sr0srucd v6rpro (Na$z0a ) m nol,r$arn{r;o vdrtpm {Ca.St}, to

uno0er66e6 v*tprc {ifaaSe0r), m 6{rvo 0ardr8aq v&rpro (NaHSOi, o Oeulcdq

o{8{po€ (FeSOa}x.u^

Anopfxpuvoq tr1q p*?'uopf.wq6 p&qaq. l"I 4orcmfi curri atpopd aite sflTv

erorcagd rar unoprirpuvoq n16 Foluop*vqq p&iog rou e8*potq tl orrlv dvrlqoq

rat ene(epyaofa tou poluopfvor rlsatog (pr*tp a*d *eat technol.ogies)

Ilaplopr.cp6g x{r,r, aacp6voraqg qq pohopdvrlg 6xtao4g Agopf strov

xeptopropd StGSoary ?qq pfrwvoqq os peyul$tepq 6rraor1. Me rep'qr€g

raruoran66, dna:E ps (clveg neprnprotrr*vqE ttiiponspctlr4raq (slurry walls),

Kooyrivag ran!€vre?foerDv Kl,n. eivur 6uvatdq o repmptop.dg tou pinou row* otqv

eodo rou erpdoav or u$poii8olopx*q cw0flreg Kor Tl 6rctuor1 rq6 prlnrt'oqg to

ernrp6ruow.

, ' '

t,

1i

.*T

t

I?t

1I

tI

II

I

II

55

3,3.2 flt0uvfg rrqy€S C(llD rrll Crrr(Vl) orrlv rreprog{Or lrr$o,v*q qyfq prri*uvoqq nnd lpdrpm rrrw undyeiov vepdrv qq euprrrtptlE St*,xpivowar oe

guomdq xar r*grqrf4 r1 av$pcrxrolevstq.

a) tfronxdqqyi,E

Xa 6,n ugopir e-tl.4 Etnrcd; n Ng 6norE nporfirter cn6 feorfqprxd Arl'crws rqq Eup6,qq r(Dv

FORECS (Forum of Furape** Geological Surveys) o oaotoq SXer {611 $rlpoareucei oto Eu8{nruo

), L6yro uw m[qpsvov asyr{s\4gbo'errw rou Xpopicu nou

anuworJv at* efid,gq rqq Tl XC$pui pog, o.ro pe*yul"rirepa r1:{p{r rqg, Sa pnoporSoe va

Tgpurr4proret aq " yrb pa xto yttoptou"

Etu e$&ry1 Kot $?u narpdupotu nig eupfzeprlg *epioflq uv6ra,rpfpovroE or tptiorx*q ?ny€q Xpc)lrifl)

ewoni{owor ora Srtlgopu ogro}.t0rrft nerprbpara (O) noo copeppd}..Iovuar ouvt${r}q g.era$ rov

Kpqa$rrdw aoBeorol"i$rr:v (K5a.ft)rat rov onoxer!*vs.trv *qroh0rrdoiv Frddlv t'1 erriv TpuSrxo-

Iottpuo-ucdrv aoBec'coli8cv. 'l'a nerpdlgata outd 6pilq Bpionowm orq nopup&q rar 6p.r mq

orw{ repw;{ evdiu<pfpor"ro_c rou Aournod norcponl.

0) Ttyvtldq- avfipanroynel; tdeg phna.voqq

!'l mporrpq napffi rou Aqconoi) nsp),,uppftver peral,l,atrnr6q xa,r 6),X"eq proprqgovrx6q

iipuotqpr6rrpq or onoieg aaorelorx 8wqtrrfq sorieq ptravoq{ lptopiou, vrxeliori xar fl}"ov

pstdi.l,rov. Ag aqtrreirr:Osi 6n rur* rqv naporiou epeuva ryuv aS*vurq q 8erypamhqryiu mr6 q

otw{ ptopryguvrrrl (<inq Orvcqt}rrov - Orvorlg Tw rrl Erepetvrlcnl Kor rfioronoiqorl rug6v

prmydva:r' e6'nd0v i,6yrr: rror,r 1p{oecw Trlg, Tou t$rorcclotarcof rcs8es'rdilro6 xfit 146 onouoiaq

oqpefal eleygou.

Ilporalei enio'r1q svrfncon{ Ko1 q safl)o[il e{aoOevo{:,q xar o}"rxot lpolpiou oe Eefipnrc rou

ndpOqruv an0 to [te$npr"rgrp^r.vo xst Edooopd rar vepd rou Aamnsr] (fP96, IP98, fP121 rcr

fP122). Awi$eru 1)VqI6q ouyx*.rpdooer{ ilpco}.r{ou xotayp*EqKaff srTlv erpmreprl naplo1rl rnq

Auii6aq reit uxoLouOorlv oi :r.epio16g exatfpco0ev rot AaoaarS 6c,r6 qv ruprkaprl reprol.{ tou

Opc'rnon3 ro0rb-c Kfil t twpw#l vorroovoxol,txd cou Aoarzorl fa4 rqv neptofl rqv euprireorl

neprofl qq Aullovog. Au(qpfveg trpreg nuparrlp{0qrav KG1 atrl 7ed:npqotl I-107 t1 orcoiu

ppioxr-tcr nl"qai,ov 46 raiqg rou Acramo0 $drpera tou AT. 8rr:p*- Knrbwv rofrou

rn0avo),oysirui 6rr or oufrlpfr.'eg npeE Tg.popiou ?rou napar4priOqxav sivor arorf,l,eopa

npoqyorlpevrav prnmnrdv mrppftwrov f1 eoncbv pfravaqg rou 6w radmrl Ewat6 va

emarlpavQofv rc4v nuporSce avsTy$)pr<rrrx{ €peuvc.

II

-_,_l

-56

Ivonrofrs ffriio$ab' & Mfi sihmrtrh gzuvr&B IB AI O OHKH

Oltpnrard Xopld - Spatopare8dveq136?? AXAFNAI A8HNA

Otrotrd e{ao0evdq Xpd;pro 0c trr,nopofoe I'u nporfryer rsr cn6 o{eiDrool rotr rproOavo0g geo>ptou,

napaunia der6otrrxdov nuprxy6vtCIv 6roq rcr o(ei$ra ror' lrfiTywioo (MnOi ofprpo:va F€ rtlv

avrt0paoq l.

+ fl + l-49 r l'ltfo m o 1 6 7 o f O l ! 6a r u t r r 5 8 o f l l ?6 f 4 ^ f 6 4 e f t 1 $

" i-5 e i'SS v f1t$

+ f$ o f79 0 rPl?.ix i"? x f81 x fD'?.,* r 8 r r 0 2s i-9 0 l-8?8o l'10 p fE3a r11 I rE4. 114 . f85r f i 5 r 1 8 6< 1"16 { r87D 11? 6 rd86 f!8 e i$9r |.fs i i90^ lzt) ^ igl1 t21 a r92s r22 r f33+ l?3 + fB0a r?4 0 r95a r25 n r97A f t S A r u ge r21 e 1100o r?8 0 f10ix f20 x fl0Ar tilt r fl030 13? 0 rJ04o R3 a f'105a fa,{ 6 i106. ,r35 . f$7a i36 a r10l8d i37 { fi08o i3$ o fi09o f5* o ri,1*r f.{C s i111t 141 r l-i12i 14?

" f113

r f${? : f114

EXtil.rc 23 Ilpofotrrl {i?rrc*ffi}u $€rpfl{t€o}v pH rcat Eh ot druypuppa maQepovTt*s ilrxgd,pCIvrcaraordss ov wts yt w piou

'Orcol6 ?tpofrillys 6pcog crc6 rq Xqlrtreg ovcltceq Ssv ?ropoxqpouvror Lfiurirspo u!nii,6q

oL:TrcernpriloltgMn ora un6yew vsp* crke o{er6or:rr* Ph-Eh rep$dX"lrrv"o nor} vfl ewoo*v }rw

sv&l,oTq avti8pcaq ce F^eydl{ 6rcaoq. Erciorlg 6rco:q apofictEc ofi0 6$tr6ttou psr,}fi$eqrcu pH

Knt ro1) Suvapmoi'r o{er$ocwuyrrrytlg E& tl.pipn 23), or o{erfi*rxvc.yrrryrx$q orwOflr:q rau

flnKp&ro$v o"rfl rrdTflo vspd sul'sorh/ rr1 oru06glrqro ror) rpl.o'Ssvo*q ?g)op{ou tC{HOhGd)

xut Cr(HO)2*1 ror 6p rou e{naflevo,r'4. 0{et6oavoyr*ytr6.; or**dreq ilvoIKeg yro rq {pusu{{

paturpontl rou rproesvorig lprsptou o€ 6{oo0svfg ruparrlp{*qr*v oe 6eiyparo rclv yecocP{o$e)v

. ,' .. . '-.. ':

0.5n!e/l oi$ntvbdCt

SrStl llir$lvEdCt

57

I?2 rsr f2?. Xaq ysrrnpqo'er4 aurdq 6prog 6av mruypdgrpc napouoio Xpoltliou ctOwdv i"t$a:

anouaiaq npunoyevdov nqydov Ksrrqq X{xpq?"{q CIuyxfvrparorlq a{ar$ian' rot p*yyavicru"

Eais'tg q Xpiaq rou yeCIplprrorl powdLou "PHHEEQC" parkhurst, and Appelo, 1999) yto rI

6epefv'qoq rqq srot1€urpsrptaq {speciationJ ro}v 8raqdprr:v rswrrdrv xscflor&ae$v trsu

woF.6vowo1, $€ pd$4 ra ororlaio trw plprxdov ayal,foeov ?roCI rpoy!.rssonanl$riruv, 6$et{e 6n o

8efiaqE ropeo;ro{r {sa*ratinn indac) o}€ npog eov mpolor"rofq (4,e{6u roCI lroyysviou) eivnr

rhrrwa aprvqrrrdg yeyov66 rou osqycf cnqv ercfpqaq *n q nopor.roio roD rnvFKs'Kprpirucu

nerpdtpatoE 8ev avapfvsrar orilv nepu1{ 6pzuva6. Iwendrq or suTKswpCocetq grcopiou nou

ra,tuyp*grlrav rrr4r*rut 6tr oc4v mLeroryqgio rouE aivat anocfXcopn ptrno,vfurirv *csrdrv. H

6d0eo1 Btopqlavrrdiv uroplfpaw oe yerorp{rsq Kor oprlrypsrs rl.r1o{ov xu,r eirudg rqg

propqlonnffi {6vrlq, 0eropalrar no[6 rr0avq

Iu 6ur06trrHfi c'totx€{s xs} o sfesud neoqoro}rdpoc sp!.Opoc Tsa}rp6os{rlv*Eery$flro?',ryt{og ofil

crev4 $ro$rflsvrxt (tiruq. SFv a&rpfrsow filv rsurorroilo'rl :crv suqrlufvc]v ou,flc€vrpdseov noo

fiapaqpttftrlrav oe fi.yyKet{pu$veg mproIa€ Fs ftvririraqr+ { SrdpaKej$gel.BrotlT|I,ffvilcfg

Epssrnpt0Ereq.

58

4, A=IOAOTHEH TON XPHTEOhI TOY NEPOY4,1 Yf,lptwlar<q xarcAfuqAorrTraH uEpnrnr{ rarn}ftqX.6tt1ro Ku,r sr}Tralcpqrf,vu r1 rota}"lLq?r6rqra vepori Fa cn€f#nvq

ratavd,l$fi1 apoa&opi{etal a*6 cxvrixateq <ruyrcevrprrroerq oprop.dvrrlv avigymrorv ni*rrov,

ogyawxd:v orr:n'ilv, tpnrorxoxqprxd*v xur &Mrov nup*irfrpcrv. Or ":rfipflpetpm$q" aur6q ttp€q

rc0dlq rc,r nw$ertrmdq" pfylsreq trpfg orrpcewp,daecov rueprypdrpoirrar uvcf,ixrxo oco rq61ov

ESvx6 rcar Euporuutx6 fuoprx6 nl,n{oro (OEK 630136-4-2007 xar 986/B/18-6-2A0T Kae6q

enioqg Kfl,l of, npo$rayputp6E rcou Dnofistrvfoyrol und appo6touq Su0veig ogyavropotlq {WHO.

EPA)

Ot Serypctolrly{eq rar ;gqprcdg nro?r{raarq nou 6ywuv oqv nopc,rioc dperxo repropiaqxav crn6

uvdpyuveg ouofsq (rcripro rdvrs rcr rproo-cot16eio) r*dr 6c!' lrp{rurggqaotflfurqV npqs-0p$H$A.jl

$U5fippwlgdl{-Aogruw-_lsqt_-.-epvavtr#9._ryfrtclrCIv"---Es 6n ntpopd orq og}'mrrr6g evdooaq or

cvotriroag neproprocqruv orov rrpoo8roproird rou Olxori Opyawrod Av0paru (TOC)

Aar6 n6 avcXrloeq aou 6ymrv, tc, f,nore1,6o$fl?c cov o?roi{ov ovaypdgowar }re'rlrop^qp66'otcuq

flfuore; .4 xat 5 aparf*rer 6cl os opxerfg rcepurrCooer4' ctv]4r(sb,rpfooeq auyrcerp4rf,valv

$poplprrdrv ruapa;r.frpcov ra0rororlv nol],s sn6 rn stry(sKprpsvs 6eiypnto 1116 arattil"hqful yttr

mr0prirnrvq ratavdlooq. Ot aupapr;rprxfq ror cr ev$enenrcdq nirfg mo'u xa,0torotlv ru vapri aur&

a4 arcutrii,lql.a enorlpcivowcr o?suq rrrodpco r{varceg ;re uvri.cnary.ouE XpalpraaapofE.

H r)dpqE a(wloy1oy rqg uEtazd.pwqg rcsdfiEqaqE not#r1rq rav wrcyeiav $ftl rz)v mtgavaarcisv

wprisv xafrrc#, mapaicrprT W EvpeftQat iletypaxfi4ryta xar avdiaot1 rri,v herytrtdrcrv wq, rn!

avfwiga-6v.@rdy o o:r'a,vr$6v w{ w@y rw ulttos Btsrfo$ g!,oan 6,

4.2 Apfieunxtl Ksrs tfidnTrcA,rnxeiparo tr16 roporkrag avc"lvr*pwar{q pe},6rng Sw eivm q Sre(o6m{ fpeuva a6

rarc),l,ql,6nryra6 t{ov 6eiryydtcr:v ror.r veporl ror e{erdo-rqKsv T1o dpdeuorl. tiapdtrn crurd,

l'app*vonog um6yq, q aoB*pfr4ta too 06prccog r{il,1 n6 crvurdorureq nfulporpopi*q no'u

xararcl,6(ouv rov triao, elurlerpefual o0ptprrlvrr, pe $r$Xruypugucd Kprrflpra, fuaq yevrxsrepoq

2gapcrr4ptop66 l.rl.J\t undyaaw vapdov rq6 euputep{q rlspro1Ttq oe 6'n ogopd oqv opdarnrr1touq

rora?tlql.drrya Fe ptiaq trJv ncpurcrrdr4ra rouvepof o'e p^fual),n Kfil l1yooto*. , ,. ..,,

.Avst€era und qv fpfi{nl rou vepor5 yrc uvOpdrnwrl rcntw6},rDoll, oe 6Tr aep''qp&i.,dq auprhtpq

y*alpyrrrl rrrypqorl ;6av un&py"our,, 0eopoOerqp*va 6prn romX.1.nl,6rrtffi {h ,rolorrr4'

se tfffi''' ''i"\';,1;''"'i '-'

*+.iil6t.i ir' .

laparqprocrxd. rcnr vepor) yrcr Ertirpopeg yeogprf€ Xp{oer€ apapaterierur orrrlpanxd yrc

trpdlrn gop6 tov nepao;revo aubvu sr&crqpwu(f1 op*Sa und tov Richards (1954). "Errorc,

pettr$i c1)"lnlv, ro 06pa unuol6lqos xor nfLr ro Are0vq OpyavropdI'ecoffi6 xar T'pogfprw tou

OIIE (I'ood and Agricultare Organization\ o oruoirog eaavql0e pe ve6reprl Sqlr,osfuoq rarv Ayers

and Westcot (1985, 1994) p.s 06prr rq "nor&rqra zou vepc'ri an1 yeory,uiu" {W*ter qua.lity .for

agriculture, http://wt+4u,fW.pretDoCREP/003/702348ft0234$0.HTbfi oqv onots

a{mluycbvrar G1r pdvo yeropyrrc€g ypi]oerq,rou vrpoli a},?,'* xai Krqvorpo{ptKdg lprioerg.

is0 2 3 4 S S 7 8 1 0 0 0 2 . 3 4 5 0 0 0

+ ri + r]l9 + f'tt'o 12 o 15? o fQ1i5t l m f , l f 5 5 s r 1 1 I. 14 a 164 6 1119I f 6 e f 6 5 v f i 2 0o r0 0 r79 0 rP121x n x t a l x t P l ur 1 8 r r 8 2o 19 0 i-g?Bq f!0 o fBi

g rtl I t-84a rla a r85I f!6 t r88< r,{6 < ftrb fr7 D r88o ft8 0 fltgr rtg r r90r . f l l 0 r f 9 1v t'?! v i-92t iit s fgl+ f20 + r94o r24 0 r-95E l n e o f 9 7a r?s a t99v r?! 0 r10&o r28 0 1101x t-ig x 1102x r31 r r1f3o rc2 ! 1104g i33 r f105t f34 E ft06a fti a t-10?r m8 r 11678< ct7 < f108> n8 D ricgo rc$ o 1110r t4s r 1111L r11 ^ f112v i4? r l-lt3r f+tJ ! f114

Kivduvo6 AAm6rqrcg

Yfi1pu24, IlpopoLfi - areiepyaola y4pttctbv avaiitoeav oe 6*7,paStpa Richcrds

gtl3tt3

{(,I3

l(l

v

homatno fur*rprrfu & Msiu]tfiardt lpr*wr,\B IB AIOOHKTI

Oluilnruxd Xoprd - Sprro;iurefidveE136?? AXAPNAI A6HNA

i :

.9e1-

zt{5c.+,oc!

E{t

6CI

H erru.roOrloio, r(rw guTdv crq notorrl?o roo veporl frpdancqq eivar auv6rtaop6q zou erdotore

gorori ro$iu6 en[oqc KU,r rc-]v aoroard;v 1fipilKTqpls"md:v rou aplieirmo0 vepo$ ooc rar tcDv

rpuorxrirv K{n pl1cvlricbv ypp*r:rqpranrrirv tou e6&goug- , .

Eqv aaporloa rcnpdrypaqo a$oloysirur 11 rcoral.Lql,6qtu. rou vsp*ii fipDeuoq-c ae 6a o.gopa tov

riv8wo ckirtooqq xsr sl,Kai,tc*s1q €irv siiagdrv, or eainroorlg a:r$ Er*qopa p6ruX,Xa rtn

q6vooror;geia xar 11 7gpr1o4 rorl orrlv rcrqvotporpta.

0 rfu6iivoq atr*tcaorlg Ks,r q,?"xof,i{rl6'r1E ?erv e6crgd:v, e}*yXeiirr ps filv apoBol,ti ro:v l4prr/irv

mra?no'sov mo e(edrreupdvo Ernypuppa Richards (1954), ro onoio a{n2'oTaitat q $XdGTl

p€ro60 rou 6eircrq rcpoopdgqoqg vazp{ar": ft SAR, Kor rq€ qlsrrprrflq uyctyqrdrqcag tou vepotS

lgr{pa 24). A.:r6 ro Xfiro 24 mpoxriar* 6rt 'ru neprrr<r6repa vepu eivur n*rr7opif{ Sl-C3,

Eq?fi8q Tapt1.illiti #vl6vots a)xal"iamlq ,€oJ atyry)*ri xwfitivots c"i"d.rarqq xav r;$utprfiv"

Yndplouv 6pc.r; rur eX.d,pora Eeirypora aou npo$&iiiov'rcr o.rc, reiito S2-C3 xat S2-C4 pdooo

xrilrtvoo eil*caifttoqg rcm oyt/a6 6ra,g raA{ ury4}o$ ttwilrSvoa a}rtraat1S. To re}"fi)raio uivnt

Seiypcra riot rcriptlqrcnv rarpirrig and Territpfl<rerg ruhloicv ciq:cokrlg tol Aoamcu"

H ru'ru},l.r17l.rrpa qq /"pflqq rou opEewmof vepori, ot 6n orpapct snlv nspwKnK6'rqto tou

veporS 6r ilfun)"lCI Ko[ rlvoorotlefa, *{n?,cJeircr ps F,iotl to trs.pctxrrlpronxd, riot rq

zrpo5raypa<prig rou fltvsra 6. E0pqarvu p€ rov niv$rc{r arx6 to urdycr* vep* rqq e.uputepqq

rueproflg lapuxaipiiovrcrr orrlv nieroyqqi.a ?ooq {nE rordl.Lq}.c yra 6p6eucq. E(aipeoq

anocel,ofv fir:iyps.cu rorv onoicov or oui'r(€vEpriroe4 prtdi*ov nau npocDropiorqtuv unsppafvorw

fi6 cvrio-rrrrxsq fiJyKc'vrprirn.tt6 scra fiivnrco 6 ru,r orryr"*cpq"rfuc, aucri. rrol) ?rnpouord{ouv

cn4'rcel'rpdro€tq otrucor"i prr*piari peTc,trinepeg and 100pg/1. Aq cqperal0et 6n ot npfg amfq efvct

wSeutnr6E rar opi(owar i6yrlt rrlg ell"raoriq yv(i)srlq yffi filv to(u<6n1rd roug $?o puni,

Xe 6u arpopd orqv xaral,lqlfrrlca tov vepciiv rqg treplo1qq yrCI. rrfv r<rqvorpocoia supqc)vfl ps nq

npo8ruypag6q tou flivo"ra ?, ole<!6v xu0' o?uoxlr1ptu CIecopor3vrcr,r aig, xat*l'i;r1i.a pe e(uipeoq

n;pioq ca 8eiypars, rou ruapouorit{ow uryrl}Ag auryr*vtpriroerg uc,vycn"i,ou ( > 50pg/l) rut

lrrprrdv r6vr{rrv (> 1 00pg/l}.

61

Ilfvarc6 6. I{pocwdptl,tc plyrmg otTrcewprboaE ryvomorycfav mo vepd attilmortE (Ayers andWestcot, 1994j

lI

I

Irory4aio llpoelSpwq paymfllowrfwotdcn {mutl} fiapurqprlceq

AI : n I}0wr1 peir*oq TrK TTspsyuryrK0r4rog or {uo e66qq {pH<5.5} qAl* $e cAnaturds66on ipH > 7.0) ro ouvrextrutvo t6v xafl(uvrr rcr cloerqr n rofxdmrd rou

ffi 0 .10 H ro[urdiqr0 cn gui6 xolri]er tuptTsru ond 12 ng/l mo "Sudan grass" ot 0O5 mglisro o0(r

H4 t J . i u H rotrxdrnro norritrsi ciro 5mer1 cno,\dxavo ui 0.05 moil cns 0cuvLlSn 6$iTpo

Cd 0.01

Tofird o"ru 6crnpra, rstr,\u xAn. ur6y4 xili ae Xuuqiiq ouynrwpboeq 0,01 mgfl.fiporsivowor ouwlpqrxd 0pro '\0pr rng Suv4lrdg ourcnirpruo4g rou or tpuro xoit6oqr1 oc ouyravrptloeq or onoieg Sa nrqv eni$i*psie-{ yro Tqv av8pd;nrvqfCfqvflrlt$On

n n q To[rro ce rolsTEE cn ouyrtiworiue6 ndvor ano 0.1 mgll. Triwr vc aior oudfrepo ror cArcr\ina e6aqr1

,I ' Y

Cr 0.10Ir yevrxtE ypfliJp,{ 6sv snorstrei pocrx6 rrorXrio cvfnrufrlq ruv qurd;'r. flopdAacurd nporrivr:vTqi oul/rqpq'rKo opro iopt r4g eMmo0E yvrirOn( crtreitrr: ge rqvrottxomrd rou ms itur*.

Cu 0.20 Tollito ot aprnd rsuru o€ owKtvr[urcrrE sn6 0.1 itx .|.0 mg,']F to A$psvonotsirui os cuSireoq rsr o,\Kahxd e$fi{$n

Fe 5.0

Arv civar ro{rxo mo qurd oc otpr(ipevo edorpq oAi6 ouvcrogipn o-rqv ofrrSooq rouelicqouE Kfll {rTqv peir*oq 4g r}oBrorporqrc6 Tou gu,crgopau ror rou po}rupGoruiou.YneppolrrciE ouyrevrg.larrq a64yofv ce xpoptrdparo mi60eo4E rpcforoq cnc purdxsr ms ooEtutxi crieTfiunrc.

U 2.5Av0snrr* yn ro neplao*irpo gurd oe o'uyrewpdmq 6$( Kar 5 mgll oar\u nurlrrrbmc reogq. Tolrr6 mc emrep6oer64 oc ;o;.r4iig ouyrewgirosrg (< 0.075 mg/t).Evepyei qygAoyo pe ro B6pro

Mn 0.20 To(rxd ot opurd Eurd rre r:uyx.ewpdrc;r4 nrru norxiicuv find pepird 6exara fugusorrd mq,4 Gjii,ft ouvftSux'sr ctrvu s$8$n

Mo 0.01Mq l4xa arc euro or ouvq$e4 o'uyxevprina{ oro vepo op6{uo4q Ksl crro cdcqxx.Eivor 6pr';g mOov{ q ro{xaiqra mu oqv xrqvoipo<pic adv q (uorporpfl r4g pe uryqltqouvxEvrod;mic 6to0ioruou uoAufi&rruiou.

Ni 0.20 Toix4 oe tw n\q0a6 qur*v oe ouyrewgireq md 0.5 tr4 1.0 mgll. il ro{rxdrrlrodtttrlc auri ilsid;vsror os cudi:repu xal sixslnd s5qon.Mnopei va errlpeaoar r4v avon,uft nw qwrxtirv rundpuv o[ noif uqrflMcouyrrwfd.roe K

s 0.02

To{ir6 oe guTc o€ ouyxewptlouE trog xci 0.025 m$l xar ra{rr6 mqv mrlvorpoqiatvo q (uotpoql KoAinpvslrcr oe eSdqq ils uq,r]\6c ouyrewgixtq oeArlvlou. flcp6iocurd or- roIS yop4itg ouydewpd]ssrq Xaponrlpi(ercr u4 anopoirrFo ryvoorolgrio

_orqy!4lqlpqqtq,SnT; Anoptilaror cnorerrrogorrd cn6 ro gur6. 6ev undpXouv cnorlric o;eird pe rqv

rotx6rmd rouWV 0.10 To(x6 ss opr:ro euro sr6iln xor os xauntri( suyrewpd;serc

Zn , ( \ To$xficn Sdoopa gurd or norxiAegouyrewploe rc. H rolrr6rqrd rou prrrivriar otebdon ue 0H > 6.0 xor ug Aemousorl ri opvqviro s66on

l .

62

Ilivaxug 7. IlpourdpeveE piyrtrtE ovyxarcpritoetg qvoororXtkuv oe vepd xzrlvmporptrctiE Wri6q;(Ayers and Westutt, 1994)

frofieis Avtfureoo ooro {mo/lll{l

As 0.2Be u . t

Bcd 0.05

l n

L/iJ t . u

\JUt t h

Fe &.sv Tro0Btrrnrrolph n {

Mn u.il5

Hs U , U I

NOrN + f'l(}r-N 100.0l,lOe'li 'tsSeY 0.107n 24

5. EYMNEPAEMATA - NPOTAEEIE5.1 Eupnapdo:ptrfirAnd ru wiot*prrr rr*rXaiu 6nn4 mrr* crvai.rrgrlrcrv onc npoqloutrwcq fi#pfiTpdtpcnlg nporcr5ntotv

cr: *Kdhou0a crpaep*aparu:

Eqv eirptrupq neprffi roo Aoconori svcrmlooovrur duo tmpmt ofipotpdpttt opf(ovztq, o

avrilrspoq xorr<di$rlg uEpog6poq ewdq tcov iieoysvriv rur fllsrmorcrvxdlv cno06oe<*v,

Ksr o puOurepoq rcupunrcdg uvrdg tov m;0panrc6v qplpraua'pdlv taw lprn6rKo -

Ioupn<irxtflv noBemo],t0rrw. EricrnE rpoolalpnriroi eis*Oepot u8pcodpor"

cncffidsoovrfi,r r:s c{no0€oerg erat€pal0w nig roitqg rou Aon:no6, Krrl srrl r*p*rnu

fipos-/JtFs.T1K* ae$is rou Qpc:nori K{).1 onlq Attii6rrg

Ol mrpu,ndvrr: udpog6pot opi(ovreq rpoqoilorcr5wot" o lirv avrirrepog and ro.

xst€roErSovro vepa q6 FpoXqg Kor anb rq 5i40f1oerq y.ctpapprrrirv u8ferov,

aupnepriopBovop8vou Kol roo Ao'ornori, w6 o paOritepo,; rnponr6q ond rqv nepn14 r4g

$61reug fitipvq0uq, und xararcCrprxpeq 6rq0{o'etg 6t rpfipato 6not tapouod(er

eintparreruxr'1 avdrm.r[q or'1v slpfrepq neprolrl roo Aoorou raOrb,; trtoqq rcr ond

rcrtur6prrqeg perwrytoxg snd rov tinepreips.vo rorndr0q u$pcrp6po rarv llfueio-

fll"erstoKowirrbv r(r'1pitrtw, t}taktpa 6rqv aeptopq 8utrrcd rcov Orvogrlrorv.

H poi rou oriyeno vepod orw uvdlrr;po rorxdr6q uEpogripo Sropop*,rd.rv*et txut a4

srdarorc nw(operpwfig or-rv0{r<e6. le yev'rr66 Tpo.ppgg ropcrrlpeitar pu "o6puuilrt'1

ratrr${Spa" &urrr& rc':v Orvo<ninov 11 oroin gaivtror vo rrnotei,ei ro Buorxdrepo

*.ao$ircq Tqg pot; rrrlv rlroyr:irl]v vrprfiv rou rorrrilEq uEpotp6pou fipoq rw tnoretp*vo

ra6rcximti t6potpdpo. Ta vepdr nurd o'rr1 cruvfusur. orol.au$o$v fii poi rc*v 'uzSyeuov

vepdlv rou rcponrori r6pog6pou [iopeiocrvoro]"rr& npCIq qv aeptffi rrlq

Maupoaotp*}ag discro snuvrofv Kfl,l rn rrEpolrlrnxri Spya ro1) ne0iou rcov

u$poyeorprlrecrrv cqg EYAAIT, r(rl orn m:v61eu arp&}fiow warol,uc6,epo o'fiq

txptil,pupeq ru4y6q rou Kai*pou Arcrr4g

H cruyrerprp&'r1 Ereri0uvaTl poliq rcrrv rndyerrr:v vopriir,, rcar q u$p*rltrn oXfoq ;ret,rfti rar-r

rcrrcd:$ouE KrLi. ror) anoretpel'or rupoT ncor5 u8porpdpou erctrp€nm ro fCI.pfiKrljprcrpd rau

64

rsh€:utsioo {Dq u6poq6pcrt) aVIqAttE pt)nortillrliE emitrlrrrdrrllraq an6 punoydveq eorfscra Spaoalpulnpeg nou l"utrrpd,vouv yrirpo, or4v e-udrreprl iex*vq rr:u Aso)nof

r 'In nomnrd lapcrcrrlptonx*, rnw rurdyeicr:v vepdw e{erirctqxav rcr ro{rvop{gqxav oeErio Srooopearc€q ndrqreq, ma rarpu r6vro rur ota ry,voorotgeia.

o xe on agopd orrlv Korovcpq raw nJptuv thvtav fiporarrrow ts, sr6i$u0a:

- lqv reptold Fsrutf Au),rirvcq Ay. Ooptl xur Aoaiaof n:rsvrouv vepd np*crqarrlitpogo8ocrioi {'fresh waterst'), nlorSora oe ofrruv0psKrxd r6wo, trre 1opr1},.6 s.r}voi,o6ral"c7-upsvcov al.dtrov (T$S). Avctol"rr6rcpd liar ercat6pco0ev rqq xoicriq ratrAsn:nof ta TDS cnr{dtn ma8urcd rnr o u6poplprrdq rou6 runoq trreropaivei oe; ^,

M g-HCo 3 Kfll o.€ prrtorl oSlrou vep0.

- Tn un6yen vepd, eivor otlv ntrsrorgrlgir rouq psflopnpfvu pe vrtprrcdr rdvrs oeouycewpcbcer4 Sralaoleg nepilrou nnd to, 0eopo$err1;:evn 6pro noorp6rq:u{ ?{r}v50mg/1. Enioqg au€qpfun efucr rcor q orryrcr*vrproafl rcrug oe X,},ropr6wa svdr, rsr*prlKoE t{:ro Acconot) Eapcrrlot18qre xar a{6qar1 c€ qciorqoprrd. r$ryrc. Enioqg oeoptoFeltsd ]r.qploy.t.q r+uayp*tpqr&1, K{11 uufqpeveq rtir"6g virpr:r$riw rar utr4rrrwurrCrrv

rdvrctv.

- H aposAeuori rcrrv vrtplrcd:v rfvrrlrv rivcrr rrrq sni ro rleiotov fl|pilnh:{ 1a[u:rorilcl,urriotrraro) st6s ra vrtpeirSq Kc,r ro appovrard, r6vra u?ro8isovcar o€ nonrceq ru,rpropry,uvrrf g e o.rie6 pirnavorl g.

- Ee Bropqxuvrxfg eorieg pritav'or1q sno$i,$ovrul Ku,r or au{qprfveg rrpfq crov

$"*:prdvrcov Kor f,cDv gocrpoprxrbv i6vrrgv. H u6frro4 rov 1trr:lprdm(r)v Grfl)q'iEt)o{rf6)psrtrcli6 tap*rtuouq u8pntpopeig rou CIpr+aof Ku,r 116 Aut,i5o6 nnofiiEerq,r

c-co lrr]Xsvrcpd qq upcfitdp$srl q

I Xxenxd pe Tqv trnavap{ rwv &agdpcov tTvoovorydap Ksl rov trrr,t6}"kov cRrrr&yovrsrrs *K6l,ouila ouprnepdoparo:

- Katuypri<pr1rccv at{r1p^sve-c aueg Srog6purv per*'iJrov Kcr rgvoo.roryeio:v dnog rookrd Kan to efaaser.'d5 yptitpt*, ro wrdao tsr o othqpoq KftL oe nepr.opropfl,eg

uvuldaeq ro apo*rrcf rcm o p61vfi6oE-

65

Ta rlvoororlgeia rou uvqyeiirqrccv napouotd,(ow- uyql,fuepeq cnvyrcevrpcbosrq. xcrir

l.ulKog rar encreprcrr0w rt:u Aoamau. or4v E€pton rori f,lparnor.r ra0dlq lcflr ofilv

KepLoTJl nlq Au?ii6cE

Obrsi gttbpm (Cr*l: Or ur;rqLdrepeq npfq ]ioporqpo*vrot o,rryv reproyn r4q

.{u},i8aq tlS0ppb) rst u,ro},ou0or1v or nep:r'ytc, rxrrrfl:c':0rv rou Aooraor! €rog w1v

eap{irspq nepn14 rori f,}parncrl ru6cbg ro.r r'1 neprofi voarosvcroiuc* to'r,r Aoo:aar1

€at6 rnv ncprc'X4 rrlv eupfrepq mprofri qq Auirbvag. H orryrerprprivq xa.ruvoprl

eintp6nei qv erripqcq 6a <rttE nepriodrepeq aepurtd:aerq or arrfqpeveq ouriq npfg

rou olrrcof "Xp{;:ltifir} sivcrr un't:rsteopa Brop4lavmqg piinavaqq. Au(qpeveq xrprq

g:coptou rapaqpfl0qKov Ks,r oe peinpqa'q r1 onoia Bpioremt niqoiov tr1-c roirqq

rou Aaoaof p6pero rou Ay. 8r*p6.

Enrorlpr:tverur 6R or or)-fKsvrprboeig tor ol,ucorl Xpritp.iou xutu.yprigrlKav {ilTlv

nepto231 vdnn rcor vorr.oovo.Tol,rrd rou Aoo:rcor5 q ono{a tuud(erar pe rq $oanc1Ereii$.woq rqq pof1q rc.lv un6yeurtv veprix oxcrv r(&pcrucd 'Lr8po<p6pc Krn. ,5y"r nvdvr4

mlrq{ 6natg r1 'nupr*1ri popero6rnrds rou A.aon*6 ii4i*61 11 neplogd Orvdrlq -

).p1purupiou.

Ot otrl'ner,"rprirccrg rau e(oofiavo$g yttfipn {cr6n}nupouord(ow rnrovopirg avdri*yr1

Fs olixli r$u otrrcof 1pr::priou. Or pe"yrcneg ap€q nou perp{0qrav cvfpgovrar oe 156

ppb oe yschrprltr4 I o?Ecio pp{onerar n}4oior, .c4q roitqg rou Aeiornof Bdpnc, rou

Ay. Oor;rrt evri.r crvdlioye6 aprig rcpouour{ouv Kr}r sr,vec*rpdosq Ksl rs. gps{rro only*

Trsplo1rl tr1c Aui;tr5*q. Ylqlfq eniicqg 'urp€q xuruypfnoqrav Ko,r os y*:ri:rnr1o"q'niqoiov qg ro{rr1q rot Aaoworl xa$ri4 ericnq Kot offry anprireprl reprog.ri qg

Aoldrrruq. Or au{'rlpeveE ouyrevcprbocrg rou sf,ac'$e'rcug iiporpiou fiou

zpoavag€p$4rcv ernpcrur pe Bepor6qra 6a rivsr a?qv nlnoyqgirr roog

anordlenp* propqlmnx{q piimrvoqg.

H rc*rrrvopui ro:c Ohro$ Etdtipoo (Fenl, rupotrarcder nvd)"oyn lopor,nlproarcd pe

trq :cporiyo*p$/$6 Kur$vop€q *,}.?"ri KGl ps oarpr:iq $ruguporurflcarg. Yrgrl),sq r4rsg

aapor4p4Oqrw 8urrxd rcru Sparnof orrJv eupurep4 zeprol4 rqq XpuooTqyri€ sr

o'uTKsrcprpfi,rl :repray4 q6 Au)d:vug, v6nu tnrv Orvotprlt<*r, xusdrg Ko.1 trreru$lIglprc,taptou xar Arii,i^6nq. I{ uugp.evq rruT!€v?pfi}oq rr{qv neprofl qE Auldivog

' gcrivsrcl ornrpoo0srCI€ va awpeaiaro.r anr5 rrry mpooda rou orf4pwrrcciror5louxot'rrir:pacoq 'uo onoio epprxviiucor enrgtxvewxd v6no qq AuL*i;vac wto oruu{rlprveg nFsi s.r16 u;rdicureq ncpiu;6q erctrprdrar 6rr cclv n}"etoqrygtu rorq siv*racertALetryn pmpqlgavrrrlE pu,rov$'qq ogo{ auvo6a}ovror, Kor tJE ir}.iouqpunnvrmo*q &eirteq rar atiqpwsq o?TKwrptiroerg petrifJ*ru.

- AoftpevegtryiqNucdiott (Nii, ncpaqporivra.r erntdpar0w rtlg roirriE rou Aoarnorjragr*6 xur vo'uur6unxs, n1q ow6qq wri: Ea, nupaqprl0qKov c.tlg neprutr€g rqgAuii$u6 KCrl roo Qpct>:rorl ot onorcg syri0erfl E8siiov uyql*g auyrsv-cprbc.srq

lpropfou rar *],irr.rv r5v'K*'. H ouyi<rrpqrfvq xuravopfl tou vrrcl,iotr anoteL€i

No"pars44rtztrcd ndw4 pfuravorlg rsr n ,Efipouotc rrnr ercrqrdrur pe Be$urdrrlm 6noledierur *peau ue $rotrr4y-uv*cfq eorieq pfnuvoqg nou hatrrp&vouv 1i*pc rrn6g qq

sLrp$rep.qq propqluvncflS i{i}!rlq .rou A.ar*noil.

- {}.i,uttiE opyawcdq Avhparcaq {Toc}: H naporoic{ Kfrr rarmvop{ rou o1iro$Opywnco$ Al4para arare),af 6$t*t7 prSravsryg rul rsndyei{r}v tnprbv an6op\,s.r,ilc{E tvtitoerq" or ;rerp{os4 €ser{av uryiii*d,; npjq, dcog rur T.Smg/l oro vcp6rou Aor*no6, xo0d:q xar atrf,qpeveq rtp€q oe ysrtxprlosrd erctdpar$eu

"tlg ro{rr1q r6u

xnr ex'inqq oe yecurpqo'or6 or caoiec, $$er(av avrior*ryp rryqi,e6 o1lrwtpdl$r1q Kor&l"?'orv prmoldvaw perdlltrrv rfi.r rdvrc:v. l{ rarcvoS-irj !o1} KGl n8rrdwpu, q o-rlmaar1T(DV SrnF€pcuq oprirvlKi0v evrb$ariv rou o.upirerrlcrw, xpft(ow nepart6proSreperivqorlg oriprparvu pr 116 apo6raypag6q nur ono8eiteq tr1q o5qyicq 2000/60 rqqE"E.

' A;)e p&*il.a, apoevrrcd {As) , pa'rltpioi ffb): At(4;isveq rrpg o-riyrewpdooeovrur npoewroir rur polfp8ou fiopoTrlprl{Jqxcv 6€ }rc}rovtolrsvec yeorrpt'loe4 n?,r1cirot,corl Aoonoi) ra0do-q Ks1 orq neprol$g ly-qparapiory. OrvoEritrnr, rcar Auldiyuq. Orncpuncoosr.g aur6q sro8ifiovru.r 6rrlv nl,eroryqgin rooE os oqpsux66 rar 6rd,ypmqe.r:'rreq pro pqlavrr4 g p urm,or16

Ee 6n orpop0 $rqv nspouoic rpuomCov rnlycirv pr5nav'oqq orqv nepropl (orEqpovrxelroriXa

rorrdopatu xur orprdlrOcr), *nd m Eru06srpc. crotlefa nporrlrcter 6ct 4 napoucig rou6asptopi(ecat eict$q a1q otsvr]g fi€pto;Tlq qE i,*rrivrlg rou Aor*rcnri, v6t6r a,tr1v opcwqrceproplrqc li&pvq(jfiq Kot pdparn o'rtiv 3ttprcf"rl rou 6poog Krun&g. Erxen66 {'rnpurar

*- r _ :. +-f .;"l!ii -- - . .

67

pe pepur.dqrc 6n tu 8dtpopa petalJ"u Kor or ybnot acnr rpoo8topiorqrmr slvsr crnv

nisraqrrlgia r*ug a;ror6leopur, Btopqluvrxt'lq. acrrucrlq Kqr ye(opylKrlq purcr\,'{rnq

Acpp&vowo.g undqq ro ,rpocrvoqep0ewa, rporcirriter 6n o rapcrtxoq ufipog6pog

opi{oltu6 ncu rrvcrzcrfoceror o-rqv euprirepq neprofi, ErcrofT,er rov rfv$wo vo

enrpapw0si uad Srq${aerq polr;op6vov u8&'rcov rdao rura 1r,f1ro6 rou Aoroncrir t5oo rflt

arqv "uEpaul,ucrl rarap60pu" aou uvnrmi$orr{xl Surrx* rtw Owo<pdrcov. To u6uarcd

s$r6 o$srTlpa uglararar erc;retd)ufeuorl pecor {rl:v yeorprlo€ov rrgg EYAAII orrl

MutpooouBtiXn xaOrb.; xo.r til?,r-rr yetrxprlcerr:v ylCI, fiq t8peunr€g ur.'&yre€ 146 etpicptlg

?rsplo/Jlq. Ag o'qi-rerrrr0et 6pri:q 6tr rc Eeiypn vspoii :rau x&pSqrce on6 nq yerr:tpr1oer6 altfq,

$sr' ?ispoosicoe avSdlerq prinavcrlq. €)a np*nsr vu pel,err10si dprrlq q nr$arq pe?'iov'nxq

ernpdprn'c4 rou u$poqdpou arro{ torr orcrrqpftroq, l8rrritepa oe nepd$ou6 avoppptuq

KCrl rrr ouv0fpeg unepavr?"r1oe*x.

! | ' 1 . , : ' j \ . - r . ] ] r

5,2 llpordoeryAnd w trpoovaqsp0€wo, rpornmter q noronrrl unoBd0pro'q rorv uaoyuio:v vspdrv qq euprltspqg

repiogtlg rcur 8torpatvsrfir o xiv$woq neprpulJovrrrqg err$ripuvcrn'; ror ropocrcof u6poro6pou

$'us'rTlp#-roq rng BA il*pvq0ag

fia rqv rcpoo'rcoiu rou uvrrirfpot ouodlparoq Kor rou erpirrepou nepr$&1,1ovtoq yewKdrepo

xs06c Kff.lTril, rq ),IW rrov $fi,'rmec':v rur nr5e8erypsvatv' enavop0c':nrrirv pdrpoy, lapprivovrng

undy4 K{}1. rtq lrTEqLpE{n$eK Troo anoppfouv and rlv O6qyie 200016f}, or apotervdpr*'eq *xdpyereg

6torpivovrct at pdrpa npoiqWqq rcat dty,y3tu Kor ce ryfiypappq, tpffiwlt rcdv epyo.or.rbv

:mparteprr: liLepeuvqoqt "Xd,peffiryptop0fi" rou r6ptryearloyrrcrf c'uo"rrliraroq qq:reprop16.

5,2.1 illErpa np6.[qqtqg Ktrt eiiylout Evrattxotcotrloq tJrryypu mr; $ropqx.sv(ilv cqq rceprofiE rcaOdlq rsr d)"il:v 6oorv

etrrnlcrcow*.r srT1v orryrcfvcpr*aq, *,nopuxpuv6ri K{rr refuir{ Sul.fteoq ralv unopitt'lrov oq

lrpo,; ro XrDplo'fi1€ $liSecr4q Kfl1rov ttJtni anodircc4.

o Eltyxoe rqq mryavdqraq trov Ee{oprevd>v ano0t'Feu$Iq Kor 6w.riv4oqg puzo'i'6varv

lnpucti:v ou<rt<i:v orrE 6uirpopeg Btopqy-r.visg qg nepraXqE. Oa ritol uorpo.?*1:repq r1

raraoxeirq c(rr:reprrdrv - rmqovstfl,rcriw 6elcrpr'.v6v-

t H runxt*fq onaydpttotl *r*o8rlrcare *vsiil?,eyxqg Dr*0eoqq ufpcuv rl &1"1xrn, o.noBL{ralv

,it:o 68*aoq Kfi.r sro urue$*.qog (n.y". oe yerocpflaarE, op{iy;;*ru" }.fi,tou€iu r,"i":r.} ru,Odog

ericirlq Kol orov Ao'orn6. Xs 6fl utpopri ora ene{epyaopavn uypd. rcm mepea aadBi,4tu ri

e5agi.rcrl rur urce8dqla Eui0eorl rouq Kol yei"rrdcepa q Eragetpr*r1 rouc 0o apfner vc

1-iverar pe aursqprlrflpqcq rrgq olrrrrrlg E0vrrcqg rur Koworrr{q Nopo0coio,g

o FI dFecyq s6*;6peoq Kor ego-ppcrfn ur6 r4 opp60re6 unqpeoieg u;ror, pllwptlq rcw lltthapvq

)$ottE yt& Tryv me{cpyaaia rcat 6ui{Jeof rov uTp(ov xur rL}ulniv anolSiirlrol', o.stlrrbv ror

proprlluvrrd:v.

5.2.1 flporervdpsvsg spsuvqnr€S rpyqoiE6Ot :repuufF{D s$}rtu"f'?'}rrx*q epyaoi€€ cou rpivovtur a:repairqrc-c riirio yrfi, rov arcprBfmep*

npoo8ropropd rrlrv ptllgcvrotruix lertatfl,'icrg ror.l cruo"rfltrr*To€, n1g fireperivrl{J'q rTl€ tn*oqq rar

*po6l^euorlq ro:v punoy6vrov ouorCov xa06g Kor rrTv eqnppoyq nrorel*o'punr6rept*r' ptrpov

npootao'iag Kfli c{iroKfi'r**raoqq rou cruordtrru.roq eivur or crr6?otr0e6:

H avdpu(4 ucawnorqrtrotl apr0pa6 apeovqtwee$v yeottp{oaav htypamfultyta6 ra

t),zypa evrdg ro.t a\aiov eq-C propqlcrvuciq icilvqq rou Aoconori ro0i*5 €nio1g rcor xc,rd,

pflroq rou rcpcrcrrori or-roaiparog nou peoo?,cpei ar6 rov Aoretc6 6toq trp naprol6q rrr:v

Teat'rpfloearv tr1E EYAAII orq Maupoootpril.o. Eoio1g npoeivercr 11 crv6pu$1

u,v*?loycrv yecorptlcrerrrv arqv euputepq asproXl xqg Ar-rlf8aq 6nou anpaqp40qro,v

oyll€q o'rlTKsvr')iiloeiq {oossvcfg lporpiou. Ag cqptrr$0si 6tr ote nlctota tqg

nuporlouq i;pewag Seir xuti;otq 8uvuft q 6erypc'ro)'qrykr a)"qotov rnt snr6g rqq

Bropqluvurrlq ftirq6 ),6yro rqg t$wuepdfilroq r(ov Xp{og6}v T116 srrlv nepwpj, tou

r8rcrr4orarco'0 ra0eodorog Kor rrlE aaoucrilrg r,ccr*l.lql,cl u$poorlpsitriv 6erypu,to?'qtlriag'

C) opr$pdq rulv fiporslop,ivov yeanp{oecov orxtilv oe npcbr4 tp&oq 6w 0o npfner vu eivsr

pircpdtepoq rov rpuivrc (30). H uv6pu{q r{Dv ye(r)rprlosc}v su'rdov Sa rcpi:ner vu

<ftvo$effisi an6 nq rard,)Aqkq Eev,vSraroX.rlyie6 rmoyaoll vspof rat uX.rrdrv Siitt|rqoqE,

u;ro 8rrpagil:q loggings Kfl06q Ksl CI.7td owh4n.rfg 6or4rf,g YilI rI Ereperlv4c'q tarv

u8parr'),mdrv r8ror{1rarv r(ov D$po{p6pci)T oxrl,u.{t'tt.oprbv,

Tqv er,c6Leoq er,6g rcpoypdpparog otSygltwwv ytatqootetbv epYenrcbv Yto rw

-npoosropropd tri:v ycctrtrrerprxtilv XopoKrllpisfit(inv rcuv u6potp6porv oplparropr-Cov Kut

rErrr.trspa nig r?rfl.grlg ro1) rcorff.diiot'q uSpogdpor: F€ rov unoxeipsvo ruponx6 r$po96po.

Or epyac'fug arnfg Oc. nirenei rat' ei*tlrmo va nepil.np$nvorx ge06$ou6 qlerrpwtlq

ropo1pu.oia.,; Ksl cle1slrm6q pt0d8oug.

H e<pcrppo'yri eir'llg np*yp6,pperog n6ps,rco),a$0ryoryq rtov nctmrxdrv xst xoocrrtxitlv

Iops,Kr"rli)torrrdx rCIv uripotpop6aw (rriprax rdwCIv l(d,i ql,ooTot1tft*r.'), p6erOr 6*truon

yeroqt'laecov, to onoto 0u np6,ner vtx alvulrou]-61rotov 6rerorig 6wpreuq, rcaA{otatm

utro).$r6r,q ava.yeaio xo,t en$t\i,r7pdvo. Ers. n?,st6tc s.utt! 0* Kilro<rtsi eqmrri Kflt rl

8eirypurolqryia and yearrprjceig or onoisq 4tuv cvevspyfg xctrd qv (leipepnnl) repio8o

qq nnporio'46 6etlpotoiqtyiaq xaflci:q sniorlg Kg.l il ovaprsv6pevq er'tov4 eroy3.rr1

8roxripc,vcl rq€ cruyrsrprD6;rlg 16rr plroydvctrv ouc'tdov IEOU l(fiTcYpf<0qrur,.

H roro0 rl oq rohoptgrptqdre ewgqoiprov eJ,ty79o0fi4 ?rpor€lvdpn'aq yeotp{oerg rCI,06q

Krrr $t en0,aJpeva oqlwio xatri pqruq r4q xoinlg'corr AorrrnotS. ,"

If flayparoAryyia rcat avdl.aoq ruv ierypd&)v Trs" rqv crvtx)'et)$rlttao, mrv rpoo8ropropd

unv oprywtedv otsottitv, roDfuigrcrruv eKeivov :lou npop),e?Eovrs.t r:-rr1v o847iet 2000/60 rar

oto rogiov 0eoprr6 n),niow r1g 2girrpaq pag (OEK 630!8126-+-2UJ7, rcuCICoq enfoq6 rur

en?*ypivcrrv opryuvrrtirv ouordtv nou avo-ypfrgovr{n orrl Sw$vr1 p$tr"royporpiu. To petpo

snra t€tgicaarst azespainlro ru enfeQlqpdvo p^n&, and tqv aviptao4 ayqithv

onyrcwrlxboaov olarotS opyawrcod dvhpaxaoe cufKffprprivrq neploy$q

11 )awwptp$E axoyputp$ rrl;av punoyivuv eondtv Kd,r. rou ei8oug ral propqigavtxdrrv xor

&)J,nrv 8paorq prorflrc]v ryrqv neptolq

Tqv rurcroxeutl xcr nyxcrd.arnoq rar6?,iql,rov pqy"avrcprirv yffi fi1v raparco)"otifiqoryqq

mupwaarc$q anoppo$q o'ro Aoayrd F€ flTV rcraorceuri 6$rt roa)"&ytorov ure:pSgaiacubv

oe errl"eyp*veg SdaerE qg xoi'rqg zou Aocoaorl. Era nlaiora uurir, nporctverar eirioqg ro.r

Vtyrarrtwn$ry l].tK{}il#tEe*paAoyrco6 otaQpoit ylo rrl\,, nnpnxo}r:*0qoq qq ppo2gflq xur

$$vsrpf$'' iltKpoper€clpoloyxdiv nopop6tparr,. ESv hqg0ei urdyl 6rt aclv roicrg rou

AaCInof napurrlpsirar anopporl 60oooFov peuo-uiuv apalorqq crivSeo'r1q rai npo€i,ei:or1g

3g--nogfy-e-o6ornpo mo orivol"o rcu lto.{i ue rj:ug noi}Ferprqotc-g1sg4tggig-_Qg

Wooo{tsgvaTppm],;;onoLrl$eixatlcl,.col6orn:u;a"ty,catplc W_oerfioroiqnqc rcei d,6}ryou" fi

1' Earlv Warning System" .

H s'iv#*q, *c*{epya.oia xar svd}.troq rnrv sr'.ors?eop&'ucrv rrov rc,pcmlvrrr egyarnrbv rnr

q av*'ntu{q uny xacd}J:4}.*tv pafitlpo.nwitv povrd}.av npooopoirttnlq qq por]g rcat qq

petc,rpop0E tal iirsiutCov oriorcbv oroug undysroug u6porotipooq a1llrs.tropodg qe

rceprc;6qq.

H u(r:l,rtyrlorl rov 6a6opevctrv xcr anoruLscpdrrov 61,ary rrov walrfprrl epeuvtpuctilv

epyuLeiow rcar epyuorduv xat Srnpdprprrioq npord,aearv yfi'rq ?urlyrl tov Bfi"notolv pirprw

$poff coisc K*, r szroKq.raartoq g rou ar-rorqpurog

o\ l

AQrgvo" #r:$pars*pnE 2008

IIAN. f lAbtri\i O YAOIIOYTTOE

Appelo C.AJ andD. Postma i2$05i Geochemistry, groundwater andpollution. A.A. SalkemaPulrlishers, 2oo Edition, 64!)p.

Ayers R,S. and D,W. \t'estcot (1994) Water quality for agdculture. FAO Irrigation and.Drainage Paper 29. Rev 1.

Burdon, M.G" and S. IVlasloum (1958). Some che.mical qrpes of groundrvater from Syria.UNESCO Symp.Teheran, pp 73-90.

Deutsch J. W. (1997) Groundrvater Geochemistry. Fundamentals and Application toContaminat.ion. I.ewis Publishers, 22lp.

Early E.L. and R*i f). {1987}. Kinetics of Chromium (III) Oxidation to Cltromium (VI) byReaction with Manganese Or^ide. Hnviron. Sci. 'fechnol.,21, I187-1193.

Fendorf S.C. and R, Z*soski {1992). Chromium(IlD Oxidation by E-N{nO?. i.Characterizatir:n. . Environ. Sci. Te*hnr:l., 26, 79-85"

Guertin J, Jacols J. and C Avakian i 2005). Chromium (VI) Hardbook. CRC Fress, 7&4 p.

Hern, J. D (1989i, Study and lnterpreiation of rhe Chemical Characteristics of Naturai Water.3'd ed. U.S.G.S. Water Supg;l-v Fape,,, 2254,263p

IIem, J. D (1992)o Study and Interpremtion of the Chemical Characteristics of Natural Water. 4eed. LI.S.G.S. Water Supply Paper, 2254,263p.

Jacobs J. and S. Testa {1fi}5}. Oven'iew of Chromium (Vl) in th* Environment Backgroundand History,ln "Chrt>nzium (VI) Ha.ndbctok", Guertin J. .Iacotts J. and Avakian C Eds. CRCPress.

Lloyd J. W and J. A. Heathcote (1985), Natural. inorganic h)'drochemistry in relationgroundwater. Oxford University Press, 296p.

Miljoprojekt, I.998, Staus fbr lukedde b*rir:ger ved aimene varndvaerker. Danish EPA.

Motzer W.8,, (2005, Chemistry" Ge{}chemistry and. Geolcgy of Chromiurn and Canrpounds."Chromium (VI) Handbooft", Guertin J. Jacobs J. and Avakjan C Eds" CRC Press.

Parlfiurst, D.t", and Appelo, C.A,J. {f999) User's guide to FHREEQC {\Iorsion 2)-acomputer prog&rri fbr speciarion, batch-reaction, one-dimensional transport, and inversegeochemical calculations: U.S. Ceological Survey Water- Resourr:es Investigations Report99-t259,312p

Piper, A. M. (LgM), A p.'aphic procedure in the geochemical interpretation at rvater analyses.Trans" Am. Liruphvs. [-lniln, 25,914-23"

Richards L.A {1954} Saiine and Alkali Soils. USDA, Agricuiture Hanclbook No. 60, i60p.

\4rorld Health Organization (1988), Ilnvironmental Health Cdteria 61, Chromium. Geneva,wHo, 197.

Aafvug A. (1971). farr:ic'yrrdq Xdprnq rqq Ell.d6ag, Ou)"?"o llpu0psi" I|ME

wHo, 197.

In

Aofvcg A.o Kal"idpFl€ I, M6pqrlq A* xar M. Ilo.^lorivqq (1978). Y6porysciL.o,vrrq eprirvul"rircrivqg anoppoflq p6cicro pmi Arrrrncii noto,poir. IT'h,fR Ap. 21,

Katorx6rooq I' (2{XX}} lecrr}.rJrr6q Xripqq rrlq Ei\.iticiuq, Ou}'"ln Epfrpw, I|MF,

Kcrorxtttooq f. (2002) feoloyxoq Xdpzrlq qq E)"1;i6ug. Otil,Lo Kqqqc'rd, I|ME

Kotarx&t<ro6 I, Mfcoq A., B166149 M, rur A. Ao$va6 {19S6} feo:lopr66 Xdpqg rqgE?S"&EoE, Otil,io A0r1vu - ELeuoiq,IfME

Mfrog A {1992}, Terctovrxtiq X&ptqe qg BA Attr.rrlq xst }{A Bcrt'rtiag (xi-, 1:50-000} f :

Meroq A. {1992} Icoi"ay*;q xc{.r ao.ifi,rolerrrypatptrtl pc}*it4 r{,}v iprttpotrrci:v Neoyer.'ri:v rc,rreroproTs'vcilv cryrlpaaoprbv BA Atu.rrlq ro.t I{A llorc:tiag. A$amoprcr1 frarpptl

M6ptpqg A. (1995) Y$poyearioyx{ Epa.rva raproucod u6porpdpou Euodl;rorog BA fl&pvq0a,;rcar erup*eup;1q nep:rop16l)*peiot Atnrtrlq. Ar$arropiicli ,kurplp{ unoB},r10eiou, ciro T'priu,nfstu)'oyta6 rou I srrsnro,trlpL{*t flcrpcil.

flona.vrrql"{i.oo A, {t986} fem}.ayta qq E}"\'i.Esq. E8vrrcd rear KdffioiirorprarS llavenra'rriproA0qv<iiv, TFrlirs l"ec*tr"ofug, 240oe1.,

Ilnpy:vdg A, Mcrpi$qq Av. xon I lYlnopvdFug Q$AT feail"o,vrxd-c X*pnriq a6 El"l"ri6ug, S6},1"oXai.xi8s,I|ME

Ttucpqq A., Koriv46 f. Mapayxoo6rircq_< N. rcr f. Xproto6oflou (1970) feroloprc6q Xapcqqrrlg Elfui8uq, O6),io OftFs, IFME

fiAPAPTHMA 1: Erntrcypfvol ldpreg KA. 1:50,000

1. fealaytr<dq X,itprqq - a4peia \erypanlrTyia,g

2. Xtiprryg tru:{apezpia4 xat porsq rou uzrdyr;rcu vepott

3. Xrtftorc rcdiaxyryEyrgq {Corine L*.wl Cover, 200A}

4. ,Ydotryq rcarcuopr1E xispttat' uivtatv oe 6w,ypd"pltdrd "Eir&;"

5. XapsrtErmzavogrTq vnpwril tdwrov (NOj')

6. ,Y.ry'rryq xatavoyrl q*sotpoptxtitv tdvrttr {PO4)

7. Xryvtg rwtarou7; y.iapfivratv (Cl' )

8. Xd.pr4; rcaurxop$q o),wo'i; yrr.tppirns {Cr*,i

9. ,Yap"qE Eo;rev(4.#lE e{o"a1wotiE Xpapfott {Cr6* )

]0. Xdpr1E xwavoprgq c'itxo{i ctirTpott (Ire*r}

11. Xaprrts rcarwopfsq vtxtiiots iNi)

12. XapwT; raravoy{1E Okrcrti Opya"vwot' Av1puxa {TOC)

IFTETITOYTO TE{}AOrIKQN tg KAI METAAAEYTIKf,TN …iftetitoyto te{}aorikqn kai metaaaeytikf,tn...

Documents

Transcript of IFTETITOYTO TE{}AOrIKQN tg KAI METAAAEYTIKf,TN …iftetitoyto te{}aorikqn kai metaaaeytikf,tn...